環境工程

Chemistry experiments in school produce an abundance of waste in both materials and equipment. Since hands-on experimentation is a critical pedagogical tool the trend in classroom experimentation is clearly towards environmentally friendly experiments that scale, but was also able to measure reaction rate in blue cupric sulfate solution using the color dissipation as a rate gauge. There was an evolution of apparatus and experiment design beginning with simple magnifying glass optics and advancing to a custom made, light-gathering microscope video apparatus that allows the experiment to be monitored and files recorded for later viewing. I was inspired by the Yin Yang Sea phenomenon in Taipei County. The Yin Yang Sea is a coastal area in Chinkuashih, Taipei County where coastal currents in the area lack the strength to disperse the heavy metal pollutants that empty into the Lientung Bay. The result is a contrast between the blue sea water and the turgid yellow ground water. This contrast led me to add an all-purpose indicator to the reactant solution. This deepens the visual effect of the electrolysis experiment. 我們從環境保護的角度去思考學校的化學實驗時，減量減廢的微型化學實驗已是未來實驗的趨勢。經過多年的努力，我除了成功的做到電解最微量的一滴溶液外，對於從藍色硫酸銅溶液顏色消失的電解時間裡，還可做定量的檢定感到不可思議！為了更清楚看到液滴溶液的電解反應，儀器的設計由放大鏡到自組顯微投影機，最後進階到顯微視訊的畫面，它不但可記錄下來，而且可在電腦中播放。為了更清楚看到液滴溶液的氧化還原反應和酸鹼變化，我想到了在北台灣的金瓜石海域一處特別的景觀，那就是離岸近海處有黃藍兩個不同顏色的陰陽海！於是我加了廣用指示劑到液滴中，由電解後出現的的陰陽海畫面，更可加深實驗的效果。 最重要的是：最環保也最接近零污染的顯微化學實驗，已然是未來可發展下去的目標。

A novel and simple method was developed to determine the activity of silver in nanometer particles more than in non-nanometer particles. The conductivity of conducting polymer, polyaniline (PANI) doped with different amount of nanometer silver particles was used to evaluated the activity of nanometer silver. In polymerization of polyaniline, hydrogen chloride solution usually used to increase the conductivity of polyaniline. When 1%(w/w) nanometer silver particles doped during the polymerization, the conductivity of polyaniline was down from 2.28 s/cm to 0.65 s/cm, then increased with increasing the amount of nanometer silver doped. The conductivity of polyaniline was changed from 2.28 s/cm to 0.47 s/cm when 3%(w/w) nanometer silver particles doped, but it is increased from 2.28 s/cm to 2.44 s/cm when was doped with 3%(w/w) micrometer silver particles. The conductivity of polyaniline changed due to the formation of silver chloride (AgCl) in doping nanometer silver. Some of the nanometer silver particles were formed to silver ion in hydrogen chloride solution for the high activity property of nanometer silver. This also can be proved from the spectra of XRD and FE-SEM. Therefore; determination the conductivity of conducting polymer by doping nanometer metal particles can be used to determine the activity of the nanometer particles. 本研究為開發一個新穎的檢測奈米金屬粒子化學活性大於非奈米金屬粒子的簡易方法。方法為利用導電高分子聚苯胺，於合成過程中添加不同濃度的奈米銀粒子，並分別偵測其成品的導電度，藉以評估奈米銀粒子的化學活性。由於聚苯胺在合成過程中通常加入鹽酸以提高其導電度，致活性較大的奈米銀粒子於氧化後，隨即與氯離子形成氯化銀的沉澱，而降低聚苯胺的導電度，如添加1﹪(w/w)奈米銀粒子的，其導電度由2.28 s/cm 降至0.65 s/cm，隨後隨著添加量的增加導電度先降後再稍回升。一般非奈米級銀粒子因氧化電位為負值，即化學活性小，而不易被氧化。由實驗結果，我們發現同樣添加3%(w/w)的奈米級銀粒子或微米級銀粒子，添加奈米級銀粒子的導電度由2.28 下降為0.47，添加微米級銀粒子的導電度卻由2.28 上升為2.44，此乃說明本方法確實足以證明奈米級金屬的化學活性的確遠大於微米級金屬，因相同條件下，微米級銀粒子未如同奈米級銀粒子一樣被氧化成銀離子。即奈米級銀粒子可以輕易的被氧化，而非奈米級銀粒子則不易被氧化。尤其也可由X 光繞射儀分析光譜圖和場發射式掃描電子顯微鏡拍攝圖證明。因此，我們可以採用添加3 %(w/w)奈米級金屬銀粒子及微米級金屬銀粒子於導電高分子的方法，並藉導電度的變化，證明奈米金屬粒子的高活潑性。

