奈米使你變美了!-奈米二氧化鈦在化妝品上的應用
奈米的科學與技術將是21 世紀所要探討的方向。在了解奈米粒子的表面效應、小尺寸效應、量子尺寸效應、宏觀量子隧道效應後,發現其應用甚廣,諸如再生物、醫學、環境、國防、工業產品等方面,都將佔有很重要的地位。我們主要是利用溶膠-凝膠法來製造二氧化鈦奈米粒子,並了解二氧化鈦奈米粒子可吸收紫外線及光催化反應,將廣泛應用電子、紡織、塑膠、橡膠,空氣淨化及廢水處理方面。本實驗將利用二氧化鈦的吸收紫外線特性,來研究其應用在化妝品上面。The science and technology of nanomater will be the direction we will explore in the 21st century. After understanding surface area effect of nanometer particle, Small size effect, Quantum effect, and Macroscopic quantum tunnel effect, we can diswver the application is very far-fluing. For example:biochemistry, medical science,eneironment,national defense and industrial products,will devine a very important position.We mainly use sol-gel method to produce U-TiO?,and understand the absorption of UV and photocatalysis,plastics,mbber,purging air,and dealing with effluents.This experiment will use characteristic of absorbing UV of U-TiO? for researching the application of cosmstics.
Synthesis and Characterization of Niobium Nitride Nanowires
This project aims to explore the potential of inexpensive in-situ deposition of niobium nitride nanowires to improve electrical conductivity. Transition metal nitrides are well known for attributes such as superconductivity, high melting point, simple structure as well as excellent electrical and thermal conductivities. In particular, niobium nitride possesses exceptional hardness and high reflectivity, as well as being a stable field emitter, making it well suited to applications as a cold cathode material. Niobium nitrides are formed by the uptake of nitrogen by niobium. This is achieved by the exothermic formation of an interstitial solid solution of nitrogen atoms in the bcc lattice of the niobium. Existing research has established the possibility of preparing niobium nitride by heating niobium in nitrogen or ammonia over a range of temperatures, by heating niobium pentaoxide and carbon in the presence of nitrogen as well as by chemical vapor deposition of other niobium compounds, nitrogen or hydrogen. For the purpose of this study, a two-step process was used for synthesis. The benefits of a two-step process over direct ammonolysis are apparent, from the greater degree of freedom pertaining to parameter determination. Additionally, characterization of niobium pentaoxide nanowires synthesize under similar conditions is also made possible by terminating the reaction earlier. NbN nanowires were synthesized by annealing niobium pentaoxide nanowires at 850 oC for 2 hours. Subsequent characterization was done using Raman Spectroscopy, X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The presence of NbN nanowires via the conversion of Nb2O5 was ascertained by the absence of sharp peaks at 1000 cm-1 for Raman Spectroscopy and XRD plots. Field emission (FE) properties and electrical properties of NbN nanowires were then measured. NbN nanowires were found to have a high turn-on voltage, stable and relatively good field emission characteristics, demonstrating its potential as a cold cathode material. No current saturation was observed for an applied electric field of 0 to 6.0 V/ μm (5). This suggests a low degree of contact resistance for nanowires produced by this method of annealing, since the passage of electrons is not obstructed. Hence there will only be a small voltage drop between the SiO2 substrate and NbN nanowires. Samples containing NbN nanowires were dislodged by ultrasound to form an aqueous suspension of nanowires. A drop of suspension was dripped onto gold-finger substrates, and current-voltage (I-V) measurements of resultant nanowire bridges were taken. NbN nanowire bridges display Ohmic properties, in comparison with Nb2O5 nanowires that are semiconducting. Nanowire bridges obtained by heat-drying were denser and had better electrical properties than those obtained by evaporation to dryness. NbN nanowire bridges display Ohmic properties, in comparison with Nb2O5 nanowires that are semiconducting. Further work would include varying the cooling processes to observe any changes or deformation. Additionally, niobium nitride nanowires can be hybridized with carbon nanotubes (CNTs). A more in-depth comparison between niobium oxide and niobium nitride nanowires is also proposed, along with exploration of the nitrification of other transition metals.
