磁性流體可調性折射率特性之研究與應用
磁性流體（magnetic fluids）是一種含有磁性奈米粒子的液體，當磁場外加於磁性流體時，流體中各磁性奈米粒子的磁矩會沿外加磁場方向排列，而導致粒子間相互吸引，形成較大的磁性叢集，即所謂的磁鍊。當外加磁場增強，該磁鍊數會變多，並使磁性流體的折射率產生變化。磁性流體的折射率變化會隨外加磁場之變大而增大。本研究除探討磁性流體折射率受外加磁場控制的變化情形及其物理原由外，並進一步運用此特性研發可調性光纖「光調制器」 ，以探討磁性流體可調性折射率應用在光電元件上的可行性。A magnetic fluid is one kind of colloids which contain magnetic nano-particles. Under an external magnetic field, the magnetic moment of nano-particles is aligned along the direction of the external magnetic field. This leads to the agglomeration of magnetic particles and to form magnetic clusters under an external magnetic field. With the formation of the magnetic clusters, the refractive index of magnetic fluid is varied. The refractive index of magnetic fluid was found to increase under a higher magnetic field. In this work, In addition to investigating in detail the behavior of the field-dependent refractive index of the magnetic fluid, we also explore the relevant physical origins. Furthermore, the feasibility of developing fiber-optical modulators by utilizing the tunable refractive index of magnetic fluids is discussed.
新竹北埔冷泉蝦子之研究
因特殊的地理關係而形成奇特之新竹北埔冷泉，其水溫長年偏低且水質特殊。本研究報告主要在探討生長於冷泉中的蝦子其所屬物種、生命力、生態及新竹科學園區所排放的廢水對其生存之影響等議題。為能獲得科學與客觀性的結果，我自己設計了實驗以及適當的實驗步驟來幫助我找到解答，這也讓我對問題有深入的瞭解。我發現這些黑殼沼蝦，螯足各節間有粗糙橙斑，可以耐7℃的低溫，靠嗅覺覓食，小蝦在前4 週呈快速的成長，污水中的蝦子短期內一定死亡，從基部斷肢才能有再生能力等結果。茲條列所探討的問題如下:1.探討北埔冷泉蝦的身體構造與其功能。2.了解北埔冷泉蝦和一般食用蝦身體構造的差異性。3.探討北埔冷泉蝦的生長環境與其行為之關係。4.探討北埔冷泉蝦的食性。5.探討北埔冷泉蝦的覓食行為。6.探討北埔冷泉蝦與養殖蝦存活率的差異性。7.探討北埔冷泉蝦與養殖蝦的耐溫能力。8.瞭解北埔冷泉蝦的雌、雄判定。9.探討北埔冷泉蝦交配與孵卵方式。10.探討北埔冷泉蝦小蝦的成長曲線。11.探討不同水質對北埔冷泉蝦的影響。12.探討北埔冷泉蝦斷肢後的再生現象。經由這次的研究，讓我對北埔冷泉蝦子的身體構造、生長環境、覓食行為、耐溫能力、交配與孵卵、小蝦的成長、斷肢後的再生、甚至水質對蝦子生存之影響等等已能深入瞭解。除此之外之外，更重要的是從疑問的產生，實驗方法與步驟的構思、做實驗的過程，及獲得可信的結果，再再使我深刻體會到科學精神的真諦。Bei-Pu cold spring of Hsinchu was formed due to the unique geographical feature. This paper investigates the species, livability, ecology and affection of water quality of the wildlife shrimps that live in this special environment. I design my own experiments and suitable procedures to help me to get the scientific and objective results. The research topics on Bei-Pu wildlife shrimps are listed below. 1. Body structure. 2. Distinguish bred and this wildlife shrimp. 3. Growth environments and its behavior. 4. Foods. 5. Hunting 6. Livability. 7. Tolerance of low temperate. 8. Male and female. 9. Mating and incubating. 10. Growth characteristics. 11. Affection of water quality. 12. Limbed and re-generation. These crayfishes can survive under 7℃. Hunting behavior is guided by olfaction other than vision. They grow rapidly in the first 4 weeks. Regeneration occurs only from the joint. Water quality is vital to them. From this study, I understood the species, hunting, mating, incubating, growth, temperature tolerance and regeneration of this wildlife shrimps. Moreover, I deeply appreciate what real scientific essence is through defining the questions, designing the experiments, procedures and obtaining the results finally.
探討聲致發光效應中，改變溫度，濃度，液體種類，頻率對氣泡發光的影響?
