全國中小學科展

2012年

酒石酸配位掌性聚合物之自組裝合成、結構與特性研究

奈米技術在 20 世紀後期蓬勃發展,而具有奈米及孔洞的超分子更為化學家所積極尋求合成上的突破與挑戰, 超分子化學用來探討一些分子間較弱、可恢復性的作用力,以期製備一系列具有功能性的孔洞材料 。 其主 要分為以下六種: 1. 凡德瓦力 (van der Waals forces,energy -1) 2. π-π堆疊作用力 (π-π stacking interactions ,energy= 0~50kJ‧mol-1) 3. 氫鍵 (hydrogen bonds,energy energy = 4~50kJ‧mol -1) 4. 偶極 -偶極作用力 (dipole -dipole interactions,energy= 5~50kJ ‧mol -1) 5. 陽離子-π作用力 (cation interactions, energy = 5~80kJ ‧mol -1) 6. 離子 -偶極作用力 (ion-dipole interactions,energy= 50~200kJ ‧mol -1) 而分子自組裝即利用這些作力, 依熱學最安定的合發生然排列現象可應用於分離、化學感氣體儲存子交換導熱以及光電性。 本研究主要利用混合掌性異構物的酒石酸鉀鈉與硝酸鈣或鎂,在水酒精的環境下進行自組裝,利用簡單與無毒的自組裝合成法,讓右旋酒 石酸分子鎂金屬配位而左石酸分子與鈣金屬配位,別得到掌性聚合物除了將兩種 掌性異構物分離,也 實踐綠色化學中無毒與環保的概念 。

高速鐵路差異沉陷的新測量方法

臺灣高速鐵路因差異沉陷而有行車安全的疑慮,每年耗費數千萬來嚴密監測沉陷。因此,我們希望能有一個可靠、簡便、便宜、及時的新測量方法。 本新測量方法利用商務筆記型電腦中的加速度感測器,來記錄列車行進差異沉陷處的電壓變化,透過Quake Catcher Network Live軟體轉換成加速度值,再經過傅立葉轉換以濾除雜訊的影響,而從加速度、速度、位移、時間之間的定義,得到高鐵於該處的沉陷值。 透過全線測量,訊號的可靠性,使我們得到台灣高鐵全台差異沉陷的分佈狀況。而高鐵苗栗麻園坑段的反覆驗證,沉陷值的正確性,也在誤差的合理範圍內。 由此顯示,此新測量法是可行的。尤其相對於傳統的人工測量方法,這個方法更有利於迅速地測量高速鐵路的差異沉陷,作到即時監測、即時預警,防範事故於未然,更可節省大量的人力與物力。

A Backpropagation Neural Network Model on Precipitation Forecasting in the Philippines

Backpropagation neural networks were used to forecast daily rainfall with minimal error for Metro Manila in order to have an inexpensive way of accurately predicting weather. Calamities brought on by heavy rainfall have caused great economic, infrastructure and human loses. Neural networks have the ability to discern complex patterns in noisy data; this makes it a viable method for weather forecasting. Daily precipitation, humidity, rain indication, sea level pressure, temperature and maximum sustained wind speed for January 2000 to December 2010 were acquired from the Philippine Atmospheric Geophysical and Astrological Services Administration. The neural network made use of Python 2.7.2 and the backpropagation program by Neil Schemenauer (python.org). It considered different neural network architectures with a total of 2844 data sets for training and 708 data sets for testing. Each neural network’s accuracy was measured with a graph of the actual and predicted values, correlation coefficient, and root mean square error. It was observed that the neural network with architecture 5-8-1 yielded the most accurate results as it had the highest correlation coefficient of 0.48599 and smallest root mean square error of 14.84. It was also observed that the trends of the predicted values followed that of the target values. This suggests that it is possible to create a neural network with a moderate correlation given daily weather data. It is recommended that further researches make use of hourly data instead of daily data for more accurate results. Other variables, which might affect rainfall, not in this study should also be considered. This research could aid in the anticipation of calamities and the decision making involved in shipping, fishing and aviation industries.

