全國中小學科展

環境工程

蚊蟲翅音的定性與防治應用

為隔離環境聲音增加蚊蟲專一性的聲音,自行製作降噪錄音箱,分析聲譜使用Audacity及Room EQ Wizard兩個軟體,結果顯示自製錄音箱可吸收95.7%的環境聲音能量。白線斑蚊的雄蚊平衡棍長與翅音統計達顯著相關;而雌蚊平衡棍長與翅長統計達顯著相關。白線斑蚊及埃及斑蚊兩者翅音皆具有專一性,同種雄蚊及雌蚊會受彼此翅音誘引,而雌蚊交尾後會被同種交尾雌蚊翅音誘引。雌性埃及斑蚊交尾後的翅音對同種雌蚊平均誘引產卵率為85.8%,統計達顯著差異。自製捕蚊機(合成翅音誘捕,平均誘捕率為66.7%)較市售捕蚊機(UV光誘捕,平均誘捕率49.7%)誘捕率高出17.0%。自製捕蚊機可做為白線斑蚊及埃及斑蚊防治資材之一,且為環境友善防治法。

「硫」不住的「紅」塵── 探討二硫化錫降解羅丹明之研究

本研究將不同比例的硫.與二氯化錫,在固定溫度200℃、加熱時間9小時,所合成出的壓電材料SnS2用來降解羅丹明染料,實驗結果發現以莫耳比1:4為最佳,降解率可達到96%。接著固定莫耳比1:4及溫度200℃下,發現在不同水熱時間時以水熱九小時的SnS2觸媒降解效果最好。最後本實驗以固定比1:4及水熱時間9小時在不同水熱溫度所合成的SnS2觸媒,以水熱溫度200℃時的降解效率最好,可達到96%。接著我們將最佳合成條件的觸媒對不同濃度的羅丹明進行降解,可發現當羅丹明濃度達到50ppm時,只需要2秒降解率即可達到99%,即使濃度達到70ppm時濃度降解效果仍可達到86%。最後對SnS.觸媒進行SEM分析發現顆粒大小為微米等級,而在PL分析發現本觸媒具有活性的能力且符合實驗結果。

Design of a new Hydrogen Fueled Hybrid Car Prototype

The proposed project involves a new water-fueled hybrid car prototype that integrates various technologies, including photovoltaic (PV) panels, electrolysis, a fuel cell, a metal hydride tank, and a battery. The car is equipped with PV panels on its surface, such as the roof or hood, which convert solar energy into electricity. This electricity powers a DC motor that propels the vehicle. Excess electricity can be stored in a battery or used in an electrolysis system to split water into hydrogen and oxygen. The hydrogen is stored in a metal hydride tank for later use. Metal hydrides are materials capable of absorbing and releasing hydrogen gas, providing a safe and compact storage solution. The fuel cell converts hydrogen into electricity to power the DC motor when sunlight is not available. This hybrid system allows for direct solar-powered operation while also storing excess energy as hydrogen. Experimental tests were conducted on a prototype of this water-fueled car, with the fuel cell serving as a backup power source to ensure continuous operation even without solar energy. This concept offers several advantages, including the use of renewable solar energy, zero emissions during fuel cell operation, and the ability to store and utilize excess energy.

Silver nanoparticles-loaded titanium dioxide coating towards immobilized photocatalytic reactor for water decontamination and bacterial deactivation under natural sunlight irradiation

