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臺灣

低溫二次燃料電池

本實驗係以台灣常見之數種植物(甘蔗、橡膠、破布子、苦苓)乾餾所成之多孔性碳棒鍍上銅和拷上Chitin 為電極兼電容,而以NaOH(aq)為電解液,製成化學電池。希望能研究出一低污染、低成本、能在常溫下經濟運作、並具有教學演示功能之電池。This research is based on the poromeric carbons which are made of several Taiwanese common plants (including: sugarcane, babul, Sabastan Plum Cordia [Cordia dichotoma Forst] , and Chinaberry tree [Melia azedadach L.]) by means of destructive distillation. The copperplating poromeric carbons later covered with Chitin functions as an electrode ac well as capacitance. Along with NaOH(aq) eletrolyte, a accumulator is then produced. The chief objective of this research is to produce a accumulator with low class of pollution and low cost, which is able to function economically under the normal atmospheric temperature. Also,this accumulator can serve as a teaching demonstration.

正多邊形三角剖分的探討

給定正n邊形,於內部區域新增對角線,使得對角線不交叉且內部區域皆為三角形,則將此圖形稱為正n邊形的一個『三角剖分』。考慮正n邊形的所有三角剖分,已知其數量為卡特蘭數Catalan(n-2)。在所有三角剖分的情形中,考慮旋轉與翻轉,將同構的情形視為相同,則將所有不同構的三角剖分總數記為Dn。本文對於正n邊形的不同構三角剖分進行研究,以三種面向進行探討,首先我們以不同構三角剖分的對稱性分類,發現其和化學式CnHn+2的同分異構物有相關性;再者,以相鄰三角形的最大數量進行分類,當相鄰三角形的最大數量為n-2、n-3、n-4與n-5時,得出不同構三角剖分的計算通式;最後,以三個相鄰頂點組成的外圍三角形進行分類,將『恰包含兩個外圍三角形的不同構三角剖分』、『圖論中的毛毛蟲圖(Caterpillar)』以及『化學結構相關的Losanitsch’s triangle』進行深入探討。

重複圖形

「重複圖形」是本篇報告研究的問題,我們利用「方程式」建立一個尋找重複圖形,並証明其個數的方法。利用此方法得出下面的結論:1.會形成lap 2 的凸多邊形只有2 種,即三角形和四邊形。(1)「lap 2 三角形」只有1 種,即等腰直角三角形。(2)「lap 2 四邊形」只有1 種,即二邊之比為1: 且內角是45°、135°的平行四邊形。2.會形成lap 3 的凸多邊形只有2 種,即三角形和四邊形。(1)「lap 3 三角形」只有1 種,即內角為30°–60°–90°的直角三角形。3.其他的lap k 三角形:(1)任意內角為30°–60°–90°的直角三角形都是lap 3k²,其中k是正整數。(2)邊長比為1:m: 的直角三角形是lap (m²+1)k²三角形,其中m、k是正整數。 To find repeated figures, we construct a method to search them with the help of algebraic equations. Here we arrive at:1. There are only two kinds of lap 2 convex polygons, triangles and quadrilaterals. (1) The only lap 2 triangle is isogonal right-angled. (2) The only lap 2 quadrilateral is the one that contains angles 45°, 90° and two neighboring sides with the ratio 1: . 2. There are also two kinds of lap 3 convex polygons, triangles and quadrilaterals. (1) The only lap 3 triangle is the one with angles 30°, 60° and 90°. 3. Other kinds of lap k triangles are listed as following: (1) A triangle with angles 30o, 60°, 90° is a lap 3k², the k is a natural number. (2) A right-angled triangle whose ratio is 1 : m : is a lap (m2+1)k², the m and the k are natural numbers.

