全國中小學科展

2023年

二氧化碳高選擇性轉化生成合成氣之碳中和工程

近年來碳排放的淨零是全人類所想達成的共同目標,因此本研究透過油浴將鐵、鈷或鎳離子與配位基配位,並形成以2-甲基咪唑為配體的前驅物沸石咪唑骨架,以及以雙氰胺和葡萄糖反應為配體的前驅物類石墨相氮化碳,再鍛燒形成可導電的催化劑。研究者分別以上述兩系列的金屬單分散催化劑,使用氣液分隔的氣體擴散電極進行電解人工光合作用,將CO2高選擇性地還原為CO,並探討各催化劑產CO效率。本研究發現鎳金屬類石墨相氮化碳對CO2還原反應的選擇性極高,能使產CO效率達到99%。而CO作為合成氣已有成熟的工業製程,能生成許多具經濟價值的產物,工業需求量非常大。未來若實際執行,則有助碳中和目標的達成。

Laying waste to Energy problems

This research aims at exploiting civil and pre-treated industrial wastewaters that go into the purifier and those that come out of it after various treatments in order to build a galvanic cell with the goal of producing clean electric energy. Our background hypothesis is that it is possible to exploit the existing potential difference between these two types of water to generate electricity. In fact, the water sent for purification contains elements (carbon, nitrogen, sulphur, phosphorus, etc.) in a predominantly "reduced" state and its oxygen level is scarce. On the other hand, the water coming out of the process contains the same elements in a mostly "oxidized" state and it is rich in oxygen. Those chemical discrepancies should get the job done. In order to simulate the two types of water, two different solutions were prepared. The first one is highly concentrated with pollutants and gaseous nitrogen is insufflated in it to reproduce its anoxic environment. The second one’s pollution level is based on the Italian legislative limits of chemical contaminants for superficial waters (Legislative Decree 152/2006) and the semi-cell is insufflated with gaseous oxygen.

STUDY OF ATMOSPHERIC AIR POLLUTION OF POLTAVA REGION

Ukraine as a whole, as well as Poltava Region in particular, have a problem with the state of atmospheric air pollution, because the vast majority of motor vehicles and industrial, energy, and mining enterprises are not equipped with proper cleaning filters. A clear confirmation of the ineffectiveness of Ukraine in matters of monitoring the condition and protection of the atmosphere, in comparison with European countries, was the scandal with the manipulation of exhausts of the Volkswagen concern (Dieselgate). Diesel engines use a catalyst with injection of a urea solution (AdBlue), or a catalytic converter built on the principle of accumulation of nitrogen oxides on a metal surface made of barium compounds . Synthetic urea in automotive catalysts transforms dangerous nitrogen oxides into harmless nitrogen and water . However, due to the software, during everyday use of the VW engines in question, this function remained disabled and the catalytic converter was simply removed. However, we see such cars, along with others, even more morally and technically outdated, on the roads of Ukraine every day. The practice of burning stubble in spring and autumn also leads to extreme consequences of air pollution. The morally outdated system of monitoring the state of the atmosphere, which has remained in Ukraine since Soviet times, is not able to show the real state of pollution, and the lack of proper control on the part of the state leads, in general, to the worsening of the situation every year. Environmental problems in the country in general, and in Poltava Oblast in particular, are the cause of the spread of cancer and high human mortality. Almost 80,000 people die of oncology in the country every year. According to 2020 data, the mortality of the population of Poltava Oblast from non-communicable diseases exceeds the average indicators for Ukraine: Ukraine – 1,597 people per 100,000 population, Poltava Oblast – 1,793 people per 100,000. Therefore, the relevance of the problem raised is extremely high, and it is necessary to start with monitoring air pollution and raising the problem at the national level, because most of the country's residents do not even know what kind of air they breathe at home and on the street.

