全國中小學科展

環境工程

Process of making a new environmental friendly straw

本研究首先製作「蔬菜紙吸管」,其耐水性及吸飲功能不佳,改以海藻膠製作吸管,經歷多次改良後的「第三代海藻膠吸管」其質地近似塑膠吸管,但吸飲功能仍然不佳。接著,以海藻膠為膠著劑;紅茶粉為骨材,成功製作出耐水性、吸飲功能較佳且可散發紅茶香氣的「紅茶吸管」。提高添加紅茶粉之比例,能有效提升吸管硬度,可應用在飲料封口膜之戳入,在冰水、熱水中均可長時間維持吸飲功能,製作大口徑「紅茶吸管」,可輕易吸飲波霸珍珠,徹底解決吸飲波霸珍珠之難題。自製擠出成型機械,可控制出料速度維持穩定,在滑軌上以直線移動,可製作出粗細一致且筆直的吸管,最後試製綠茶、咖啡、檸檬等調味吸管,均會飄出天然原料之香氣,頗具商品化之潛力。

Synthesis of Biodegradable Plastic From Food Waste

Based on NEA Waste Statistics and Overall Recycling Rate for 2017, 809,800 tonnes of food waste and 815,200 tonnes of plastic waste was generated. Both food waste and plastic waste account for more than 10% of the total waste generated in Singapore in 2017 respectively. However only 16% of the food waste and 6% of plastic waste was recycled, the rest of it was disposed at the incineration plants and then the landfill. Such action will eventually lead to 2 major environmental issues that Singapore will face in near future: 1)Semakau landfill is our only landfill left and it is expected to run out of space in near future 2)The burning of food waste results in the release of methane (CH4), a greenhouse gas that has over 25 times the impact in trapping excess heat in the atmosphere as compared to Carbon Dioxide (CO2). This will increase carbon footprint and contribute to greenhouse effect and global warming in due course. According to the Sustainable Singapore Blueprint 2015, Singapore is working towards becoming a Zero Waste Nation by reducing our consumption, reusing and recycling all materials. A national recycling rate target of 70% has been set for 2030 with an aim to increase domestic recycling rate from 20% in 2013 to 30% by 2030 and non-domestic recycling rate from 77% in 2013 to 81% by 2030. As part of our total commitment towards waste management and sustainability effort, the purpose of doing this research project is to investigate whether food waste can be recycled and made into biodegradable plastics. First of all, chitosan will be derived from shrimp shells and be dissolved in acetic acid and lactic acid produced by probiotic fermentation of fruit and/ or vegetable waste for synthesis of biodegradable plastics.

Considering Fukushima’s contaminated water treatment system using algae ~ To protect the oceans from radioactive emissions

Nine years ago, the Great East 日本 Earthquake caused the spread of a large amount of radioactive materials. Even now, the amount of contaminated water is increasing at a rate of 180 tons per day, and it is said that the storage tanks for the contaminated water will run out of space in the next two years (Fig. 1). If the contaminated water is discharged into the ocean, it will cause reputational damage to the fishing industry, and the environmental pollution. We are conducting to research to prevent it from happening. In the wake of the nuclear accident, the senior started water quality surveys at Chaya Marsh near the school. During the survey, they found (Chara braunii, Fig. 2), (Nitella axilliformis, Fig. 3), Closterium moniliferum (Fig. 4), and (Nostoc commune, Fig. 5).

