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環境工程

探討石油與細菌的故事—加「塑」分解

本研究想透過能分解石油的嗜油菌加速同為碳氫構成的塑膠分解。本實驗採用參雜一般塑膠的生物可分解塑膠片。從含有油污的土中經過DNA分離與純化後透過NCBI比對出主要菌種為Pseudomonas citronellolis和Achromobacter。菌種與經實驗室紫外光照射24小時的塑膠片反應時重量下降幅度最大,經約含7%紫外線的太陽光照射3天的塑膠片次之,無前處理的塑膠片最小。本實驗透過三種堆肥方式研究塑膠片分解的情形,在加入菌種和碳基生物復育劑的土中反應的塑膠片重量下降幅度最大,加入碳基生物復育劑的土中的塑膠片次之,加入自來水的最小。從塑膠片殘留重量比與實驗天數畫出的折線圖中可看出若維持經實驗室紫外燈照射24小時且在加入菌種和碳基生物復育劑的土內反應的塑膠片重量下降趨勢便能在883天後完全分解。此外,在探討不同酸鹼值的實驗中,可知pH10的分解最快,而含沙量實驗中則可得知含沙量0%對分解對有利。未來預計長期研究嗜油菌與一般塑膠的分解及不同有機質對塑膠分解的影響,期望解決塑膠過量的問題,使環境不受影響。

Anti-forma Chitogel

Formaldehyde is an air-borne, carcinogenic indoor pollutant. It may cause adverse effects on human health such as irritation of eyes and respiratory system. Shells of hermetia illucens, Black Soldier Flies (BSF) are leftovers when the insects mature from pupae to adults. BSF shells are rich in chitin which can be converted into chitosan by demineralisation and deacetylation. Chitosan and its ammonium salt (chitogel) can remove formaldehyde via condensation of water. In this investigation, the efficiency of removal of formaldehyde by different substrates were compared including shells of BSF before and after demineralization, deacetylation and action of vinegar; and common commercial products and Anti-Forma Chitogels made from shells of BSF and some crustaceans. Anti-Forma Chitogel of BSF was found to be effective in removing (91.2%) formaldehyde (1:20 by mass) among shells of BSF with different treatments and its efficiency was better than all commercial products tested. Concentration of formaldehyde in the container with deacetylated Anti-Forma Chitogel is 0.54 mg/m3. It removed 74.8% of formaldehyde compared to the control (2.14 mg/m3). Concentration of formaldehyde in the container with Anti-Forma Chitogel without deacetylation is 0.76 mg/m3 . It removed 64.5% of formaldehyde compared to the control (2.14 mg/m3). The Anti-forma Chitogel of BSF was found to be eco-friendly with high formaldehyde removal efficiency when placed in a drawer (removal of 54.8% of in 24 hours), the chamber of a newly renovated room (removal of 84.9% in 30 minutes reducing the conc. of formaldehyde from 0.53 mg/m3 to 0.08 mg/m3; cf. the safety limit of formaldehyde <0.125mg/m3) and drawers of a new wardrobe (removal of 83.7% at 20.2oC in 1 day reducing the conc. of formaldehyde from 0.49 mg/m3 to 0.08 mg/m3 & kept the conc. of drawers below 0.125mg/m3 most of the time over a month when temperature was below 21oC). Conc. of formaldehyde in air-tight boxes (5g of construction adhesive in 9.3 dm3) with air purifiers with and without Anti-forma Chitogel as filter before and after 3 hours was reduced by 44.5% (from 6.25mg/m3 to 3.47mg/m3 ) and 27.7% respectively showing that Anti-forma Chitogel as filter in air purifier outperformed that without by 160%. Besides, anti-forma Chitogel is antibacterial, so it would also kill bacteria when used in air purifiers. [1] proving that Anti-forma Chitogel is effective in removal of formaldehyde on the spot and can be applied to households. It can also help achieve Target 3.9 and 12.5 of the Sustainable Development Goals of the United Nations.