不同氮源的氮氧化鈦可見光光觸媒之製備與性質探討

本研究擬利用液態合成法,以尿素(urea)、硫脲(thiourea)與氨作為摻雜物與市售之TiO2粉末均勻混合,製備高活性於可見光下應答之氮掺雜的二氧化鈦奈米光觸媒(TiOxNy)。探討氮物質來源與濃度、合成時間與鍛燒程序對於生產之氮氧化鈦的性質影響。合成之氮氧化鈦粉末將利用X光繞射儀(XRD)、掃瞄式電子顯微鏡 (SEM)、紫外光-可見光分析儀(UV-Visible analyzer)進行材料特性分析(如結晶型態、表面型態與能階)。在實際光觸媒分解污染物之應用方面,由於亞甲基藍呈色容易且較易量測,將作為污染物用於做氮氧化鈦之初步效能評估。研究結果發現:摻雜不同氮源之氮氧化鈦光觸媒與純二氧化鈦結晶相似,且並未發現其他雜相形成。透過EDS N Mapping,可證實氮原子確實分佈在二氧化鈦上。本研究製備之不同氮源的氮氧化鈦可見光光觸媒的吸收範圍確實提升。其中,又以硫脲(Thiourea)為最佳,且其光降解效能最佳。

聖嬰現象與西北太平洋颱風之關係

我們透過1970~2010 年西北太平洋颱風的資料分析,探討聖嬰現象與颱風生成、路徑、強 度和消亡的關係。我們發現,聖嬰現象發生時颱風較晚生成,颱風季較短,且生成後路徑偏 北,東北亞國家受到颱風侵襲機率增加,反聖嬰時期颱風則較易侵襲東南亞。在夏季,臺灣 於正常期比較容易受到颱風的侵襲,而反聖嬰現象發生時,秋颱侵台的機率增加,臺灣須嚴 防秋颱的威脅。雖然聖嬰期颱風生成月份較晚,但生成位置遠離陸地,使平均壽命較長,颱 風強度也易增強。統計結果也顯示,颱風的消亡與聖嬰現象無明顯關聯性。

DCPIP變色比一比

“藍瓶反應”是一個常見的趣味實驗,以亞甲藍的藍色←→無色瞬間的變化令人稱奇。經過實驗,我們從許多不同的染色劑中,發現除亞甲藍之外,亦有能夠進行藍瓶反應的──“DCPIP”。於是我們進一步探討“DCPIP”的結構,並探討其可能的反應過程,及在不同條件下之反應速率。於是我們就發現了不僅葡萄糖、果糖、半乳糖可出現藍瓶現象,只要可以繼續氧化的官能基(例如羥基或醛),在其官能基附近有拉電子基的存在,亦產生效果絕佳的藍瓶反應。 亦以葡萄糖本身為探討的主題,到底是哪一個官能基最有可能先開始反應?也探討DCPIP、氧氣、葡萄糖及氫氧化鈉四者之間可能發生的機制。我們也發現了藍瓶反應的現象要發生,四者的條件缺一不可。另我們亦以氧化電位及還原電位去探討其中可以變色的原因。於是就慢慢揭開藍瓶反應神秘的面紗。

Fig Preservation

Figs have become an expanding industry here in New Zealand and are a current export fruit which could potentially provide a large amount of profit to both growers and the New Zealand market as a whole. Nicola’s family has about 10 acres of fig trees. They sell the figs locally and as an export. They generally sell for about $13 per kilogram here in New Zealand and $26 in the USA. However, figs only have a shelf life of about 7 days. This is because at present there is no proven pre or post-harvest treatment or method of storage that helps to decrease the rate of decay of the fig fruit. After researching post-harvest treatments for figs, Nicola found a report which claimed to have developed treatments that increased the shelf life of figs by about 5 weeks. With this kind of increase, it would be possible to transport, store and export figs over longer periods of time without running the risk of losing large amounts of produce, or delivering unsatisfactory fruit to customers. Nicola developed 7 different post-harvest treatments based on the ones that had shown promise in earlier research. These were hot-water baths of different temperatures, both with and without different bleach concentrations. To test these on the fruit she set up four experiments – a dry matter test, a firmness test (using a penetrometer), a colour test and observation of detrimental features of the fig. She tested these treatments at 0, 7, 14, 21 and 28 days from harvest. Nicola found that after 7 days, the firmness of all of the figs that had been treated had decreased to a large degree. The only figs that did not have a massive decrease were the untreated fruit. However after about 14 days, the firmness of all of the fruit became about the same and after this 14 day mark, she would not have considered any of the figs to be edible. However, in the appearance tests, it seemed that the treated figs that had the least amount of mould and rot were the ones that had been treated with higher levels of bleach such as the 55 degree Celsius water bath with 0.003L of bleach to every litre of water, and the 35 degree Celsius water bath with the same concentration of bleach. Overall, Nicola’s results showed that the hot water bath, and hot water bath and bleach post-harvest treatments did not slow the decay of the fruit in the earlier weeks after picking. In effect, Nicola’s research showed that the information she had relied on to help plan her study had claimed too much and that the treatments were less effective than had been stated. More research will be needed to find a more reliable way to improve the shelf life of figs.