聲致發光效應(sonoluminesence)為最近二十年來相當新穎的研究領域，其基本原理是利用超聲波將水中的氣泡集中，並使之隨著超聲波快速且連續的膨脹壓縮，當氣泡被壓縮至最小時溫度急遽上升，並放出藍白色的光芒。正因為這是一個嶄新的領域，所以許多實驗是以嘗試錯誤的方法去進行，但也因此發現了一些特殊的現象：1. 氣泡在正常的頻率(30kHz)以外，經過一段不可發光的頻率後，還可在更高頻率(接近40kHz)的地方發光2. 氣泡發光效率曲線在不同性質溶液中的差異3. 針對高頻率發光及雙泡發光的部分，做了兩個相關的假設並進一步驗證，得到了相當特別的結論。至今已有許多關於此研究的成果發表，但對於同時兩顆氣泡存在並發光的雙泡發光現象(double-bubble sonoluminesence)卻還很少人研究。因此我們嘗試較系統化地分析雙泡發光，期望能夠對這個現象有進一步的認識，並對日後的多泡發光(muti-bubble sonoluninesence)研究奠定基礎。Sonoluminescence has been a very popular topic for the past twenty years. Single-bubble sonoluminescence occurs when an acoustically trapped and periodically driven gas bubble collapses so strongly that the energy focusing on collapse leads to light emission. Because it is a new topic, few related experiments on this issue have been carried out before. However, while doing the research and making adjustments at the same time we discovered some special phenomenon: 1. Besides the normal amplitude frequency (30kHz) added on the bubble, we found that after a period of frequency which can not emit, the bubble is able to remain and emit in higher amplitude frequency (about 40 kHz). 2. We also compared the emission efficiency when bubbles are in different liquids. 3. To explain part of the results in high frequency and double-bubble sonoluminescence, we made two assumptions and attempted to demonstrated them in the end of the report. Some research studies in this field have been released already; nevertheless, few people concentrate on “double-bubble sonoluminescence.” Therefore, we attempt to systematically analyze the emission of double-bubble, expecting to have more comprehension of this marvelous effect and also establish the fundamental background to “muti-bubble sonoluninescence.”
含環胺-亞胺雙牙配基及其鎳錯合物的合成、結構鑑定，及烯烴催化聚合反應
本研究合成含環形胺—亞胺雙牙配基鎳金屬催化劑，用以催化烯烴聚合反應。將2-甲基丙醛經由溴化、胺化及亞胺化的步驟合成含胺—亞胺的雙牙配基，Et2NCMe2CH=N(2,6-iPr2C6H3) (3a)、(c-C4H8)N- CMe2CH=NPh (3b)、RNCMe2CH=N(2,6-Me2C6H3) (R = c-C4H8 3c，c-C5H10 3d)。再將配基和Ni(DME)Br2 (DME = 1,2- 二甲烷氧基乙烷) 反應， 形成鎳金屬錯合物Ni [Et2NCMe2CH=N(2,6-iPr2C6H3)]Br2 (4a)、Ni[RNCMe2CH=N (2,6-Me2C6H3)]Br2 (R = c-C4H8 4c，c-C5H10 4d)，並作結構鑑定。其中3b、3c、3d、4c、4d 均為合成的新化合物，4d 獲得X 光單晶繞射結構。
以合成之鎳錯合物作為催化劑，催化乙烯或降冰片烯(C7H10)的聚合反應，探討反應活性和高分子產物的性質。與含相同碳數的錯合物比較，在胺基具環形取代基的錯合物對乙烯的催化活性較佳，聚乙烯產物分子量較高，分子量分布範圍狹窄；其對降冰片烯的催化活性略遜於非環形者。同為環形取代基時，六環較五環者對乙烯的催化活性較差，但對降冰片烯的催化活性較佳。顯示乙烯聚合與降冰片烯聚合有不同的反應決定步驟。催化劑及配基的設計的確可以操控聚合反應及其高分子產物的性質。
The synthesis of α-amino aldeimines Et2NCMe2CH=N(2,6-iPr2C6H3) (3a), (c-C4H8)NC Me2CH=NPh (3b), RNCMe2CH=N(2,6-Me2C6H3) (R = c-C4H8 3c，c-C5H10 3d), as well as the nickel complexes Ni [Et2NCMe2C- H=N(2,6-iPr2C6H3)]Br2 (4a), Ni[RNCMe2CH=N (2,6-Me2C6H3)]Br2 (R = c-C4H8 4c，c-C5H10 4d) has been succeeded. Their structures were mainly determi ned by spectroscopy or elemental analysis. The complex 4d was characterized by X-ray crysta llographic analysis. It shows that the nickel complex has distorted tetrahedral configuration.