「轉環」的餘地
在生活的觀察中,我們注意到人們在轉動呼拉圈時似乎是行一種「以軸轉動一個半徑遠大於軸半徑的環」的運動,在查過相關資料後,並沒有發現比較完整的探討。本研究的目的,是要找出在圓環被轉軸所驅動的運動模式中,影響環轉動頻率的各個因素,諸如:環半徑、環質量、轉軸半徑與環轉速之間的關係。根據我們所做的實驗,對相同的一個環而言,以半徑較小的軸用固定轉速轉動時,即使環的轉速變快,但始終與轉軸的轉速相等。由此我們推斷:無論環與軸之間的半徑關係為何,在環能穩定轉動的情況下,兩者的轉動週期將會相等。另外,在實驗的過程中,「軸驅動環」所引起的軸晃動一直困擾著我們,但這也引發了一項應用:如果原本穩定轉動的環和軸振動,則振動將被放大,藉此設計可以作為地震感測器。亦可作為儀器的保護裝置或是指向裝置。While playing a hula-hoop, we noticed that it seems to be a motion that the axis rotates a circle whose radius is larger than axis’. By checking relative theses, we found that there is no better research having fully discussed about this topic. The purpose of this research is to find out the motion pattern that a circle is rotated by the foce of an axis and the factors affecting rotation, such as radius and mass of circles, the radius of axes, and the frequency of axes and circles. According to our experience, no matter which height the circle stay at, or how fast the frequency of axis is, the frequency of circle will be the same. As a result of this, we guess that if it can be a stable circle, the frequencies of the axis and the circle shall be the same. Another confusing fact is the vibration of the axis, but it enables a new application: if a vibration affects a circle-axis system, the vibration will be enlarged. By this application, we are able to design an earth-quack senor, or protecting or pointing instruments as well.
電源線磁場再生能源的研究與應用
目前正逢能源危機之際,能源再生成為全球關注的課題。有鑒於此,本研究應用高導磁環形鐵粉芯,在表面纏繞多圈漆包線,形成環形管(Toroid)。環形管外圍再繞上交流電源線,電源線內電流產生的磁場,被高導磁環形鐵粉芯所引導,產生較強而均勻的磁場,傳遞至內圈的單心漆包線環形管,依法拉第定律產生電動勢,達到能源再生的目的。藉由六項實驗,驗明我們研究雙環形管理論,推演所得的電動勢公式 ε=(μN1N2/2 r) a2ωIo cosωt 是正確的。再生的電動勢能驅動高亮度的發光二極體提供照明、電器產品充電;還能提供電流過載警示,防止電路過載起火的危險;串、並聯使用則可產出較大功率,深具應用與研究的價值。During mankind are urgent developing of new energy, recycle energy are also one of the global topics; we are using single-heart-Turn around how the high permeability enameled wire ring formation of iron powder core ring solenoid, from the external power supply line also used around - Ring solenoid (Toroid), due to changes current power supply lines of magnetic field generated by the high-permeability core Ring guided iron powder, and can produce more uniform magnetic field so that the inner ring of single-heart enameled wire Ring solenoid, according to Faraday's Law electromotive force can be generated to achieve purpose of recycle energy, we will be divided into six experimental studies to confirm this theory deductions obtained by electromotive forceε=(μN1N2/2 r) a2ωIo cosωt is correct, this electromotive force will enable to supply high brightness LED Optical lighting, can also be used for current overload warning system , if use on series-parallel connection that will produce larger power output, it has great application potential, so the subject is worth to research and development.
