全國中小學科展

2021年

以空氣盒子探討台灣環境中懸浮微粒的潮解膨脹現象

我們的研究是利用空氣盒子設計出一個裝置,用以觀察環境中懸浮微粒潮解膨脹現象。 我們觀察了由硝酸銨與硫酸銨各自以及不同比例與混合模式組成的懸浮微粒。純硝酸銨的潮解點不明顯,純硫酸銨有明顯的潮解點。內混合懸浮微粒有一個潮解點,並且出現3種類型的潮解行為,分別是偏向硝酸銨或硫酸銨以及過渡型,後者粒徑成長的比例會比前兩者來得高。外混合懸浮微粒有兩個潮解點,保留兩種成分各自的特性。 我們利用雨水觀察環境中懸浮微粒的潮解膨脹現象,將其與內混合懸浮微粒的潮解點與潮解行為做比較,來推估其成分與來源。確定我們的裝置能推估出主要的污染成分及來源。

「馬道」成功

象棋的馬與西洋棋的騎士走法有異曲同工之妙且棋子的走法似乎有些特殊的規律,兩者的走法我們稱為同構,因此我們針對這個現象進行研究。 (圖一) 馬步與騎士 我們得到下面四個結論: 一、定理甲:動點P可經由馬步從原點(0,0)走到棋盤上的任意格子點。 二、定理乙:平面棋盤的馬步路徑皆可找到起點、終點在同一象限(含軸),且步數相同的路徑。 三、定理丙:每一個最少步數K≥5,K所對應的總格子數f(K),數列為公差7的等差數列。 四、定理丁:給定第一象限(含軸)任意點P(X,Y),可求得最少步數K。

AGRIBOT – ROBOTIC SOLUTION TO FOOD SUSTAINABILITY

Food sustainability is key to human survival. Robotic solutions have started playing large roles in automating farming tasks in order to assist with crop yield and the efficiency of production. Due to the unreliability of and lack of manual labour in many parts of the world, Agribots are playing bigger roles. One of the biggest advantages of Agribots is that they can operate 24/7, 365 days a year without payment. Agribots are being used more often in dairy farms to milk cows while others are used to shear sheep. Agribots are fast becoming very important to farmers by gathering valuable data; milking cows; automating animal feed; measuring the right amount of pest control, detecting weeds and pests, harvesting and ploughing with unmanned tractors. In many parts of the world farm labour is scarce and difficult to come by. In 南非 for example farm labourers endure gruesome attacks. These attacks on farmers result in the closure of the farm for an extended period of time resulting in the loss of large quantities of crops. Food sustainability is dire in Africa and many parts of the world. “Each day, 25,000 people, including more than 10,000 children, die from hunger and related causes. Some 854 million people worldwide are estimated to be undernourished, and high food prices may drive another 100 million into poverty and hunger. . 90 percent of the world’s farms produce over 80 percent of the world’s food. They also manage about 75 percent of farmland worldwide. Yet, paradoxically, these farmers are often poor and food insecure themselves. Due to the increase in the world’s population annually, there is a growing demand for food. This has led to increasing pressure on farmers to produce crops. In order to meet this demand, farming innovations are vital for the future of food and agriculture. Constant innovations in agriculture is thus needed to constantly feed a growing and increasing population. Innovation in agriculture is also critical to help farmers use resources in better and more efficient ways. “Innovation is one of our best tools for creating a #ZeroHunger world.

THE DESIGN OF MICROFLUIDIC PUMP (MFP) FOR MEDICAL FIELD

The ability of microfluidic (MF) device technologies to provide a lot of information with a small amount of sample, the opportunities it offers increases their use in the medical field in the bedside monitoring in drug delivery systems. Three-dimensional (3D) printer technologies provide advantages such as cost-effectiveness in the production of MF devices and quick and easy production in intricate designs. In our project, it is aimed to design microfluidic pumps (MFP) to be used in the medical field and conduct its production with 3D printer technologies. The developed MFP is intended to be at low cost, bio-compatible, adaptable, and portable to the drug, suitable flow properties as a pharmaceutical pump. First of all, MFP air channel, flow channel, etc. parts were designed and printed with the help of a 3D printer and on AutoCAD, one of the professional drawing programs. The poly(dimethylsiloxane) (PDMS) membrane that will enable MFP activation is produced in different thicknesses and glued to the air channel of MFP. The resistance to the applied pressure is observed, and the appropriate membrane thickness is determined as ~ 235µm. Liquid PDMS was applied to the inner surfaces of MFP's air and flow channel, PDMS membrane was placed between them, and the parts were assembled in the oven at 60ºC. MFP has been connected to the pneumatic valve system, where operation codes have been prepared with Arduino Uno, and flow properties have been examined. The flow rate of MFP is ~ 50 µL/min at a maximum of 15 Hz, and the backpressure is ~ 0.085 Pa under a maximum pressure of 3 bar. Also, values such as size, membrane thickness, and applied pressure for the possible models of MFP were supported by theoretical calculations. As a result, MFP, which is biocompatible, drug adaptable, portable, wearable technology application potential, and has suitable flow characteristics as a pharmaceutical pump, has been developed. MFP introduced a microfluidic pump system that can make life easier for the patient and contribute to the national economy through domestic production and can be used as a drug pump in the treatment of diseases such as diabetes and cancer.