The Waves Fish Controller

Our oceans, coasts, and estuaries are home to diverse living things. These organisms take many forms, from the tiniest single-celled plankton to the largest animal on Earth, the blue whale. Understanding the life cycles, habits, habitats, and inter-relationships of marine life contributes to our understanding of the planet as a whole. Human influence and reliance on these species, as well as changing environmental conditions, will determine the future health of these marine inhabitants Humans influence the whole environment even if they don’t notice , the growth of men and our increasing reproduction over the years results to an over consumption of nutritious products , which makes us exploit the wildlife more and more and in the same time take parts of its habitats for us to life in and throwing our non-needed materials in what’s left of the world. And that’s a big problem because the Eco-System was just fine before we started over exploiting it in a greedy and unreasonable manner, and since the ecosystem’s parts are related altogether in an ongoing circle , the absence or the destruction of one part of It may lead to the unbalance and even destruction of the whole organized system. And that’s why as humans, it is our first duty to take care of nature generally and both fauna and flora specifically, not because of a moral code of some kind; but to protect Humanity from ourselves, and to preserve the human kind from destruction and extinction. And that’s the main goal of our project, that’s to help us organize our fishing exploitative activities with how much can the environment handle from it.

改良鐵氧體法利用配體去除含鉻廢水

鐵氧體是一種有特定晶體結構的複合氧化物,不溶於酸、鹼、鹽溶液和水。 鐵氧體法是目前較高效率、低成本處理六價鉻廢水的方法,該方法是利用亞鐵離子提供的電子將水溶液中的六價鉻還原成三價鉻,三價鉻取代鐵離子進入鐵氧體晶格後,形成鉻鐵氧體並沉澱。但在此過程中亞鐵離子只能提供一次電子,無法再次還原六價鉻。 目前已有文獻利用鐵氧體法達到99.68%的二鉻酸根去除率(1)。而在另一份文獻中指出,藉由亞鐵反應後形成的鐵離子與特定配體螯合,配體會釋出一個電子並使其再次還原成亞鐵離子(2)。根據這份文獻所指出的反應對鐵氧體法做出改良,進而達成亞鐵離子重複利用。目的是利用較少的亞鐵達到一樣甚至較高的去除率。 在我們的實驗中選擇了兩種配體。第一種是2,2'-聯吡啶,其是根據文獻的特定配體中選擇。第二種是乙二胺四乙酸二納,選擇它的理由是其對環境的危害較小。

製備超疏水性修飾石墨烯海綿應用於廢油回收

本研究使用聚胺基甲酸酯海綿為基材,藉由在表面吸附石墨烯材料使海綿具有超疏水性,使其能從水中有效分離出油類,達到油水分離的效果。我們研究出簡易自製氧化石墨烯的方法,並使用自創的照紫外光乙醇法將其還原成還原氧化石墨烯,接著吸附在海綿上,再使用十三氟辛基三乙氧基矽烷修飾石墨烯海綿,使其鍵結上具有超疏水性官能基。藉由測量海綿表面與水珠間的接觸角,我們找出了製做超疏水性海綿的最佳條件,最終完成了矽烷修飾還原氧化石墨烯聚胺基甲酸酯海綿(FS-rGO-PU Sponge)。 本研究超疏水性海綿的製程簡易、成本低且符合綠色化學,同時具有單位體積吸油量大,可多次重複使用等優點,我們除了測試其對食用油、礦物油的回收能力,並製作成可連續分離油水的裝置,可應用在工業、家庭廢油及海上油汙的回收,甚至可做為空氣清淨機或排油煙機的濾網。

懸浮微粒三維偵測與預報系統

近年空氣品質已是居住環境與健康的指標,「細懸浮微粒」充斥在空氣中,造成過敏,增加肺癌的危險。本研究探討懸浮微粒在受到重力、空氣阻力與空氣浮力影響後,形成分層。並利用VPython軟體模擬不同大小的懸浮微粒(pm10、pm2.5與pm1.0)於空間中碰撞及受到空氣阻力產生能量衰減,藉此了解不同微粒之分層現象。再實作以居住樓層不同的垂直高度,設計組裝架設「懸浮微粒三維偵測器」及物聯網。以台灣中部地區,日益增加的空汙狀況下,模擬以台中火力發電廠為例,探討其風向、地理環境、以擴散模式理論模擬後,選定數棟建築物,監測每棟建築物地面上不同高度的空氣品質數值。最後監測數值自動上傳至物聯網雲端資料庫 ThingSpeak,並可於使用者端監測及取得測量數值;期許再利用機器學習及歷史累積的三維空氣品質資料,將來更優化預測空氣品質數值之成效。