The environmental implications of rapid industrialization, including rising pollution, depleted resources, the effects of climate change brought on by global warming, and unrestrained groundwater extraction, are contributing to a growing water scarcity crisis [1-3]. The improvements in quality of life are largely attributable to the innovations in manufacturing technology made possible by the Industrial Revolution, but these innovations also pose risks to the natural world and human health [1-3]. The textile business uses a wide variety of raw materials, including natural fibers like cotton as well as synthetic and woolen fibers, and the chemical components of dyes are just one example. The annual output of synthetic dyes is around 700,000 tons, and there are over 10,000 different varieties available. As much as 200,000 tons of synthetic dyes are released into the environment every year due to the inefficient dyeing technique commonly employed in the textile industry. According to the World Bank, the processing of textiles for dyeing and finishing accounts for between 17 and 20 percent of industrial wastewater [1-3]. Textile wastewaters contain a high biological oxygen demand (BOD), chemical oxygen demand (COD), nitrogen, color, acidity, high suspended particles, high dissolved solids, surfactants, dyestuffs, heavy metals, and other soluble chemicals [3] due to the variety of dyes used to color textile items. In particular, water-soluble reactive and azo dyes are employed to obtain the required color. Ten to twenty percent of the dyes used end up in the effluents, where they might harm wildlife and the ecosystem (carcinogenic or mutagenic). Headaches, nausea, skin irritation, respiratory difficulties, and congenital deformities are only some of the health problems linked to exposure to textile wastewater. There are repercussions for aquatic ecology, environmental biodiversity, and the quality of receiving water bodies. New, low-cost, and highly effective water treatment methods are needed to deal with polluted wastewater. Adsorption and coagulation, two common water purification methods, just concentrate pollutants by shifting them to other phases; they do not "eliminate" or "destroy" them. Sedimentation, filtration, chemical oxidation, and biotechnology are all examples of conventional water treatment methods, but they all have their drawbacks. These include insufficient removal, high chemical reagent consumption, high treatment costs, long treatment times, and the creation of toxic secondary pollutants. New water treatment procedures are needed to improve the quality of treated effluent [1-3]. The use of semiconductor particles in photocatalysis is gaining appeal as a solution to global pollution problems due to its shown efficiency in degrading a wide variety of contaminants. Photocatalyst-coated surfaces-based reactors have proven to be practical for long-term operation over photocatalytic powder-based reactors (i.e., slurry-based reactors) [4-5]. As a promising photo-electrode and photocatalyst, titanium dioxide (TiO2) has enjoyed wider applicability in photocatalytic hydrogen generation, solar cells, and remediation of organic contaminants among other photo-catalytic applications [4-6]. TiO2 has been recognized as one of the low-cost, most effective, and fascinating photo-catalyst as a result of its interesting thermal and chemical stability, desirable electronic features, others, and environmental benignity [6-8]. Pristine TiO2 semiconductor is characterized by a wide band gap that can only utilize the UV part of the light spectrum with a wavelength of less than 385 nm, which is just 5% of the sunlight energy capacity. Spectrum usability extension to visible regions warrants further and extensive research study [8-10]. Additionally, the quickness of the recombination of photo-generated holes and electrons further restricts the practical applicability of the semiconductor [10-12]. It is highly desirable to develop a cost-effective scalable strategy to over these drawbacks toward sustainable development and a clean environment using only natural sunlight irradiation [5-11]. In addition, it is preferred to fabricate them as films rather than powders as photocatalytic immobilized reactors are more practical than powder-based reactors [4-8]. Dye sensitization, supports, magnetic separation, and surface modification by doping with non-metals, metals, and transition metals and coupling with other semiconductors have all been used to enhance the photocatalytic activity of TiO2 photocatalyst. Higher photonic efficiency can be attained through the synergistic fine-tuning of features such as physical, chemical, and electronic, and these composites and hybrid materials based on TiO2 are creating a big trend. Doping has been widely studied as a means of altering the surface of TiO2. Rare earth metals, noble metals, and transition metals are all discussed in the existing literature on the surface modification of TiO2 doped with cations [4-12]. In this study, for the first time, Ag nanoparticles loaded mesoporous TiO2 coating was prepared and applied as an immobilized photocatalytic reactor for water decontamination and bacterial deactivation under natural sunlight irradiation.

開發共聚凝膠應用於金屬離子之富集吸附與回收

水凝膠被廣泛應用於生醫材料方面,其特性可用來吸收大量溶劑、生物流體,或是吸附水樣中的物質,其中應用於吸附金屬離子以淨水為最具發展潛力。本計畫將N-異丙基丙烯醯胺與幾丁聚醣反應形成共聚物NIPAAm-g-chitosan水凝膠,此合成水凝膠具有 生物可降解性、溫度敏感性,探討不同嫁接程度之共聚物對金屬離子之吸附效率。目前研究從FTIR確認已成功合成出NIPAAm-g-chitosan水凝膠,且膨潤率可高達約900%。此NC水凝膠比幾丁聚醣更具廣泛的pH溶脹範圍,且在150℃高溫下不會熱裂解,顯示其穩定性佳。對於金屬離子的吸附,NC水凝膠的吸附率皆較幾丁聚醣 為佳,對於鈷離子的吸附率更可高達75%,應用在工業廢水的檢測會是一大效益。

「稻」出「鋁」想「充」能力

本研究利用農業廢棄物再加工後的-炭化稻殼,經食用醋處理後搭配環保防水明膠配方製成碳紙電極,作為可充式鋁電池的正極材料;負極則是在鋁箔上塗一層較環保無毒的PVA;電解液使用2M氯化鋁/0.1M食鹽水/5g醋酸鈉,吸附在濾紙上,成功製作出可充式「炭化稻殼紙/鋁電池」,充放電循環3次後,放電的初始開路電壓最高可達1.296V,初始短路電流可達137.1mA,串聯兩個電池後,成功使LED燈發光持續至少72天,亦可推動風扇在約4mA的工作電流下維持215分鐘。本作品多使用食品級的環保材料,較以往作品具有低汙染、低成本、超輕薄、可充電、可彎曲等多項優勢,充電後的穩定性更優於市售石墨片電極,可連續充放電至少5次,在進行穿刺實驗後更證實其安全性較鋰電池高,期待能為大型儲能系統添加一股永續環保的新契機。

