全國中小學科展

環境工程

奈米鑽石性能對於重金屬吸附之應用

奈米鑽石之多官能基、介面電位負值(PH=7時)…等性質使本組考慮其吸附重金屬離子之可行性。本研究目的在於利用奈米鑽石吸附重金屬離子及探討重複利用性。 將硝酸鉛、鋅、鎳、銅、鈷與鐵離子及錯離子水溶液配製奈米鑽石混合懸浮液。本實驗利用共扼焦顯微鏡了解奈米鑽石之生物共生與吸附特性。於重金屬吸附上運用LM324系統、及ICP-MS測量溶液濃度, 且用SEM觀察表面。 研究結果顯示,奈米鑽石具優越吸附離子能力,吸附前後奈米鑽石表面在巨觀與表面微觀上有顯著改變;且再利用性極佳,可利用硝酸置換出金屬離子。故奈米鑽石應可作為具再利用性之吸附材料。

Extracting Water from Humid Air Using Solar Energy in Humid Areas

The study aims to evaluate the technique of extracting water from humid air using solar energy through greenhouses in local areas. This technique is believed to provide limited amount of water in areas where potable water is not accessible or abundant. To solve this problem a pyramid-shaped device was designed, it is made of glass panels ad equipped with glass doors, fans operated by solar energy, and multiple shelves covered with fabric to act as Absorbent Calcium Chloride (CaCl2) with a 30% concentration. The doors are open during the night for absorption and closed during the day for energy-generating. Humidity, temperature, and atmospheric pressure are measured every two hours. The amount of water extracted in this area in one full day was around 3.0 liters a day for every square meter. Perhaps the limited amount of water is due to low level of humidity in the area: an average of 50% and temperature of F10 Celsius at night. However, the device itself is independent, does not need power sources, water sources, or infrastructure, can be installed in various places depending on humidity level as well as having the possibility of increasing number or size of device. This makes the device a promising, alternative and environmental friendly solution to produce water. Cost-effective and lighter material can be used to make the device, which will produce an easy-to-use and affordable devices. It is an area in need for further research to improve and further develop it.

Flexible Thermoelectric Module Application in Therapy Usage for Human Body

福島核災的發生,更凸顯能源的重要性;又因近年來廢熱總量不斷提升與全球能源需求量增加,本研究利用熱電晶片冷端與熱端的溫度差產生電的特性,將環境廢熱回收成為可用的電能。 本研究設計之可撓性熱電晶片成功改良傳統熱電晶片的兩點缺點;其一 : 傳統的硬式平板狀晶片無法配合不同環境空間而改變其外型,其二 : 硬式晶片的表面為陶瓷片,較易摔破導致晶片毀損,本研究之可撓性熱電晶片改良以往熱電晶片的陶瓷基板材料,改用具有可撓性的FCCL材料作為基板,因此可完整吸收表面彎曲物體的能源並將熱能轉換成電能。本研究之可撓式熱電晶片成功大幅降低熱電晶片之成本,有利於未來大量生產,成功應用人體體溫發電,同時也可利用Peltier效應,作為醫療用冷敷或熱敷之器材。

Beets Revolution

There is currently an interest in developing supercapacitors as the booming of smartphones and other mobile electric devices. Despite offering key performance advantages, many capacitors pose significant environmental hazards once disposed. They often contain fluorine, sulfur, toxic transition metal and cyanide groups, which are harmful if discarded by using conventional landfill or incineration methods. The objective of this project is to find an environmentally benign alternative for building various key components of supercapacitors structures. From the electrolyte, carbon substrate and materials corresponding for Faradic reaction, all the materials were devised from renewable biomass. In our research, two novel designs of betanin/sulfonated carbon supercapacitor and quinone/sulfonated carbon supercapacitor were invented. Betanin and quinone, extracted from beets and Sencha, was preloaded on the sulfonated carbon nanosphere as the composite. While sulfonated carbon nanosphere were fabricated by hydrothermal synthesis of renewable biomaterial, followed by surface functionalization - sulfonation for increasing the loading capacity of nanoparticle. Nanostructured morphology and surface functional groups were examined and confirmed by SEM and IR spectroscopy. Specific capacitance can be boosted up through optimizing the particle size, morphology and surface polarity of carbon substrate and the type of electrolyte. From the experimental result, it is believed that the nano-architecture, with active functional groups, of carbon nanosphere enables the efficient charge transport and electrode stability, allowing the composite with high capacitance (94–209 F g–1 at a current density ranging from 1 to 4 mA cm–2), high capacitance retention of over 90% after over 20,000 cycles respectively, and over a wide range of temperature. Superior electrochemical performance of both betanin/sulfonated and quinone/sulfonated carbon supercapacitor can be attributed to the large accessible surface area of the porous structure, low interfacial resistance and its structural stability. It shows that they have relatively higher tolerant towards heat and extreme pH mediums. The green electrochemical capacitor exhibits a promising capacitive performance of 209 F g–1 with high capacitance retention of over 90%, opening up new possibilities for the production of environmental friendly, cost efficient and lightweight energy storage system using renewable biomass as the basic building materials without harming the environment.