將廢矽泥製成奈米矽以及進一步應用於鋰離子電池負極材料之研究

矽元素因具有極高的理論電容和鋰攝取量(Li Uptake)而被認為是有潛力的鋰電池負極材料,然而該材料的特性使其在充放電時體積巨幅脹縮,造成結構碎裂,縮短了電池壽命。 本研究設計一套低耗能、低成本的製程,以現今台灣光伏產業大量難以回收之廢矽泥及鎂金屬為原料,將矽之粒徑縮小為奈米級以解決上述體積膨脹問題而成為極佳的鋰電池負極材料。 我們先將矽合成矽化鎂,再利用二氧化碳及氮氣的氧化還原反應製成多孔矽,隨後再利用創新的化學蝕刻法產出奈米矽。目前業界奈米矽的製備仍以高功率研磨為主,本研究首度使用銅離子、過氧化氫及氫氟酸作為蝕刻液,成功製造出平均粒徑100nm之負極材料。而過程中所使用的鎂粉可回收再使用,回收率高達94%,故幾乎無成本廢料排放,大幅降低當今鋰電池的生產成本,也落實防廢、再生、節能等綠色化學原則。

以空氣盒子探討台灣環境中懸浮微粒的潮解膨脹現象

我們的研究是利用空氣盒子設計出一個裝置,用以觀察環境中懸浮微粒潮解膨脹現象。 我們觀察了由硝酸銨與硫酸銨各自以及不同比例與混合模式組成的懸浮微粒。純硝酸銨的潮解點不明顯,純硫酸銨有明顯的潮解點。內混合懸浮微粒有一個潮解點,並且出現3種類型的潮解行為,分別是偏向硝酸銨或硫酸銨以及過渡型,後者粒徑成長的比例會比前兩者來得高。外混合懸浮微粒有兩個潮解點,保留兩種成分各自的特性。 我們利用雨水觀察環境中懸浮微粒的潮解膨脹現象,將其與內混合懸浮微粒的潮解點與潮解行為做比較,來推估其成分與來源。確定我們的裝置能推估出主要的污染成分及來源。

Detect the Defect

"When the Well is Dry, we will know the Worth of Water." Most of 埃及 and the world suffers from water and petrol shortage. With the current consumption rate, two-thirds of the world's population may face water shortages by 2025. These are water pollution, overpopulation, and agriculture, leading to wastewater from landfills and pipes that seep into the ground and may pollute the water, making it unfit for human consumption and waste more water. Besides, some accidents happen to water distribution and irrigation systems, causing a significant loss in water. According to the ministry of water resources, in 2016, the need for freshwater is 67 billion cubic meters. On the other hand, 埃及 receives only 55 billion cubic meters (2.6 billion cubic meters of them evaporate during runoff). Also, one of the wasting water methods in modern irrigation systems is water leakage from pipes as the water transmission and distribution lose about 31% of the produced water due to pipe leakage. Besides, every day more than 3.3 billion liters of treated water – 20 percent of the nation's supply and 234 million liters a day more than a decade ago – are lost through leaking pipes in England and Wales. Many reasons lead to leakage in pipes like water pressure, clogs, and corrosion. The leakage in pipes does not exist in the lines of water only. Also, the pipes in a petrol can cause dangerous accidents like the accident in the Bahira government that led to the death of 6 people and made 19 in a dangerous state. Our project designed a system that can detect fluid leakage and deal with it fast to prevent the wasting of fluid by using sensors and electronic circuits. Our system provides us with information about the fluid (like the amount of the flowing fluid and its speed). Therefore, if there is a difference in the reads, we understand that there is a leakage in this region, and the system will automatically stop the fluid flowing through the pipes. the system will locate all the leakage sites and send them to the mobile app with the amount wasted and the actions taken.