評估不同有機酸用於燃料電池之可行性

本研究主要著重在以三極式電化學測試探討不同有機酸燃料甲酸、草酸、檸檬酸與不同觸媒Pt/C、PtRu/C、PtPd/C 在陽極電極的氧化反應之研究。從CV 圖可得知,分子量較低的甲酸有較低的氧化電位。以CV 與LSV 圖可知,以較高的氧化電流區分,是以PtRu/C 為三種觸媒中最適合當陽極電極的;若以穩定度區分,則以PtPd/C 為最佳。我們挑選PtRu/C 此觸媒進行燃料電池放電性能測試,得到的電流不高,原因在於配置的甲酸溶液為1M,甲酸在PtRu/C 電極反應太快,質傳推動力不足,使得燃料供應不足,造成電位迅速下降。This main target of this study is using three-electrode cells to choose which Formic Acid, Oxalic Acid or Citric Acid and Pt/C, PtRu/C or PtPd/C are better for fuel cell. From CV test, Formic acid which structure is simple has the lowest oxidation potential. Combine CV with LSV, if we focus on current, PtRu/C is the best catalyst for fuel cell. But if we focus on Stability, PtPd/C has the best of them. We choose PtRu/C to do the cell performance test. The current density isn’t enough high, this is because the concentration of formic acid is just 1M. Oxidation reaction of formic acid on PtRu/C is very fast. Mass transfer driving isn’t enough for this high reaction rate, so the potential drop is very fast.

變色螢光之研究

目前市面上可以轉換顏色的物品大多可是經由物理變化所控制的,而以化學發光的產品,往往都只能有單一顏色,例如螢光棒,當它被製造出來時,就註定了本身就帶某種顏色,難道光的顏色無法經由某些特殊反應讓其在不同顏色間轉換嗎 ?

海鱺血清濃度對海鱺鰭細胞成長的影響

本文以動物細胞培養方法探討培養基中添加海鱺血清(CS)來培養海鱺鰭細胞株(CF-2)的可行性。發現CF-2單層細胞培養在L15-10/0 (L15 添加10% FBS)、L15-5/5 (L15添加5%FBS及5%CS)、L15-2.5/7.5、L15-0/0、L15-0/1.25、L15-0/2.5、L15-0/5、L15-0/10及L15-0/20等培養基6天後,其細胞數分別為最初的4.16、10.8、12、0.97、4.9、5.64、8.14、11.36及9.72倍。細胞接種於L15-0/0、L15-0/1、L15-0/2、L15-0/4、L15-0/8及L15-0/16等培養基24小時後,其附著率則分別為23.1%、96.9%、94.8%、93%、84.5%及39.5%。 CF-2繼代後直接培養在28℃,L15-0/2培養基中,細胞附著及成長良好,5-6天後再以1對2進行繼代。目前已在L15-0/2培養基中培養12代以上,命名為CF-2cs。在1%-16%海鱺血清濃度下,其增殖能力隨濃度增加而增加。培養在pH 7.6、pH 7.3、 pH7.0及pH 6. 7 的L15-0/2培養基中發現pH7.0為其生長最適酸鹼度。CF-2cs對嘉蠟魚虹彩病毒(RSIV),文蛤呼腸病毒(HCRV)及淋巴囊腫瘤病毒(LCDV)等三種魚類病毒具有感受性。以90%L15-0/2及10%DMSO超低溫冷凍保存CF-2cs,解凍後細胞附著及生長良好並在2-3天後長成單層。此外,L15-0/2也可直接用來培養RGB及RSS兩種源自於玳瑁石斑及銀紋笛鯛的初代細胞。這些結果顯示海鱺血清可完全取代胎牛血清來培養魚類細胞。