斜槓元宇宙-智慧新農機:全球首創利用Arduino自動偵測「迴轉耕耘機」犁耕土壤深度的火犁仔(曳引機)、解決人類糧食危機

本研究以機電整合,發明了【曳引機迴轉犁偵測系統】,將大型農業機械智能化,並優化及整合工程技術,設計了六大系統,藉由量化評工程效益及作物的產量變化,觀察設計成效。 根據文獻,水稻管理使用「灌溉系統」+「雜草抑制蓆」+「生物肥料」的機制,可以增加產量[1,2]。因此我們優化這些機制,並設計「精準深耕」、「智慧噴桿」、「滴灌系統」形成六大系統。利用自創的【曳引機迴轉犁偵測系統】,犁耕時就可以在每一寸土地上,精確控制土壤深度在25cm的「精準深耕」。我們也發現,在這六大系統的協同效應下,不僅省下3~12倍的作業時間,同時在加乘效果的作用下,產量可以大幅提高至79%。 本實驗花二年時間,在台中清水地區1.2公頃的農地,實際建構這六大系統。並使用無人機偵測飛行高度的3D立體影像感測器、Arduino微控制器、燒入自行設計的Arduino C程式,成功發明【曳引機迴轉犁偵測系統】,並裝在大型曳引機,用來偵測迴轉耕耘機翻鬆土壤的深度,同步將該數據立即顯示在駕駛室的儀表板。 目前全球六大品牌大型曳引機,造價超過新台幣400萬元,尚無一款具有本研究自創的迴轉犁自動偵測功能。

CREATION AND RESEARCH OF ECOLOGICAL MATERIALS AS AN ALTERNATIVE TO SYNTHETIC POLYMERS

The research work is dedicated to analyzing the impact of disposable tableware and packages made from synthetic polymers on people and the environment, and the search for ecological alternatives to synthetic polymers used in their production. Various types of disposable tableware and packages, their composition, production technology, harmful effects on the human body, environmental pollution, processing and recycling were studied. The statistics of the use of disposable tableware and packages in Ukraine and the world as a whole, the places of their use were analyzed. Ecological alternatives to disposable tableware and packages made from various natural materials have been studied. A practical study of the use of organic waste and wastepaper for the production of ecological disposable dishes and packages was carried out.

探討實際執行、動作心像、動作觀察與鏡像動作時之腦部活化情形

本研究以功能性近紅外光頻譜儀,探討雙側主要運動皮質(M1)、前運動皮質(PMC)及聯合動作皮質(SMA)等動作相關腦區,以實際執行(ME)、動作心像(MI)、動作觀察(MO)及鏡像動作(MVF)等模式執行上肢功能性前伸動作(Arm reaching)時,腦部之活化情形。研究結果發現「實際執行」、「動作心像」與「鏡像動作」執行時,動作相關腦區皆顯著活化,包含M1、SMA及PMC。且可觀察到執行「動作心像」、「鏡像動作」時之大腦活化模式與「實際執行」呈現相同趨勢。此結果可應用於臨床復健訓練中,對於上肢偏癱患者(如中風患者),建議使用「鏡像動作」模式訓練,而對於雙側皆有動作障礙之患者(如頸部脊髓損傷),可使用「動作心像」作為替代治療。

塑膠發電– PLA降解之燃料電池研究

本實驗主要將PLA塑膠產品以水解降解、光降解方式形成小分子乳酸單體或其寡聚物,作為燃料電池之燃料,使其再循環產生能量,減少塑膠產品對環境之汙染。PLA降解之方法,可將PLA浸泡於低濃度氫氧化鈉溶液或照射UV光進行前處理再置入乙醇中,或直接放入高濃度氫氧化鈉中並加熱將其迅速降解,後者可於5分鐘內將市售PLA產品完全降解。以上述PLA降解溶液作為燃料電池之燃料,同時以自製氧氣供應裝置提供氧氣,作為電池兩極。電極為鍍鉑鎳鉻絲,電解液為0.7M氫氧化鈉溶液,電壓可達0.85V。PLA雖為生物可分解性塑膠,現今仍主要以燃燒方式處理,此迅速降解PLA之方法可解決目前使用後處理之困境。同時本實驗為首次利用乳酸作為化學燃料電池之燃料,並成功使其產生電力,此研究可提供PLA塑膠分解與利用之新思維。

EVALUATION OF THE SURFACE TENSIO, LARVICIDAL AND ANTIBACTERIAL ACTIVITY OF PLANT EXTRACTS FROM THE LEAF OF THE ARACA TO COMBAT THE PROLIFERATION OF THE Aedes aegypti MOSQUITO IN STILL WATER CONTAINERS