神農菌、嚐百草-利用基因轉殖的大腸桿菌偵測中草藥內的重金屬

中藥一直存有重金屬汙染的疑慮,而目前檢驗這些可疑重金屬的儀器與技術皆需耗費大量金錢與時間,因此研發出簡便快速的偵測工具極為迫切。本研究目的是利用基因轉殖的大腸桿菌,偵測出中草藥內的重金屬。 實驗結果顯示,利用含有銅離子基因轉殖的大腸桿菌,偵測7種常見的中藥材浸膏,除了黃岑之外,其他6種中藥材內可偵測到銅離子,並且具有定量的螢光表現。其中,研究發現由於黃岑本身會有吸附銅離子的現象,因此利用螯合劑EDTA來解決此問題。結果顯示,螯合劑不會影響大腸桿菌的正常代謝,但能成功地將銅離子搶出並誘導細菌產生螢光。最後利用螢光顯微鏡觀察,發現深色的中藥並不會影響大腸桿菌的螢光表現。 未來期望可將本研究初步成果,做更進一步的研究,除了能合成更多不同基因的大腸桿菌,以偵測不同種類的重金屬外,還製成便宜且方便使用的重金屬生物感測器產品,方便民眾檢驗手中的中草藥材,確保所使用的中草藥之安全性。

廢電池回收製成空氣電池與效能的探討

一般日常使用的電池雖是重要的供電來源,但在使用後也產生了許多的廢電池,造成環境汙染的問題。本實驗探討回收廢電池製成空氣電池的可行性,所謂的空氣電池是以空氣發電的一種電池,其負極為金屬,正極則是直接使用空氣中的氧氣。我們知道廢電池中所包含鋅殼、碳棒以及黑色粉末,其中黑色粉末內含有氧化錳與電解質,而電解質可溶於水,於是我們將其泡水過濾分離出氧化錳,然後將碳棒搗碎與得到的氧化錳混和製成正極。而鋅殼可作為負極。運用以上處理方法,我們成功的處理掉廢電池中大部分的廢棄物。 效能的研究方面我們改變了4個變因: 1. 正極反應物之碳與氧化錳的比例 2. 加熱純化氧化錳的溫度 3. 以不同金屬製成一次性電池 4. 改變電解液種類與濃度 分別得到以下的結果: 1. 碳粉0.8g加氧化錳1.2g時的反應最佳 2. 以300°C加熱可產生最多的二氧化錳讓反應較佳 3. 鋅可放電最久,高達19小時 4. 6MKOH中可產生最好的效能 此次實驗利用簡單的處理加工,將原本的廢棄物轉變成可以再次使用的能源,把這個技術做到最好,就是所謂的「循環材料高值化技術」。如果能夠擴大生產技術及回收流程成的速度,便可以發展成一個綠色能源。

Green Wastewater Treatment: Using Graphene Oxide produced from Date Pits to Degrade Organic Dyes via Novel Microwave Technique

Water treatment is considered as one of the top research priorities in Saudi Arabia. It has been reported by World Health Organization that, 50,000 people die every day from diseases caused by contaminated water. This research attempts to degrade organic pollutants present in wastewater by using Graphene Oxide synthesized from Saudi natural source. Physical activation of date pits was carried out by carbonizing the samples at different temperatures to produce active carbon. Hammer’s method was employed for the purpose of Graphene Oxide production. The resulted Graphene Oxide has been characterized using FT-Raman, XRD and SEM techniques. Methylene Blue (MB) dye was used as a model organic pollutants to examine the ability of Graphene with the aid of a microwave-system to remove such pollutants. A modified domestic MS furnace with a variable power was used to supply microwave energy. The MB solution 2.5x10-6M was mixed with 0.1gm of Graphene Oxide. The applied microwave power was ranged between 100 to 700 W and the time was set between 0 to 12 minutes. The samples were centrifuged and then filtered through a millipore filter to remove the Graphene Oxide dispersed particles. It is found that, 98% of the initial concentration of MB is removed effectively within 12 minutes under microwave power of 500 W. Chemical oxygen demand is shifted from 450 to 87 mg/L while biological oxygen demand was decreased from 270 to 12.8 mg/L which indicating the degradation of organic constituents. This method can be used for water purification from organic pollutants.