ReCiPla - Cyclic Soil Microplastic Remover

GROSSMANN, João Miguel Sastre. ReCiPla - Cyclic Soil Microplastic Remover: A way to remove microplastics from soil using electrostatics. 2023. 28 p. Research report – Scientific Apprentice Program, Colégio Dante Alighieri, São Paulo, 2023. Microplastics are the largest form of physical pollution on the planet. Affecting everything from terrestrial and aquatic environments to the air, compounds up to 1 micrometer in size are present inside the human body and can intoxicate the main organs in which they are found, such as the lungs, spleen, liver, and heart. Therefore, methods of removing these compounds from nature are essential, which is why this research is based on electrostatically removing MP from the soil. To this end, a vibrating conveyor belt was designed that would act in conjunction with a plate electrified by a Van de Graaff generator to separate the plastic compound using electric field induction. After characterization tests to quantify the voltage produced by the generator, which produced an average of 95 kV, the vibrating belt was made and will be used later in conjunction with the electrostatic method. This methodology suggests that it’s a success even after the electrified plate was applied to its structure. It carried out the proposed processes, such as moving the test masses, vibrating them, and fully supporting the electrified plate. In addition, the electrostatic removal method was tested to verify its efficiency and applicability. It was found that the removal of microplastics ranged it from 10 to 20% efficiency, suggesting it to be an effective method for separating microplastics. It should be noted that these statistics will be improved as the research progresses. In this way, the research proved capable of establishing an electrostatic removal method, as well as a process for transporting the material to be removed, thus achieving the objectives it set out to achieve. Finally, it should be noted that this research is still under development, with a view to applying the process in conjunction with the conveyor belt to carry out sample tests, as well as improving the removal process in the future to make it more efficient.

Design of a new Hydrogen Fueled Hybrid Car Prototype

The proposed project involves a new water-fueled hybrid car prototype that integrates various technologies, including photovoltaic (PV) panels, electrolysis, a fuel cell, a metal hydride tank, and a battery. The car is equipped with PV panels on its surface, such as the roof or hood, which convert solar energy into electricity. This electricity powers a DC motor that propels the vehicle. Excess electricity can be stored in a battery or used in an electrolysis system to split water into hydrogen and oxygen. The hydrogen is stored in a metal hydride tank for later use. Metal hydrides are materials capable of absorbing and releasing hydrogen gas, providing a safe and compact storage solution. The fuel cell converts hydrogen into electricity to power the DC motor when sunlight is not available. This hybrid system allows for direct solar-powered operation while also storing excess energy as hydrogen. Experimental tests were conducted on a prototype of this water-fueled car, with the fuel cell serving as a backup power source to ensure continuous operation even without solar energy. This concept offers several advantages, including the use of renewable solar energy, zero emissions during fuel cell operation, and the ability to store and utilize excess energy.

Silver nanoparticles-loaded titanium dioxide coating towards immobilized photocatalytic reactor for water decontamination and bacterial deactivation under natural sunlight irradiation