阿里巴巴轉盤問題

本作品為環球數學城市競賽的考題之推廣( International Mathematics Tournament of the Towns, Senior A-Level Paper, Fall 2009, No. 7 ),然而此題目本身比較接近Scientific American ( Feb 1979 )中 Martin Gardner 的文章 The Rotating Table 所提出的問題。 而此問題的多邊形版已被數學家解決(Ted Lewis & Stephen Willard, 1980, The Rotating Table,Mathematics Magazine, 53,Page 174-175.)。然而此份作品採用簡潔的初等數學歸納法證明了原本的多邊形情形,且專注於探討條件改變為m=n-1時的多邊形情形。 m=n-1時的情形是前人所沒有做出結果的,且m=n-1的情形遠遠比m=n 的情況來得複雜多變,其中估計上下界所使用的許多組合技巧相當特別。然而其中當n為3 和5的倍數時有比較特殊的情況,這一個部分僅能給出目前得出的k值上界。而其他情況則能夠找出所有的k值。

缺幾格大不同-從方格排列結構到路徑之探討

本研究探討將方格填入Young Diagram之排列結構,考慮填入的順序並計算其方法數。已知Hool Length公式得以計算特定形狀的Young Tableau方法數,而本研究欲討論在給定各相連方格形式與其數量的情形下,一般化的排列圖形之性質及數量關係。首先發現骨牌的排列與「缺一格」形式之數量相同,進而深入觀察排列的結構以尋找兩者間的關聯性,並藉此對應關係(bijective relations)解釋這個特別的現象。接著,進一步的利用路徑表現此結構的相關性質,嘗試探討一般化的缺格情形,藉由路徑的對應,得知該排列方法數均為「廣義Motzkin數列」的線性組合。除此之外,更擴展至廣義的r-Ribbons「多格相連」的排列結構,發現r-Ribbons方格排列圖形在完整與「缺一格」的情況下可一一對應,若將n個r-Ribbons填入高度為H的Young Diagram中,當H不超過r時,其總方法數為Hn,以各列編號相異的方格數量進行分類,其結果為在H為空間下的Pascal分佈。

Seeing Dots.

一樂隊表演,攝影師站在這樂隊的外圍拍攝。由於樂隊排列的位置,攝影師必須在外圍移動才能拍攝完整個樂隊。現在將樂隊移至直角座標中整數格子點上。攝影師依序在原點,x軸,y軸整數上的拍攝點拍攝位於平面上mxn (n→∞)的陣列。但有些點會被其他的點擋住,而無法拍攝到,討論如何用拍攝點拍攝到全部的陣列的方法探討其點數。要解決這問題需要其他的點去輔助。隨著mxn的陣列變大需要越多的拍攝點才可以看完。想要用最少的拍攝點拍攝,需要固定且有理論的方法。經過研究,找到mxn陣列(1≦m≦100, n→∞)的結果,若y軸上取一個拍攝點,其結果會使拍攝點個數都是優於先前文獻之結果。由於拍攝點點數是全新的數列,我們使用數學方式預測。由二維平面拓展到三維空間,其二維平面結果仍適用於三維空間。可探討天文望遠鏡拍攝恆星間的關係。