全國中小學科展

2025年

法拉第波輔助合成奈米鎳並應用於有機污染物的快速脫色 Nanostructured Nickel Synthesized through Faraday Waves and Its Application to Rapid Contaminants Decolorization

超音波已廣泛用於奈米粒子的製備,然可聽聞音對奈米粒子製備的影響卻少有研究。本研究以簡易喇叭裝置產生可聽聞音並在溶液表面產生法拉第波及內部流動,來輔助製備奈米鎳。法拉第波是一種表面非線性駐波,透過調整容器形狀、振動頻率等,可產生不同波形。本研究嘗試在法拉第波輔助下,以化學還原法及電沉積法製備出不同性質的奈米粒子。SEM量測並比較無輔助、法拉第波輔助、超音波輔助製備出的奈米鎳的形貌、分布的差異。並將其應用於有機物(即剛果紅、亞甲藍、4-硝基苯酚、2-硝基苯酚)之催化還原。而由SEM量測、催化還原結果及理論模擬反應熱可知,法拉第波確實能夠改善奈米鎳的粒徑大小、分散性、對氫的吸附能力及催化還原能力。

探討年齡影響急性腎損傷的潛在機制

在現代社會高齡化的趨勢下,老化與衰弱成為引人注目的社會問題,近期也被認為是造成死亡的主要原因。本研究探討了不同年齡小鼠腎臟功能及分子機制的變化。結果顯示,老化小鼠腎絲球過濾率較差,腎損傷指標NGAL和KIM-1增加,顯示老化影響腎功能。此外,老化小鼠的抗氧化能力下降,CHOP蛋白顯著上升,顯示內質網壓力增加。急性腎損傷實驗進一步發現,老化小鼠的腎功能下降及組織損傷較年輕小鼠嚴重,且脂質代謝及粒線體生合成指標呈下降趨勢。這些變化是否由於適應性未折疊蛋白XBP1表現下降造成,仍須更進一步研究釐清。總結,本研究探討年輕與老化小鼠腎臟之分子機轉差異,有助於深入了解老化對腎臟功能的影響和造成急性腎損傷與衰弱症之關鍵因素。

在量子電腦上模擬量子諧振子隨時間演化

量子電腦是近年來新發展的科技,利用量子糾纏態的量子位元進行計算。本文希望可以利用量子電腦計算諧振子隨時間演化算符。而這也是我第一次在量子電腦上模擬諧振子隨時間演化系統。首先我找出可以用於諧振子算符的合適算符矩陣大小、空間步長(Δ𝑥)、質量(m)、角頻率(ω)並且在位置基底下表現時間演化算符矩陣。設計並簡化量子電路後,使用IBM公司提供的量子電腦模擬並計算數值。我透過矩陣修正減少修正輸出錯誤產生的誤差,達到較精確的結果。模擬出在一個時間單位內的數值與理論值大致相符,未來希望可以利用此量子電路尋找矩陣的特徵值或是模擬更大型的系統。

ZIFs與釩氧化物作為鋅電池陰極材料之應用與性能研究

本研究旨在優化鋅離子電池陰極材料的性能,選用沸石咪唑酯骨架材料(ZIFs)與釩氧化物(V6O13)進行複合材料的合成與應用。隨著鋰電池成本的上升,鋅離子電池因其安全性與成本效益逐漸受到重視。ZIFs 具有高比表面積及良好的離子導電性,而V6O13則因多價態和優良導電性而成為潛力材料。通過結合這兩種材料,我們開發了具有多孔結構和優異穩定性的複合陰極材料,再使用 PXRD、SEM 及 EDX 對材料進行結構表徵,並使用此新材料製作鋅離子電池進行電化學性能測試。結果顯示,熱裂解後的 PY-VxOy@ZIF-Zn/Co具有最佳的克容量及穩定性,且在500次循環後保持良好的穩定性。本研究展示了ZIFs和V6O13結合在鋅離子電池中的應用潛力,為低成本、高效能的儲能解決方案提供了新的方向。

Tlaolli Onilli

Most people in the country tend to consume soda as part of their daily lives, without thinking about the health consequences that this entails. And the fact is that 墨西哥 is considered the main consumer of soda in the world (Universidad Nacional Autónoma de México [UNAM], 2019), and not only that, it also tops the lists of obesity and diabetes (Procuraduría Federal del Consumidor [PROFECO], 2018). A bad diet is one of the main causes of these medical conditions, so it is necessary to rethink the foods of daily consumption. In this project, the development of a carbonated beverage with three main ingredients: purple corn, hibiscus, and pineapple, which contain diverse nutritional properties in addition to having significant amounts of antioxidants (Secretaría de Cultura,2020; Sumaya et al., 2014; Kongsuwan et al., 2009), is established as an objective. In addition, antioxidants act as regulators of cellular aging and prevent chronic diseases (Vilaplana, 2007). For this reason, the elaboration of a beverage with these characteristics is considered harmless and a good option for people with a chronic disease or who are prone to it, as well as a healthy alternative to the consumption of soft drinks. In this project, an experimental methodology was followed to prepare the nutritional beverage, which had nutritional properties, such as vitamin and antioxidant content, in addition to having a pleasant taste and texture.