The catalytic reactions of ethylene or norbornene polymerization using the newly synthesized nickel complexes are studied. All catalyts show high activity toward studied olefin polymerization. Comparing the data of the catalytic ethylene polymerization for complex 4c with those of its isomer complex 4a, the former is found to results in higher activity as well as the larger molecular weight of the PE products with the narrower dispersity. On the contrary, 4c shows lower activity in the reactions of norbornene polymerization than 4a. For the cyclic amine derivatives, 4c of five-membered amino group shows better catalytic activity toward ethylene polymerization than 4d of six-membered amino group. But 4d gives better perfomance for norbornene polymerization than 4c. Such results indicate that the processes of ethylene and norbornene polymerization might have different rate-determining steps. These study confirms that the design of ligand and catalyst are crucial with respect to the control of the catalytic olefin polymerization and the properties of the polymeric products.
記憶學習機
一般學生對於學校課程學習的負擔，再加上對本身的自信心不足，往往導致學生自己所「背」的東西不是十分確信是否有真正記進腦中，也常常困擾著他們。因此，引發本小組想設計一個可以自我評測且可以立即得到成績的輔助學習機;在研究過程中，本小組設計記憶學習機不但可以做到使用者自我評測的功能，還可以讓使用者馬上得到檢測的結果並且使用者可以回顧先前成績欄紀錄;記憶學習機經過本小組組員的辛苦孕育下誕生，本小組便拿著「它」讓班上同學認識，雖然「它」不是同學心中的最佳主角，但是同學卻一致認定「它」是『最佳伴讀夥伴』。本作品主要功能有:1．能調整使用者所要求的測試時問。2．該作品能記憶此次測試成績，以便和下次相互比較。3．依使用者的需求選擇中文、英文、數字及遊戲模式做記憶訓練。4．能有立即性的成效及回饋。 Due to the pressure of courses and lack of confidence, many students are often not sure of what they have recited on a lesson previously, which in turn always disturbs and cut down learning confidence of students. To eradicate the obstacles they encounter, we decide to research into this topic. A memory-based learning-aided machine is designed for students to self-evaluate themselves and to get the feedback at once. In the process of development, the memory-based learning-aided machine not only lets users practice the exercise of their own, but also is able to derive the outcomes immediately and retrieve the previous records effectively and efficiently. We strive to make this learning-aided machine at its best performance as possible as we can. Besides, the memory-based learning-aided machine provides the alternatives for the users to answer the question in a way that they like. For example, users can answer questions in English mode, can choose the limit time into test themselves in a time. In addition, the system can expand its material by inputting data into the knowledge base. By our group members' lasting efforts, the learning-aided machine was created, finally. According to the result of experiment that we applied to the classmates, we conclude that the memory-based learning-aided machine is the best assistant and learning partner for the students. We would like to introduce it to classmates and hope they will be interested in using it to enhance their learning motivation and performance.
姑婆芋的傳粉生物學
我們在校園內設置兩樣區，從2007 年4 月至2007年6月，共調查9株姑婆芋，93朵佛焰花，以瞭解姑婆芋生活史、傳粉昆蟲生活史及兩者之間的互動關係。 姑婆芋在11 月至7 月花期時會不斷產生佛焰花苞，剛冒出的花苞經過1到3天後，雌蕊漸成熟，佛焰苞會漸漸展開，開始產熱及一些特殊氣味，吸引果蠅科未知種的蠅類傳粉。當胚株受粉後，佛焰苞頸部會閉合，迫使傳粉昆蟲會往上爬到雄蕊部位攜帶花粉，飛至另一株姑婆芋雌蕊上傳粉，因此姑婆芋與傳粉昆蟲之間具有互利共生的關係。佛焰花序主要產生氣味的部位是在附屬物及雄部，而佛焰苞則可以幫助吸引更多傳粉昆蟲。佛焰花序的附屬物及雄部相對溫度較高，可能具有產熱以吸引傳粉昆蟲的功能。 ;Our study started from April, 2007 to June, 2007. We observed a total of 9 Alocasia odora and 93 spathes to help understand the life cycle of these understory clonal herbs, its pollinators, and the relationship between them. Alocasia odora produces spathes continuously during inflorescence. In the female phase, the pistillate part of the inflorescence ripens and an opening appears at the spathe, heat and a special odor is produced to attract pollinators of Drosophilidae. When the ovule is pollinated, the male phase begins and the opening encloses, which forces the pollinators upwards to the staminate part to carry its pollens, and then fly to an other Alocasia odora, Heat and the special odor are produced by the appendix and the staminate part of the inflorescence, and the spathe can increase the number of pollinators attracted. The relationship of mutualism between these two species contribute to the study of coevolution.