臺南市違停的離散小波與ARIMA分析

現今逐漸有許多科學家研究出一些能夠進行預測事件的方法,諸如天氣預報、價格變化的幅度等等。在眾多生活常見的問題中,我們選定違規停車為例,作為研究主題,而我們推測違規停車是一種具有週期性的問題,有多樣的潛在變因存在,於是我們跳脫以往多以心理層面、法規制度與地理熱點等的視角去看待違規停車,以資訊科學及數學的方法,建立一套分析的模式加以進行研究。 本文以連續小波變換CWT、最大重複離散小波轉換MODWT、差分整合移動平均自迴歸模型ARIMA、混合MODWT+ARIMA模型及混合Harr離散小波變換DWT+ARIMA模型,對臺南市三個不同特性的行政里的共五個聚類點,進行預測。原始的資料以週為單位,分成全日(allDay,0~24時)及白天(Day, 08~16時)兩種型態,並以連續46週的資料預測接下來4週。結果採用方均根誤差RMSE相對平均值、標準差、最大值的比值,進行預測品質的比較。

囊中之物~探討台灣藜抗鹽耐旱的可能原因及囊狀細胞角色

台灣藜為原生種作物,本實驗探討其抗逆的可能原因,並發現囊狀細胞的不同功能。台灣藜種子發芽率與幼苗生長,隨鹽度及乾旱程度上升,受到很大抑制;發展至第一對葉,台灣藜才展現較好抗逆能力。不論子葉或第一對葉,鹽度越高或越乾旱,花青素與類黃酮含量均較高。但POD與CAT活性,子葉時活性變化不大;生長至第一對葉時,POD在2%鹽處理組及乾旱w40%組,活性分別上升10.8及3.6倍,而CAT在2%鹽處理組及乾旱w40%組,活性上升5.2及3.8倍,酵素活性上升的結果與抗逆關鍵時期相符。刷除囊狀細胞後,發現台灣藜在鹽逆境下生長較差;2%鹽處理後,刷除囊狀細胞的葉片,其CAT活性下降約64%。收集囊狀細胞,進行CAT活性分析,囊狀細胞組及其去除活性組(加入去除CAT活性的Stop solution),兩者間的OD值相差達7.9倍。顯示台灣藜的囊狀細胞不僅有儲鹽的能力,還具有抗氧化酵素協助抗逆。

同「鋅」協力 —— 以醇解法探討金屬鋅催化解聚 PET之反應

聚對苯二甲酸乙二酯 (PET) 是一種常見的合成高分子材料,其被應用的範圍相當廣泛,如產品包裝、手提袋等,然而隨著人類的過度使用,越來越多的 PET 產品被發現有回收不當的現象。 文獻指出,醇解法為一具有反應條件簡單、反應過程溫和及較不會產生多餘副產物的解聚 PET 方法,且醇解法能使用非均相觸媒,具有易於分離觸媒的優勢,具工業化潛力。本研究嘗試利用廢電池中的鋅作為催化劑用以解聚 PET 成單體對苯二甲酸乙二酯(BHET),並深入討論影響反應進行的因素與發展應用。利用廢電池中的鋅作為催化劑不但成本低廉,也更能符合本研究的核心「綠色化學」。 本研究已透過最適化條件搜尋,發現能在催化劑使用量為 0.2 克、反應時間 4 小時、反應溫度 180 度時,解聚 5 克的 PET,有最佳效果之 BHET 產率 75.8% 和 PET 轉化率 93.2%。根據最適化反應條件,並比較不同種的鋅化合物做為催化劑,發現廢電池中的鋅作為催化劑催化反應,具有較佳的轉化率與產率。

