全國中小學科展

2025年

大氣常壓微電漿合成共價有機框架應用於光催化降解汙染物

為了解決水污染問題,本研究探討共價有機框架(COF)作為光催化劑的應用。COF具備高度可調孔洞、高穩定性及選擇性吸附等優勢,有助於有效去除水中污染物,對未來具有前景。本實驗採用大氣常壓微電漿合成COF,此方法能在室溫下以水為溶劑,無需高溫或有毒化學品,並僅需一小時即可完成合成,具有綠色化學優勢。實驗結果顯示,成功合成的COF能有效降解水中常見染料污染物(結晶紫及亞甲藍),證明了COF的高效光催化性。在紫外-可見光光譜中,隨著光催化反應的進行,染劑吸收波峰顯著減弱並幾乎完全褪色,確認了COF優異的降解能力。掃描電子顯微鏡圖像顯示,COF的高度有序孔洞結構提升了其催化活性與穩定性。這項技術不僅能高效處理水中有機污染物,還具備廣泛應用潛力,有望為全球水污染治理與環保提供新思路。

沙波紋與新月丘—從地球到火星

本研究旨在探究風成沙紋的型態和其移動速度及新月形沙丘的演化過程。利用吹出式風洞建立穩定且單一風向的風場,並運用不同粒徑的石英沙,以研究不同情況下沙紋和沙丘的變化。研究發現,風成沙紋的波長變化不僅受到風速、粒徑等特性的影響,還可能受到波峰後渦流長度的影響。另外觀察沙紋移動速度的變化後,可以明顯的發現與風速有高度正相關,亦討論能量的變化,並試圖建立風速與移動速度的轉換模型。在新月形沙丘演化過程的模擬中,我們歸納出三個主要時期:延伸期、崩落期和消逝期。我們也針對這些結果進行質性分析,透過觀察與討論,進一步了解沙紋與沙丘之變化過程與形成條件。最後我們比較了火星橫向風成脊(TAR)的形狀、動力及分布差異,推論其可能成因,希望進一步探究行星地表形貌的形成和演化過程。

臺灣西南部古亭坑層泥岩之古水深變化

二仁溪剖面因受到小滾水逆斷層截切 ,而分為東、西剖面兩部分,東剖面的地層較老西剖面的地層較年輕,故推測該地區東剖面古水深較西剖面深。本研究利用微體化石有孔蟲比例(%P)進行研究,希望能夠探討臺灣西南部沉積盆地的演化,以及二仁溪剖面地區的古水深變化與粗顆粒含量的相關性。但由於本研究使用的樣本並沒有採樣於每一沉積岩層,故臺灣西南部沉積盆地的沉積物供應量與構造抬升的因素仍需進一步的研究。

正本「塑」源-探討河川塑膠微粒

基於對鄉土的關懷,我們選定高屏溪流域,來研究河川中塑膠微粒的尺寸大小和含量,透過光譜來了解塑膠微粒的材質。高屏溪流域是跨高雄及屏東地區最大的河流,我們共分為枯水期及豐水期來採水,比較不同季節之塑膠微粒類別,若以形狀區分:枯水期塑膠纖維最多,豐水期塑膠薄膜最多。若以尺寸區分:枯水期100~500μm的佔最多,豐水期25~100μm的佔最多。若以材質區分,枯水期含量最多分別是PE及PP,豐水期含量最多分別是PE及PET。若從顏色區分,大多是白色及透明為主要顏色。以上實驗結果可供主管機關列為重要監測參考,特別是國內少有研究單位或機構,在進行高屏溪流域塑膠微粒類別、含量之調查與研究,因此本研究重大發現為國內創舉深具意義,可供相關單位後續深究參考之價值性。

Measuring the large nonlinear refractive index of pigment from avocado leaves by a laser pointer