滑鼠狂想曲
光學滑鼠會以很高的速度不斷地對著接觸面拍照,藉由比對每幅影像間的變化來偵測滑鼠移動的速度與方向,本研究利用此特點而設計一個簡易的光學量測系統,其中包括透鏡、光源與接觸面材質的選擇,以及利用Raw Input 模式讀取個別滑鼠移動訊息而發展出來的量測程式,使得此系統可以在無接觸與無摩擦的情況下來測量外界物體的移動速度與距離,經由實驗證明,在光學感測器還可以感應與追蹤的範圍內,量測的數據還蠻精準的。接觸面到光學感測器透鏡的距離越遠,能夠測得移動物體的極速也越高,但是會造成感測器的解析度下降,如此限制了接觸面的材質種類,無法量測表面較為光滑的物體,但是在設計得宜的情況下,仍有蠻多方面的用途,日後若能採用較高效能的光學感測器並加上測距儀的輔助,相信此系統的應用層面會更為廣泛。Optical mouse can take continuous snapshots very quickly of the contact surface and compare the images sequentially to detect the direction and amount of movement. This study uses this feature to design a simple optical measurement system, including lens, illumination and contact surface choice, as well as the measurement program using raw input model to accept the movement information from the mouse. This system can measure the distance and speed of the motion object under the non-friction condition. From the experiment test result, this optical measurement system is workable and satisfactory. Contact surface to optical sensor distance farther, can measure the higher speed of the motion object, but will cause the lower resolution of the optical sensor. This will limit the variety of the contact surface; superficial smoother object is unable to measure. In the future if we can use the high performance optical sensor and assist with rangefinder, believed this system can have more widespread applications.
Titania Nanotubes for Solar Energy and Catalysis
Introduction The discovery of titania (TiO2) nanotubes suggests vast improvements over extant titania properties. Titania nanotubes are aligned in highly-ordered arrays with a large geometric surface area, making them the ideal material for many applications. However, the mechanism responsible for the growth rates of highly-ordered nanotubes with optimal adhesive properties is not fully explained or understood. Purpose of Research The aims of this project were threefold: to explore the effects of different anodizing parameters on the fabrication of titania nanotubes; to study the photocatalytic activity of the nanotubes; and to deposit gold nanoparticles into the nanotubes. Methodology Nanotube Fabrication: Titanium foil was subjected to potentiostatic anodization with the use of various fluorinebased electrolytes, anodization voltage and duration to compare the effects of different parameters. Scanning electron microscopy (SEM) was used to characterize the nanotube diameter and length of the anodized samples. Photo-electrochemica1 Water-splitting: A PEC cell was assembled using the nanotubes as the photoanode and the samples were anodically polarized in a 1M KOH electrolyte. A potentiostat was employed to control the applied bias and to measure the photocurrent response under light irradiation. Overall photoconversion efficiency (ηc) of the samples was then calculated. Catalyst Support: A gold precursor solution was prepared with HAuC14‧3H2O. Using a novel depositionprecipitation (DP) protocol, gold nanoparticles were deposited on the nanotubes. SEM was used to scan for traces of gold and their locations. Energy-Dispersive X-ray (EDX) spectroscopy was used to confirm the identity of the gold nanoparticles. Data and Discussion Nanotube Fabrication: Preliminary studies found the glycerol/water and glycerol/formamide combinations to be the most promising. In glycerol/water-based electrolytes, higher water content corresponded to a decrease in nanotube length while higher anodization voltage resulted in a significant increase in tube diameter and length. In glycerol/formamide-based electrolytes, higher water content corresponded to a decrease in nanotube diameter while higher fluorine concentration resulted in an increase in inter-tubular spacing. The effects of various fabrication parameters were better understood, contributing to greater control over array dimensions. Photo-electrochemical Water-splitting: A higher anodizaion voltage resulted in a significant improvement in photoconversion efficiency. However, this trend was reversed in chlorine-doped samples, where a longer anodization duration corresponded with better photoconversion efficiency. Doping was found to enhance the photoresponse of the samples, with 6.32 % photoconversion efficiency obtained, suggesting new strategies for light harvesting and a step closer towards commercially-viable solar energy. Catalyst Support: Gold nanoparticles (5-10 nm) were successfully deposited onto the titania nanotube samples. Based on current literature, this was the first successful attempt at depositing gold nanoparticles into titania nanotubes. An EDX spectrum confirmed the identity of the gold nanoparticles. Compared to current catalytic converters, the gold/titania nanotube structure offered a larger catalytic surface area for reactants and the ability to function at low temperatures. Conclusion: By understanding the effects of various parameters on titania nanotube fabrication, the anodization process can be optimized to enable more precise control over array dimensions. High photocatalytic efficiency has also been achieved. In addition, doping is found to improve the photoresponse of titania nanotubes. Gold nanoparticles have been deposited, to our knowledge for the first time, onto the surface and inner walls of titania nanotubes.