A novel and simple method was developed to determine the activity of silver in nanometer particles more than in non-nanometer particles. The conductivity of conducting polymer, polyaniline (PANI) doped with different amount of nanometer silver particles was used to evaluated the activity of nanometer silver. In polymerization of polyaniline, hydrogen chloride solution usually used to increase the conductivity of polyaniline. When 1%(w/w) nanometer silver particles doped during the polymerization, the conductivity of polyaniline was down from 2.28 s/cm to 0.65 s/cm, then increased with increasing the amount of nanometer silver doped. The conductivity of polyaniline was changed from 2.28 s/cm to 0.47 s/cm when 3%(w/w) nanometer silver particles doped, but it is increased from 2.28 s/cm to 2.44 s/cm when was doped with 3%(w/w) micrometer silver particles. The conductivity of polyaniline changed due to the formation of silver chloride (AgCl) in doping nanometer silver. Some of the nanometer silver particles were formed to silver ion in hydrogen chloride solution for the high activity property of nanometer silver. This also can be proved from the spectra of XRD and FE-SEM. Therefore; determination the conductivity of conducting polymer by doping nanometer metal particles can be used to determine the activity of the nanometer particles. 本研究為開發一個新穎的檢測奈米金屬粒子化學活性大於非奈米金屬粒子的簡易方法。方法為利用導電高分子聚苯胺，於合成過程中添加不同濃度的奈米銀粒 子，並分別偵測其成品的導電度，藉以評估奈米銀粒子的化學活性。由於聚苯胺在合成過程中通常加入鹽酸以提高其導電度，致活性較大的奈米銀粒子於氧化後，隨即與氯離子形成氯化銀的沉澱，而降低聚苯胺的導電度，如添加1﹪(w/w)奈米銀粒子的，其導電度由2.28 s/cm 降至0.65 s/cm，隨後隨著添加量的增加導電度先降後再稍回升。一般非奈米級銀粒子因氧化電位為負值，即化學活性小，而不易被氧化。由實驗結果，我們發現同樣添加3%(w/w)的奈米級銀粒子或微米級銀粒子，添加奈米級銀粒子的導電度由2.28 下降為0.47，添加微米級銀粒子的導電度卻由2.28 上升為2.44，此乃說明本方法確實足以證明奈米級金屬的化學活性的確遠大於微米級金屬，因相同條件下，微米級銀粒子未如同奈米級銀粒子一樣被氧化成銀離子。即奈米級銀粒子可以輕易的被氧化，而非奈米級銀粒子則不易被氧化。尤其也可由X 光繞射儀分析光譜圖和場發射式掃描電子顯微鏡拍攝圖證明。因此，我們可以採用添加3 %(w/w)奈米級金屬銀粒子及微米級金屬銀粒子於導電高分子的方法，並藉導電度的變化，證明奈米金屬粒子的高活潑性。

The purpose of research:Lies the importance of research in rationalizing the consumption of water during the irrigation of gardens, farms and green spaces. Where the world suffers from the problem of water scarcity, especially groundwater was the slogan of World Water Day in 2007 ((water scarcity)), and therefore we find through studies and scientific research that the world is suffering from a marked decrease in the water up to 30% and thus to drought. The one of the reports issued by the United Nations Environment Programme, that more than half the world's population will live during the next thirty years until in 2032, In areas suffering from water shortages, and West Asia, including the Arabian peninsula will be more areas suffering from water shortages, are expected to live about 90% of the population in areas suffering from water shortages in 2032. Steps of scientific research: Theme: the rationalization of water consumption in irrigation How can rationalize water consumption and maintenance? How to benefit from raw materials to the environment be friends of the environment and water? How to maintain in our hemisphere is suffering from the problems of pollution? R: field environment Compile information: Started to develop the idea of working model in detail (scientific deliberate scheme) of the parts used in the rationalization process model and then work on the ground. Forming hypotheses, research and analysis of information: Assume that the flow of water through the faucet immediately for a period of one minute quantity of 2 liters permission when using pregled control the flow of water and a minute amount of water will be 0.2 liter. Suppose that the system used in the rationalization process is linked with the timing of rush hour drops of water every minute and measuring the quantity flowing from the pipeline, we find it 2 / 10 from the amount of water flowing from the tap directly. Procedures used: Been working model ready by using the following tools: Ban small-sized water Basin water model using plastic-coated shell and clay. Wall hours with wire sensitive prove on the basis of hours rolled aluminium conductor of electricity affected debates clock Plastic trees. Electricity wires - the context of an electric effort to 220 volts. The idea of working model: Labour deliver electric power 220 volts. Scorpion am touching on the sensitive installed base pm (aluminium foil) relates to the electric dynamo worked on the flow of water to the delicate moment senses only wait until touching once again to work regularly. Conclusion: Conclude that the rationalization of water consumption by 90% during irrigate parks and green spaces and farms. Perception of the future work: Research can be developed so that rationalization for more than a minute using the control and distance.