本研究報告,從酪梨葉利用柱層分析技術萃取出葉綠素-a、葉綠素-b以及類胡蘿蔔素,用來研究其物理性質以及測量非線性折射率(n2)。 當雷射光束照射在置於比色管中的樣本時,中央軸上的強度最高,導致溶液產生了溫度梯度和折射率梯度。雷射光束穿過溶液後,在屏幕上產生了遠場繞射圖樣。這些繞射圖樣的最大半徑(Rm)和暗條紋的數目(N)隨雷射光的功率(P)、光徑長度 (𝓵)、溶液的熱吸收係數(μ)和溶劑的熱光係數(dn/dT)變化。從N對𝓵和N對P的關係圖中,可以計算出溶液的n2。 在本研究中,從酪梨葉中萃取的色素濃度分別是從菠菜和朱槿葉中萃取色素濃度的4.0倍和3.1倍。更令人驚訝的是測得的n₂ 值比石墨烯大100倍。結果顯示,該樣品具有顯著的非線性折射率,使其成為各種光學開關應用的理想材料。

The Maximum Area of N-gons within the Intersection Region of Two Congruent Circles

At the 61st National High School Science Fair of Taiwan, the first-rank paper "The Study of the Largest Area of Inscribed Triangle within the Intersection of two circles" was presented. The authors discussed several properties of maximum area of inscribed triangles within intersection regions of two congruent circles. They only claim their results but without providing a rigorous proof. However, we give a proof by showing the convergence of the iteration of finding the largest height. Subsequently, we offer new methods to approach the problems such as the trigonometric identities, Jensen's Inequality to prove the maximum area of triangles and quadrangles within the intersection region of two congruent circles. Finally, we determined the maximum area for the case of n-gons. We conducted further research and discussion on this issue. In the future, we hope to prove why the maximum area of n-gons within the intersection region of two congruent circles occurs when there are two points on the intersection points of the two circles. We aim similar problems in the three-dimensional space, namely the maximum volume of tetrahedron within the intersection of two unit spheres.

Wrong seating around the table

本研究探討在一場圓桌會議中,n人逐一亂序入場找尋各自對應的名牌編號(1~n號)入座,其中1號第一個入場並坐到了k號位,此後入場的人們若發現與自己編號相同的位置是空的,就直接入座;若與自己編號相同的位置被占走了,就以逆時針方向尋找空位入座。在上述的規則下,若共有n 人,且 1 號坐到 k號位的情況,給予與問題相關統計量的組合證明。後續本研究將規則改為1 ~ p號 按照順序進場且皆想坐到 k 號位的前提下,探討了坐錯的人們是怎麼樣的循環和坐錯人數的次數分佈。並多數的研究結果皆與 stirling numbers of the first kind 有相關。 本研究還 探討了共有 n 人,且 1 號坐到 k號位的情況下, 坐錯人數的標準差函數的遞增情況 與對數函數完全曲線相關。

Synthesis of Nanocomposite Nanocellulose From Durio zibethinus L. and TiO2 NPs as Potential Food Packaging Antibacterial (E. coli Wild Type and Resistance)

According to the 印尼n Association of Olefin Aromatic and Plastic Industries/INAPLAS, 2019 national plastic consumption still relies on plastic packaging at 65% and surprisingly, around 60% of plastic waste is absorbed by the food and beverage industry. The waste has been widely sought to be environmentally friendly, one of which is by developing biodegradable packaging. The purpose of this research is to make durian peel cellulose nanocomposites impregnated with TiO2 NPs, to form antibacterial properties against E. coli wild type and resistance. In this research, there are research methods consisting of nanocomposite synthesis, PSA test, FTIR, physical characteristics test and resistance test. The results analyzed that the nanocomposite nanocellulose-TiO2 NPs was successfully made using a 1:1 ratio and had a particle size of 458.7 nm based on the PSA test, which is classified as a nano size. The success of nanocomposite synthesis was proven by the results of FTIR analysis, which showed the formation of 698.65cm-1 and 1633.99cm-1 spectra, indicating the peak of TiO2 NPs and O-H functional groups on TiO2 NPs, as well as 1028.98cm-1 and 1158.42cm-1 showing C-O and C-O-C bonds in cellulose. The antibacterial test performed showed no significant activity in disc diffusion and well diffusion tests against E. coli wild type and resistance. This is potentially caused by inhomogeneous particle size variation. Physical characteristics test showed that the tensile strength test (0.075 > 0.0125 MPa) Durio Nano-Pack is superior to styrofoam, but the compressive strength test (0.125 > 0.875 MPa) shows the opposite. In this study, nanocomposite has a potential innovation that provides good mechanical properties and has a dual function mechanically as bio-based food packaging and chemically as antibacterial. Further research is needed to improve the particle size homogeneity of nanocomposites, modify the impregnation method, so that it has the potential to develop multifunctional materials that excel in various applications.