運用機器學習強化探測重力波訊號

本研究欲利用機器學習演算法,透過觀察重力波訊號來判斷黑洞融合訊號的時間。本研究 的數據來源於雷射干涉引力波天文台的開放資料庫,我從中獲取最被廣為認定的64筆原始數據,並生成具有不同黑洞質量與不同訊噪比的模擬信號。我將模擬信號與不同噪聲混合 後,進行強度調整、Q轉換和資料白化等數據處理,並提取資料的統計量,將其用於訓練三種決策樹演算法和兩種迴歸演算法中。最終研究結果顯示,決策樹演算法的判斷能力優於迴歸演算法,以及指出強度差值的標準差是最關鍵的特徵,重要性達全體特徵的27%。 我們的模型在重力波訊號判斷上表現出較高的效率,並成功降低了模型的複雜度,使其更適合實際應用。

Natural resources utilization for the in-house production of fluorescence lipid nanoparticles

Nanotechnology, a transformative force, has steadily gained traction across multiple scientific disciplines, including physics, chemistry, engineering, and biology. It offers unprecedented capabilities, especially in the realm of nanoscale particles, ushering in new paradigms in various applications. One of the most revolutionary applications of nanotechnology is in the pharmaceutical sector. Here, nanoparticles have transformed drug and vaccine delivery systems, offering both efficacy and precision. Among these nanoparticles, lipid nanoparticles (LNPs) have stood out, especially for their role in delivering nucleic acid-based drugs and vaccines. These LNPs are intricate assemblies composed of lipids and nucleic acid complexes, offering an amalgamation of stability and deliverability. Such properties have rendered LNPs as invaluable tools in enhancing therapeutic efficacy while minimizing off-target side effects. The myriad of nanoparticles available includes the likes of silver, gold, and lipid nanoparticles. However, the emphasis of this research lies with lipid nanoparticles, given their widespread success in the pharmaceutical arena. LNPs have showcased their potential in delivering drugs with low therapeutic indices, emphasizing their capability to act as versatile platforms for novel drug development. Recent advances have further expanded the horizons of LNPs, paving the way for novel antisense oligonucleotides, innovative vaccines, and complex lipid nanoparticle formations. Characterizing these nanoparticles is paramount, not only for the development of novel drugs but also to comprehend their in vivo behavior. Their multifaceted nature, stemming from their unique excipients, core-bilayer design, and varying sizes, makes their characterization a critical step in the research and development pipeline.

Eradicating Cystic Fibrosis Biofilms by a Novel Non-Toxic, Multi-Pathway Salicylate Therapy

1.1. Cystic Fibrosis Biofilms Biofilms are bacterial aggregates in a matrix of polysaccharides, proteins and nucleic acids (Donlan, 2002). They account for 80% of all chronic infections and cause over 500,000 deaths annually. Cystic fibrosis (CF) is a genetic disorder characterized by mucus accumulation in the respiratory tracts (Morrison et al., 2020). This impairs mucociliary clearance, allowing chronic colonization by bacterial biofilms, leading to fatal respiratory failure, lung scarring, and necrosis of pulmonary epithelial tissues (Martin et al., 2021). 1.2. Obstacles in Current Treatments Three major therapies are used against CF biofilms: (1) aminoglycoside antibiotics like tobramycin, (2)non-aminoglycoside antibiotics such as ciprofloxacin and vancomycin, and (3) non-antibiotic therapies including flushing, chlorination, and ultraviolet disinfection. These have two major flaws. First, they are cytotoxic; 30% of patients experience acute kidney injury after three days of intravenous aminoglycoside therapy (Joyce et al., 2017). Furthermore, non-aminoglycoside therapies can cause phospholipid buildup in lysosomes of proximal tubule epithelial cells, accounting for 10-20% of acute renal failure cases. Second, antibiotic resistance due to horizontal gene transfer and mutations has significantly reduced treatment effectiveness. Therefore, cystic fibrosis biofilms remain a critical threat with few effective treatments. 1.3. Salicylate Derivatives This project tackled this issue using an innovative non-antibiotic approach with salicylate derivatives. Salicylates, a class of benzoic acids—benzene-based carboxylic acids (Figure 1)—used in painkillers and blood thinners, were investigated for their antibiofilm potential through a 3-step process: 1. Literature review: Identified three key biofilm therapeutic targets: quorum sensing, bacterial adhesion, and cell motility. Disrupting these pathways would result in biofilm eradication. 2. Molecule Identification: Recognized key molecules in each pathway: LasR, adhesins, and flagellin. Inhibiting these molecules would disrupt the pathways. 3. Screening: Found that salicylates could inhibit the identified molecules, though they had never been tested against cystic fibrosis biofilms.

塗色次數期望值之研究

n個圓圈以一維排列所構成圖形中,若指定當中一圓圈塗色時,其左右相鄰圓圈各有1/2機率被塗色,欲求出使得該圖形之指定塗色次數的期望值達最小之最優化塗色方法。本研究共探討了n個圓圈之「直線排列」、「環狀排列」與n個圓圈及m個圓圈之「環狀結合直線排列」等三種圖形。

「稻」出「鋁」想「充」能力

本研究利用農業廢棄物再加工後的-炭化稻殼,經食用醋處理後搭配環保防水明膠配方製成碳紙電極,作為可充式鋁電池的正極材料;負極則是在鋁箔上塗一層較環保無毒的PVA;電解液使用2M氯化鋁/0.1M食鹽水/5g醋酸鈉,吸附在濾紙上,成功製作出可充式「炭化稻殼紙/鋁電池」,充放電循環3次後,放電的初始開路電壓最高可達1.296V,初始短路電流可達137.1mA,串聯兩個電池後,成功使LED燈發光持續至少72天,亦可推動風扇在約4mA的工作電流下維持215分鐘。本作品多使用食品級的環保材料,較以往作品具有低汙染、低成本、超輕薄、可充電、可彎曲等多項優勢,充電後的穩定性更優於市售石墨片電極,可連續充放電至少5次,在進行穿刺實驗後更證實其安全性較鋰電池高,期待能為大型儲能系統添加一股永續環保的新契機。