The environmental implications of rapid industrialization, including rising pollution, depleted resources, the effects of climate change brought on by global warming, and unrestrained groundwater extraction, are contributing to a growing water scarcity crisis [1-3]. The improvements in quality of life are largely attributable to the innovations in manufacturing technology made possible by the Industrial Revolution, but these innovations also pose risks to the natural world and human health [1-3]. The textile business uses a wide variety of raw materials, including natural fibers like cotton as well as synthetic and woolen fibers, and the chemical components of dyes are just one example. The annual output of synthetic dyes is around 700,000 tons, and there are over 10,000 different varieties available. As much as 200,000 tons of synthetic dyes are released into the environment every year due to the inefficient dyeing technique commonly employed in the textile industry. According to the World Bank, the processing of textiles for dyeing and finishing accounts for between 17 and 20 percent of industrial wastewater [1-3]. Textile wastewaters contain a high biological oxygen demand (BOD), chemical oxygen demand (COD), nitrogen, color, acidity, high suspended particles, high dissolved solids, surfactants, dyestuffs, heavy metals, and other soluble chemicals [3] due to the variety of dyes used to color textile items. In particular, water-soluble reactive and azo dyes are employed to obtain the required color. Ten to twenty percent of the dyes used end up in the effluents, where they might harm wildlife and the ecosystem (carcinogenic or mutagenic). Headaches, nausea, skin irritation, respiratory difficulties, and congenital deformities are only some of the health problems linked to exposure to textile wastewater. There are repercussions for aquatic ecology, environmental biodiversity, and the quality of receiving water bodies. New, low-cost, and highly effective water treatment methods are needed to deal with polluted wastewater. Adsorption and coagulation, two common water purification methods, just concentrate pollutants by shifting them to other phases; they do not "eliminate" or "destroy" them. Sedimentation, filtration, chemical oxidation, and biotechnology are all examples of conventional water treatment methods, but they all have their drawbacks. These include insufficient removal, high chemical reagent consumption, high treatment costs, long treatment times, and the creation of toxic secondary pollutants. New water treatment procedures are needed to improve the quality of treated effluent [1-3]. The use of semiconductor particles in photocatalysis is gaining appeal as a solution to global pollution problems due to its shown efficiency in degrading a wide variety of contaminants. Photocatalyst-coated surfaces-based reactors have proven to be practical for long-term operation over photocatalytic powder-based reactors (i.e., slurry-based reactors) [4-5]. As a promising photo-electrode and photocatalyst, titanium dioxide (TiO2) has enjoyed wider applicability in photocatalytic hydrogen generation, solar cells, and remediation of organic contaminants among other photo-catalytic applications [4-6]. TiO2 has been recognized as one of the low-cost, most effective, and fascinating photo-catalyst as a result of its interesting thermal and chemical stability, desirable electronic features, others, and environmental benignity [6-8]. Pristine TiO2 semiconductor is characterized by a wide band gap that can only utilize the UV part of the light spectrum with a wavelength of less than 385 nm, which is just 5% of the sunlight energy capacity. Spectrum usability extension to visible regions warrants further and extensive research study [8-10]. Additionally, the quickness of the recombination of photo-generated holes and electrons further restricts the practical applicability of the semiconductor [10-12]. It is highly desirable to develop a cost-effective scalable strategy to over these drawbacks toward sustainable development and a clean environment using only natural sunlight irradiation [5-11]. In addition, it is preferred to fabricate them as films rather than powders as photocatalytic immobilized reactors are more practical than powder-based reactors [4-8]. Dye sensitization, supports, magnetic separation, and surface modification by doping with non-metals, metals, and transition metals and coupling with other semiconductors have all been used to enhance the photocatalytic activity of TiO2 photocatalyst. Higher photonic efficiency can be attained through the synergistic fine-tuning of features such as physical, chemical, and electronic, and these composites and hybrid materials based on TiO2 are creating a big trend. Doping has been widely studied as a means of altering the surface of TiO2. Rare earth metals, noble metals, and transition metals are all discussed in the existing literature on the surface modification of TiO2 doped with cations [4-12]. In this study, for the first time, Ag nanoparticles loaded mesoporous TiO2 coating was prepared and applied as an immobilized photocatalytic reactor for water decontamination and bacterial deactivation under natural sunlight irradiation.

快速合成金屬有機骨架複合材料用於微量工業廢氣吸附移除Rapid synthesis of metal-organic framework composites for removal of trace industrial waste gases

本研究開發一種新穎孔洞性吸附材料:金屬有機骨架 (MOF)。MOF 在反應溶液中自組裝形成孔洞結構,透過物理吸附有效捕捉氣相乙酸分子。研發出綠色、快速可在常溫常壓下大量合成三種MOF(HKUST-1(Cu)、UTSA-280(Ca) 及 A520(Al))方法。此外,為提升材料機械強度和應用價值,採用 PVA 聚合技術製備 MOF 複合物,使其造粒型化更易處理,提升商業和環境應用價值。吸附實驗結果顯示,HKUST-1(Cu) 粉末對乙酸移除率高達98%,而HKUST-1(Cu) PVA 複合物達93%,對比活性碳及其PVA複合物(移除率分別為85%和78%)表現更優異。MOF憑藉優異吸附性能和可大量生產低成本優勢,成為極具潛力有機無機氣體吸附劑,可為半導體產業提供一種維持高標準製程環境精密且簡便解決方案。

Upcycling of Abandoned Beehives!!