The Aedes aegypti mosquito is one of the main transmitters of viral diseases in countries close to the equator. This vector promotes a series of generalized endemics that are difficult to control and prevent in these regions. Furthermore, the presence of bacteria in the environment favors the proliferation of mosquito larvae, which increases the probability of Aedes aegypti reproductive success. The Araçzeiro (Psidium guineense Sw.) is a plant present throughout the Brazilian Atlantic Forest and has in its composition, especially in the leaves, several substances that can be used to solve problems. Thus, we sought to verify the activity of flavonoids and polyphenols in terms of their antibacterial potential and the performance of saponins in their larvicidal potential, as well as surfactant, in order to prevent the accommodation of the mosquito in the water at the time of egg deposition and larvae respiration. The saponins were extracted from the araçazeiro leaf using a hydroalcoholic solvent and the flavonoids/polyphenols using methanol, the latter being subsequently rotaevaporated to maintain the non-toxic nature of the extract. Through the aqueous extracts, the content of total saponins by UV-VIS spectrophotometry, surfactant activity, larvicidal activity and toxicity were determined. In relation to the ethanolic extracts, the content of polyphenols and total flavonoids by UV-VIS spectrophotometry and high performance liquid chromatography (HPLC), antibacterial activity and toxicity were determined. The results showed that the aqueous extract has a satisfactory amount of saponins, as well as a surfactant potential due to the formation of foam and larvicidal activity in the two highest concentrations of the extracts. Ethanol extracts showed phenolic acids, especially gallic and ellagic acid, and flavonoids, especially catechin and quercetin, and antibacterial activity in most of the worked concentrations. Both extracts (aqueous and ethanolic) showed a dominant nontoxic character, which favors their use without risk to the environment, having an alternative and sustainable potential for controlling the proliferation of the Aedes aegypti mosquito.

Application of Technical Analysis to the Stock Market

Money drives the world and in times of crisis, money is more important than ever. Most political, economic and, as we have seen recently, health crises are accompanied by pressure on the economy. With such pressure, ordinary citizens are worried about their money, which is at risk either from inflation or from an uncertain economic outlook. In such times, some people resort to appreciating their money by investing. It is wise investments that can protect savings from inflation, or at least mitigate the effects of inflation. Investing in the stock market is among the most popular ways of investing. During the global coronavirus crisis, the number of small investors more than doubled (Galik and Brody [2022]), and in 2021, Covid (new) investors accounted for 15 % of investors in the U.S. market (Schwab [2021]). It is this phenomenon that inspired the author to write this paper. Investing in the stock market is one of the riskiest forms of investment, which means that there is a high probability of losing the originally invested capital. Some companies that allow retail investors to invest state that more than 90 % of their users lose their capital when investing in the stock market. On the other hand, investing in the stock market has one of the greatest potentials for profit. In the case of a long-term investment in index funds, for example, an average annual appreciation of between 8 % and 12 % can be expected (the average appreciation of the S&P 500, the most famous US index). However, it is necessary to wait several years for stable results. To see appreciation in a long-term portfolio, it is recommended to wait at least 12 years. This is because if a recession or a simple market correction comes, said portfolio can lose up to 50 % of its value in a year. But as history shows, markets do rise over the long term, and that is what long-term investors bet on, waiting for their capital to appreciate over time. But the market does not grow all the time. The market often changes price trends, and in some rare cases a long-term trend can reverse for up to several tens of months. This phenomenon, volatility, is attempted to be exploited by so-called speculators. A speculator is an investor who sells and buys in short periods of time and thus speculates on price movements. The speculator therefore needs a way to determine the likely behaviour of the price in the foreseeable future in order to make their trades profitable. The two main ways of analysing price behaviour are fundamental and technical analysis. And since fundamental analysis incorporates a large amount of diverse information into its predictions, this paper concentrates on working with technical analysis.

選擇相對論-研究零元效應與需求強度關係

「零元效應」所指的是消費者面對同類性質之高低價兩商品,當低價商品從原價降至零元,而高價商品同時等量降價時,消費者對低價商品之偏好將顯著增加,並且因確定性效應、損失規避及稟賦效應造成。研究目的驗證零元效應的強度與成因,設計實驗零元效應於不同消費領域、族群是否皆成立;設計兩種商品,A為高品質高價位,B為低品質低價位,兩種定價情況,定價情況1,A商品為A元,B商品為B元,定價情況2,A商品為A-B元,B商品為B-B元(零元)。實驗結果使用Wilcoxon 等級和檢定,以需求光譜進行分析,並與 Dan Ariely (2007) 實驗結果進行比較,發現其差異不大;結果發現受試者身分不影響零元效應存在,除「必需品」外,其他品項皆存在零元效應,並且發現零元效應的強度受需求強度影響,若需求越強,零元效應將越弱。需求遂受試者環境影響改變,故不同國家將有不同結果。