Although it is well known that, unlike the feces of a fowl, those of an ostrich\r do not produce foul smell, the impact of different enterobacteria on elimination of malodorous\r substances has not been seriously investigated. I sought to test the hypothesis that ostrich\r enterobacteria (OE) are useful to eliminate hydrogen sulfide (H2S) and ammonia (NH3), two\r important components of foul smell of the feces.

To find out if Sphagnum moss could be used as a cheap, reusable filter\r for poor families with water contaminated by heavy metals.

運用自製低頻噪音(

商家或是店家常常為了保持魚肉的鮮紅色澤使其看似新鮮可口，往往會利用CO氣體進行處理。CO對於魚肉中的肌紅蛋白有很強的結合力，可保持鮮紅色澤不易腿去。為了簡易、快速又有效的偵測魚肉中CO氣體之有無及含量，我們自製電化學CO偵測器，並以不同種類的溶劑以及不同濃度之酸，探討肌紅蛋白中CO氣體逸出的機制。此外，我們也討論如何有效增進CO氣體的偵測。我們由一氧化碳感測器(SnO2)、花茶罐、鑽洞的器材、三通閥、電池及電路板，完成自製偵測CO氣體電化學儀器，不僅方便攜帶，更能取代市售昂貴CO氣體偵測器及改善偵測器體積太大的問題。實驗中我們加上pasco電壓偵測及電腦裝置，利於我們進行實驗觀察。而且本儀器也利於在硫酸、醇類及高溫的環境下進行實驗，且高溫的環境下有利於促進CO從魚肉中逸出並偵測。

After an annual swimming rally in the Nahoon river, concerns were raised after several swimmers fell ill, complaining of possible symptoms of mild E.coli infection. Research was hence conducted to determine the following: \r \r \r The Nahoon River is safe for recreational activity in terms of faecal-coliforms and E.coli \r \r \r Whether the amount of rainfall affects these levels. \r \r \r If faecal pollution is present, to determine the possible point sources of the pollution \r \r \r To devise a method that needs no assistance from a laboratory, and could be done in a home environment at low cost. \r \r \r \r Procedures \r Colilert-18, (the reagent) contains nutrients which react to faecal-coliforms and E.coli in the sample. It causes samples to change colour when contamination is present. A dilution method (used by the Kowie Catchment Campaign) was used to test the severity of the contamination. The dilution levels were as follows: 1, 1/10, 1/100 and 1/1000. A control test was also performed. One Colilert capsule was divided among the five samples, which were incubated in a household stove at 37ºC for 18 hours. A sample was collected every four days and after heavy rainfall. \r The results were rated on a severity scale of 0-4, where a two was considered unsafe for recreational activity. If the undiluted sample remained clear, it was ra ted 0, if all the samples changed colour, it was rated as a four. The same rating system was used when fluorescing samples to test for E.coli. The daily rainfall level was compared to the levels of faecal-coliforms and E.coli. \r Conclusion \r As it has high levels of faecal coliforms and E.coli, the Nahoon River is not safe for recreational activity on a daily basis. \r Heavy rainfall causes the levels of E.coli and faecal coliforms to rise. \r The major source of the contamination is a stream entering the river from a newly developed settlement, and not a leaking sewer. \r This experiment has developed cost-effective home environment testing method which could be used in researching other rivers, marine environments, recreational waters and even drinking water by community researc