Upcycling abandoned beehives to make new products can reuse the useful materials in old beehives and produce less trash. As known that bees leave their beehive in these following situations like insufficient replenishment, frequent unboxing and environmental issues. Then the beehive will be abandoned and will have no use left. In this project, a piece of honeycomb was collected from abandoned beehive and melted in order to extract beeswax. The potential of the extracted beeswax for replacing plastic to produce fillers of 3D pens was studied. Natural materials like seashell, rosin, soy bean and coffee ground were tested as ingredients of 3D printing materials. Finally, the potential of using extracted beeswax in 3D printing was confirmed. Beeswax has a low melting point at around 64°C and solidify quickly at room temperature. The high plasticity of this natural wax fulfills the criteria of 3D printing materials. Biodegradable wastes, like coffee grounds and soy bean grounds were tested as additives for reducing the beeswax content. Sea shell grounds were eliminated from the tested list as its filaments broke into small pieces of brittle fragments during the production process. 5% and 10% of these additives were the optimal formula for making long filaments. Yet, the thin filaments made by pure beeswax were not strong enough, filaments of selected beeswax-soy bean grounds were further strengthened by mixing with 5% or 10% rosin. Among the four different ratios of Beeswax: Soy bean grounds: Rosin (9:1:0.5 / 9:1:1 / 9.5:0.5:0.5 / 9.5:0.5:1), filaments in the ratio 9.5:0.5:0.5 demonstrated better flexibility, higher tensile strength and compressive strength, thus B9.5:S0.5:R0.5 was the final formula of biodegradable beeswax 3D filament.

Development of Oil Collecting Submarine using AI and hydrophobic solution

Such as the plastic waste and industrial discharge that permeate our oceans, it is the insidious and infamous nature of oil spills that demands our immediate attention. These spills, with their far-reaching ecological ramifications, pose a profound danger to our marine ecosystems, demanding urgent action and a heightened awareness of the true menace that is caused by this oil

奈米 MPC 材料應用於電阻式有機氣體感測器

工業環境中揮發性有機化合物(VOCs)的洩漏不僅危害人體健康,更可能導致工安事故。現有氣體感測器常存在選擇性低、反應時間長等限制。本研究開發高選擇性與快速反應的奈米材料導電式氣體感測器,以實現即時監測。 研究中合成並測試六種銀奈米 (Ag-MPC)材料:Ag@C6、Ag@C12、Ag@C16、Ag@MCP、Ag@C12/MCP及Ag@C12/MBT複合材料。在500-5000 ppm濃度範圍內偵測1-丁醇、正辛烷及間二甲苯等目標氣體的電阻變化。實驗結果顯示,Ag@C12經官能基修飾後,對1-丁醇具有明顯的選擇性。我們開發基於Arduino微控制器的即時監測系統,透過運算放大器電路實現高精度的電阻變化檢測。可以在工業環境中持續監測VOCs濃度並即時示警。未來將著重於優化訊號放大電路、開發新型官能基修飾材料、實現複雜氣體混合物的組分分析。開發成本低、反應快、選擇性好的感測系統,為工業安全監測領域提供實際應用價值。

雙酚 A 對白線斑蚊幼蟲生長發育的影響及病媒蚊防治策略探究

登革熱病媒蚊幼蟲主要孳生於人工積水容器中,幼蟲生長發育主要受到溫度與食物的影響。本研究至戶外調查人工積水容器,發現塑膠類人工容器為主要孳生類型。於實驗室以 11 種人工容器培養白線斑蚊幼蟲,結果發現塑膠底盆的幼蟲發育速度較快,蚊蟲平均翅長較長。以塑膠組成物質雙酚 A 進行試驗, 發現高濃度 (>50 mg/L) 雙酚 A 會導致幼蟲死亡, 活動力降低; 中濃度(12.5~1.56 mg/L) 會促進幼蟲生長速率,縮短發育時間;低濃度 (<0.78 mg/L) 則不顯著。以濃 6.25mg/L 雙酚A 處理蚊幼蟲,Q-PCR 顯示四個齡期的幼蟲蛻皮激素基因 (Ecr) 分別表現量都有增加,其中四齡幼蟲增加 9.68 倍,蛋白質分析顯示 34~72 kDa 之間的片段濃度增加。在蚊幼蟲防治上,4.0 %蛋胺酸和 1.0% 硼酸皆可 100%抑制孑孓活性,結合低濃度蛋胺酸(0.13%)和硼酸(< 0.5% )可以提升 30% 抑制孑孓活性的功效。