以奈米錫奈米銦增益小分子團水製備及促進藥物傳輸效能探討

小分子團水(water cluster)的製備及應用一直是科學界的挑戰。本實驗利用熱蒸鍍法,加熱金屬塊材成原子蒸氣,在氬氣環境配合液態氮溫度下冷凝收集,成功製備了平均粒徑10nm金、20nm銀、54nm銦、71nm錫、14nm鎳奈米顆粒。將定量的奈米顆粒滲入去離子水中,以超聲波分散顆粒團聚,再以波長530奈米的綠光照射,讀取拉曼散射譜圖,判定來自小分子團水的振盪強度,探討5種奈米顆粒對形成小分子團水的功效。我們驚訝的發現奈米銦藉表面電漿共振(surface plasma resonance)及表面電子氧化還原功效,弱化水分子團簇成大分子團的功效為奈米金的16倍,奈米錫為12倍,也均高效於奈米銀及奈米鎳。以奈米銦及奈米錫增益小分子團水後,對將癌細胞藥物、養分帶入細胞的功效明顯提升。

Hydrogen Functionalization of Graphene using RF Plasma for photodetection

The growth of the internet is propelling an ever-increasing need for faster communication. Modern telecommunication data is mainly carried through fibre-optic cables, with pulses of light representing bits of data; the main factor limiting data transfer speed is the rate at which the optical receiver at the opposite end of the cable can detect light pulses. Graphene-silicon Schottky photodiodes are a promising alternative to traditionally-used germanium photodiodes, promising higher detection frequency and better contrast between light and dark. To make it less susceptible to erroneous measurements due to graphene having a low band gap, hydrogen functionalisation was used to increase the barrier potential of the Schottky diode so that a higher voltage would be required to allow current to pass through in forward voltage bias and trigger the sensor. This study seeks to determine the optimal conditions — of physical proximity, duration of exposure, and plasma power — for hydrogen functionalisation using radio frequency plasma. Graphene was synthesised using low pressure chemical vapour deposition, then transferred onto P-type silicon to create a photodiode. The graphene-silicon photodiode was then doped with hydrogen plasma to introduce defects in the graphene layer to increase the barrier potential of the photodiode. To assess the effectiveness of hydrogen functionalisation, photocurrent measurements were conducted while light was shone onto the photodiode in pulses of increasing frequency to find the magnitude and spontaneity of the response. Light was shone in pulses of 100ms, and was successfully detected by the photodiode. The pulse spacings were gradually decreased and it was found that the diode was able to detect pulse spacings as low as 1µs, significantly better than germanium photodetectors. The sample demonstrated clear optoelectronic response and was sensitive to changes in frequency. Results show that the intensity of the optoelectronic response in graphene-silicon diodes is inversely related to its physical proximity to the plasma source during hydrogen functionalization; and directly related to the power of the plasma and to the duration of exposure up to a point, after which it will deteriorate. Thus, it can be concluded that graphene-silicon Schottky diodes offer much promise in electronic communication.

THE BLIND'S SHINE

Nowadays, all blind people are able to read any type of text thanks to The Braille system, which is a system of reading by touch. The Braille system provides a good and important help to blind people but it’s not enough. They try to integrate into society, try to read and write the same as those blessed with sight. However, only 18% of people can actually write in Braille and doing so takes a lot of effort. While Braille techniques have existed for many years now, there isn’t one that takes advantage of the comfort and easiness of modern technology. To be fair and give more chances to the blind people, and with all the available technologies nowadays, we must find solutions and innovative ideas to fulfill this objective. And this is how our project was born. To be honest, it’s not just a project, for us it’s a dream. Our focus in this project is creating an automatic machine based on transforming our language to their language and transforming this new invention to assist the blind in writing whole texts through speaking. It will be easier than the traditional way. This part of the project will help us print Braille on paper automatically in the cheapest, fastest and easiest way, unlike the traditional method that not only takes a lot of time but also needs a professional. Our printer will only cost approximately 250$ compared to regular printers that cost 6500$! the principles of the code of the speech recognition are voice pickup in all languages as first step, second speech recognition, then speech translation, after that speech analysis and finally translation into Braille and printing it. As for the future, we will work on face, object and image recognition as a scanner to make the visually impaired people read the name of the object and recognize people’s faces like anyone else.