A STUDY ON TRADITIONAL ARCHITECTURE IN ITANAGAR CAPITAL COMPLEX AND TO IMPROVE A MODIFIED TYPOLOGY FOR A CLIMATE RESPONSIVE CONTEMPORY HOUSE

The lifestyle of the Arunachal Pradesh rural population demonstrates the example of sustainable living where bamboo plays a major role. Bamboo has its home in this tropical climate region of India. In order to understand various aspects of traditional bamboo constructions, a field visit was made to Rono, Emchi, Lekhi villages and Karsingsa, Pachin, NEEPCO areas. The paper studies the patterns affecting the housing styles of these regions, the traditional method of construction including bamboo treatments. Various parameters which are required to be considered for constructing a house are also studied. It has been found in the field survey that the utilization of bamboo is mostly in wall panels, columns, floor, door and windows. The question posed here is whether tradition houses perform better than a typical contemporary house in creating comfortable internal conditions. And if they do how it is possible for the contemporary house to benefit from the advantages presented in the design of the traditional house in terms of thermal performance. The results indicate that improved performance might be achieved by combining selected lessons from the traditional design e.g. improved shading, regional variations in window size related to orientation and adoption of adjustable ventilation and window openings.

"turn" -on (free food and renewable energy )

Nowadays Electric energy is the most useful in the world because we use it every day for lightening, work, entertainment ext … but electric energy also can be expensive and it will pollute the air plus we all know that the air pollution is getting worse. Our world consumes a huge amount of electric energy . Also we know that the homelessness is getting higher all around the globe and it reached a high percentage. The high price and the sudden cut of the electric energy and with it the air pollution makes a big problem. That’s why we created this project named TURN ON which is a friend of the environment and a friend of the humans. Our product will help us to produce and create strong, clean and renewable energy plus it will help the homeless to have free food and free transport tickets. After doing a lot of researches we found that our new method of producing energy gives a great electric energy and limit pollution. The kinetic energy is produced using rotations. That’s why we used the rotations of motorbikes, bicycles, cars wheels and turn that mechanical energy (wm) into electrical energy (we) that we can easily use in our daily life plus we can help homeless by giving them food widgets… in exchange with the electrical energy that they produced while using bicycles…After performing several tests and taking notes, we are able to conclude that our apparatus is indeed efficient as it is able to convert the rotation into electronic energy that we can store and use in emergencies to solve this big problem and in the same time to limit air pollution with using bicycles and reducing hunger regarding homeless. This machine should be easy to implement, cheap, does not depend on any other parameters such as the wind. Any rotation in any place can be a source of Electrical Energy. To facilitate the use of this new device, A START UP will be launched to rent electric bikes for “free”, distribute free food, snacks, tickets to homeless regarding to the energy production.

電池養魔豆──自製環保電池

本研究在於製造出一顆環保並可回收利用的電池,在顧及環保的同時,也要有更多經濟與日常的考量。 在電解液方面:藉由添加植物肥料中常見的含氮、磷元素之化合物,及金屬離子以產生氧化還原反應來獲得電動勢,如此一來,電池使用完畢後,還能將剩餘的電解液做為肥料來為植物施肥。 在電極方面:在政府教育的推廣下,使用後的乾電池都必須要進行回收以免破壞生態。據此,我們進一步從廢棄乾電池中取出電極部分並作為環保電池的電極運用,如此一來便能使廢棄乾電池重獲新生。 在外殼方面:我們利用可生物分解的甘蔗渣吸管為包覆材質。 我們已自製成功可產生約1.5 V的環保電池,後續將發完電的電池做為肥料並用來使植物茁壯成長,未來若能取代現有乾電池,那麼對於廢棄電池造成的環境汙染,將具有極大的改善效益。