Proposal for the Restoration of Fire-Damaged Soil Using Water-Soluble Aromatic Compounds Derived from Soil Actinomycetes

The following issues associated with soil affected by wildfires were identified: First, there was a significant decline in the populations of anaerobic and aerobic soil bacteria, which play a critical role in the decomposition and cycling of organic matter. This decline resulted in reduced water retention capacity and porosity of the soil, leading to poor moisture retention and increased evaporation compared to unaffected soil. Moreover, the organic matter content in the soil was significantly depleted, inhibiting plant growth. Additionally, there was a notable proliferation of methane-producing bacteria, which contribute to the greenhouse effect. It was further observed that fire-damaged soils exhibit limited natural recovery, even over prolonged periods. .An investigation into the underlying causes of these problems revealed that actinomycetes, the primary microorganisms responsible for producing watersoluble aromatic compounds in soil, are particularly sensitive to heat compared to other bacterial species. Research demonstrated that the population and diversity of actinomycetes are significantly diminished in soils exposed to wildfires. To mitigate these issues, water-soluble aromatic compounds produced by actinomycetes were extracted and introduced into wildfire-affected soil. This intervention promoted the restoration of actinomycetes populations, enabling their normal growth in the affected soil. Consequently, various wildfire-induced soil problems were effectively resolved. These outcomes were confirmed through the study...Key Words: Actinomycetes, anaerobic and aerobic soil bacteria, methane-producing bacteria, wildfires, water-soluble aromatic compounds.

Utilizing Sparse Optimal Linear Feedback Control to Design Targeted Therapeutic Strategies for Enhancing Gut Microbiome Stability

According to the 2024 American Cancer Risk Survey, one in 24 individuals is at high risk of developing colon cancer. This condition is linked to gut microbiome instability. Consequently, there is a pressing need for a more effective and precise approach to maintaining gut microbiome stability, which this research aims to solve by finding the most crucial bacteria species in maintaining the stability of the gut microbiome through the application of Optimal Linear Feedback Control. Two of its variants being applied in this research are Sparsity Promoting Linear Quadratic Regulator (LQRSP) with a variety range of  (0.05, 44.58, and 49.84) and Linear Quadratic Regulator (LQR) ( = 0) along with other supporting methods; Controllability Gramian and Network Theory (graph analysis). The finding in this research shows that bacteria species Bacteroides hydrogenotrophica, Bacteroides uniformis, Bacteroides vulgaris, Bacteroides thetaiotaomicron, Escherichia lenta, and Dorea formicigenerans have an important role for preventing and medicating a variety of gut-related diseases. This conclusion is reinforced by the analysis conducted using the Controllability Gramian, displaying five of the chosen bacteria with the highest controllability index, which demonstrates that the system can be effectively controlled. This finding suggests a potential for enhancing therapeutic strategies, rendering them more precise and systematic. To gain deeper insights into the relationship between each bacteria and the rationale behind the selection of these bacteria by LQRSP, this study also employs network theory, which successfully elucidates the choice of Bacteroides uniformis despite its low controllability index. Additionally, to further validate the efficacy of these bacteria, the research develops a simulation that compares the controlled system with the uncontrolled system, utilizing two types of disturbances. The results indicate a significant difference in robustness against disturbances between the controlled and uncontrolled systems. The findings from this research can be used as a foundation for a more efficient and systematic intervention strategy findings. By researching gut microbiome composition regulation using a mathematical approach, it opens new opportunities for new method discoveries aiming to increase the health of the gut microbiome which is beneficial for the medical field and prevention of gut related diseases.