Experimental Study on Optimal CADR Filter Thickness of Air Purifiers

美國環保署指出美國民眾 90%的時間待在室內,人們常用空氣清淨機改善不良的室內空氣品質,所以空氣清淨機效能對於健康影響至關重要。市面空氣清淨機常宣稱使用 HEPA濾材,但其厚度未必是理想的乾淨空氣輸送率(CADR)。目前僅有最佳CADR濾材厚度的理論,尚未有實驗資料佐證。本研究以實驗方式研析濾材厚度與最佳 CADR 厚度之關係。實驗使用自製空氣清淨機含離心風扇和不同厚度之濾材,測試四種濾材品牌及四種風扇功率,以 SMPS 測量上游及下游顆粒濃度來判定過濾效率,用單通法計算 CADR。結果顯示,隨著濾材厚度增加過濾效率與CADR 提升,但超過最佳濾材厚度後,厚度增加反而造成 CADR 降低。最佳 CADR 濾材厚度約出現在 0.1 微米顆粒有約 20-40%過濾效率時。若以最易穿透粒徑為參考點,則過濾效率約在 10- 30%。欲發揮空氣清淨機最大效益並延長使用期限,濾材厚度應約略小於最佳 CADR 濾材厚度。

開發共聚凝膠應用於金屬離子之富集吸附與回收

水凝膠被廣泛應用於生醫材料方面,其特性可用來吸收大量溶劑、生物流體,或是吸附水樣中的物質,其中應用於吸附金屬離子以淨水為最具發展潛力。本計畫將N-異丙基丙烯醯胺與幾丁聚醣反應形成共聚物NIPAAm-g-chitosan水凝膠,此合成水凝膠具有 生物可降解性、溫度敏感性,探討不同嫁接程度之共聚物對金屬離子之吸附效率。目前研究從FTIR確認已成功合成出NIPAAm-g-chitosan水凝膠,且膨潤率可高達約900%。此NC水凝膠比幾丁聚醣更具廣泛的pH溶脹範圍,且在150℃高溫下不會熱裂解,顯示其穩定性佳。對於金屬離子的吸附,NC水凝膠的吸附率皆較幾丁聚醣 為佳,對於鈷離子的吸附率更可高達75%,應用在工業廢水的檢測會是一大效益。

禽畜糞堆肥除臭與氨氣資源化

禽畜糞堆肥常伴隨氨氣排放而有異味問題。目前成本低、培養易的木黴菌已廣泛用在堆肥中來加速發酵。此外,部分業者會將含氨臭的氣體蒐集再以稀硫酸水洗,產物硫酸銨可作為氮肥,但多被排棄。本研究結合木黴菌添加與排氣稀硫酸水洗,可縮短堆肥期程,更將氨氣肥料化,以 (1)木黴菌合適添加劑量、(2)稀硫酸水洗參數等二項為試驗主軸。結果顯示:(1)添加2/100木黴菌可使堆肥成品中總氮增加13%,減少氨排放;(2)含氨排氣經pH6-7稀硫酸水洗,98%的氨氣轉化成含約1,400mg/L之硫酸銨溶液,氮含量為300mg/L,相當於沼渣沼液農地施灌水準。

以水代法將廢棄鰻魚骨製成營養食品添加物的永續解方

本研究採用創新設計的「水代法」處理養殖鰻魚加工後廢棄魚骨,成功解決過往鰻魚骨含油量高,無法利用而丟棄的環保問題,使生物資源得到充分利用。透過「低溫烘乾前處理」製成的鰻魚骨粉香氣與口感俱佳,適合作為食品添加物。 水代法是將鰻魚骨在90℃水溫、粉水比1:3狀態,藉由攪拌、壓榨去油,不僅保留營養成分(蛋白質、鈣質、磷質),同時降低高達90%的脂肪含量。水代產生的處理液可進一步開發為胺基酸萃取物和鰻魚油,創造多元的商業價值。「食鹽水浸泡處理」取代較不環保的「強鹼處理」製作鰻骨鈣粉,可有效減少環境負擔。本研究製程簡便且低耗能、低耗水,可降低成本,顯著提升產業競爭力和環境效益。