台灣不同世代A 群鏈球菌對紅徽素抗藥性之研究

A total of 64 nonduplicate isolates of erythromycin-resistant (MIC, >1 μg/ml) Streptococcus pyogenes collected from 1979 to 2003 in Taiwan were evaluated. They were collected from three cohort period: 1979 –1989, 1990-1999 and after 2000. The in vitro activities of 10 antimicrobial agents were determined by the agar dilution method. Penicillin, cephalothin, cefotaxime, vancomycin, and ofloxacin were shown to be active against S. pyogenes isolates (100% sensitive). Erythromycin and azithromycin both had poor activities (MIC50s, 16 and >128 μg/ml, respectively; MIC90s, >512 and >128 μg/ml, respectively). The activities of tetracycline, clindamycin, and chloramphenicol against a significant number of these isolates were also limited. Among the 64 S. pyogenes isolates, 58% had constitutive resistance [cMLS], 40% had an M phenotype and 2% had an iMLS phenotype (inducible resistance [iMLS]). A substantial upsurge in the incidence of M phenotype erythromycin-resistant isolates was found with time for S. pyogenes (10% in 1979–1989, 48% in 1990–1999 and 65% after 2000). The erythromycin resistance genes in 64 isolates of the different cohorts were investigated by PCR. All cMLS phenotype isolates tested had ermB gene. The M phenotype isolates had only the macrolide efflux (mefA) gene. This study shows the secular changes of increasing susceptibility of S. pyogenes isolates to both erythromycin and clindamycin in Taiwan. The mechanisms of erythromycin resistance have changed from the predominance of ermB gene (cMLS) to mefA gene (M phenotype). 本研究是探討台灣自1970 年代末期以來不同世代A群鏈球菌菌株對紅黴素的抗藥性及抗藥基因特徵的演變。研究者收集台灣二十年前(1980 年代前後,第一世代)、十年前(1990 年代,第二世代)、)及最近(2000 年以後,第三世代)之A 群鏈球菌菌株共64 株,利用抗生素圖譜和雙藥錠擴散測試及聚合?連鎖反應(PCR)、和脈衝式膠體電泳研究A 群鏈球菌對紅黴素抗藥性的表現型及基因型特徵。結果發現第一世代的A 群鏈球菌對紅黴素最小抑菌濃度(MIC)值相當高,幾乎都是>512 μg/ml,90%為多重抗藥菌株。第二世代則相對有降低,在第三世代此現象更明顯,多重抗藥菌株為30%。在雙藥錠擴散測試結果,從第一世代來看cMLS 佔大多數(90%),M 型佔10%;第二世代cMLS 及M 型相當分別佔52%及48%;第三世代主要為M 型佔65%,cMLS 佔30%,iMLS 佔5%。利用PCR研究紅黴素抗藥性基因發現所有cMLS 菌株皆有ermB 基因,所有M 型菌株皆有mefA 基因,iMLS 菌株則有ermTR 基因。由本研究顯示在台灣A 群鏈球菌對紅黴素之抗藥性隨著不同世代有逐年改善之趨勢,由MIC50的降低可看出,菌株對紅黴素的敏感性提高,可為臨床治療之參考。

來去自如的氣體分子─氣體穿過氣泡的行為研究

男人夢想的小老婆~探討水火箭車發射動力之研究

本研究利用回收寶特瓶、廢棄CD及重複使用的鐵條設計好玩的水火箭車,藉由高壓氣體將水推出瓶外,形成水火箭車行駛的的動力,從實驗中找出空氣與水的比例、打氣壓力、輪胎寬度、大小與胎紋(摩擦力)……等對車子行駛的影響,探究能讓車子行駛最平穩、快速的最佳條件。研究結果發現:水量在350cc、空氣壓力120psi,水火箭車具有較大的動能;輪胎CD片數愈多、輪胎直徑愈大及止滑膠帶材質(摩擦力愈大),皆會影響車子行駛的路徑及穩定性。 為了符合水火箭車創意設計競賽,從最佳行駛條件中去設計多款節能環保的創意水火箭車,經過不斷創作與改良,終於創作出一款符合競賽規則、節能環保的水動力概念車,也激發了另一個研究靈感,是這次科展最大的收穫。

天空之城耐震設計與隔震技術之探討

我們的研究包括兩部份,第一部份是實地調查訪問。瞭解地震成因、傷害及現有防震方法,並調查坊間各種建築物類型,及常見私自改變建築物結構現象,做為研究的基礎。第二部份為建築物抗震實驗。研究發現:牆面挖空、頂樓加蓋、樓層挑高,建築物會在該處產生弱點,由此斷裂。柱子數量相同下,散開時支撐力較弱。不對稱建築物遇震時會不自然扭轉且易倒。隔震素材恰當,能有效提高耐震力。滑軌、彈珠隔震效果很好,但位移太大,為實際建築所不容許。建物下加裝阻尼材料,能吸收部份地震能量,降低地震對建築物的危害,並有效控制位移問題,是良好的隔震素材。樓頂加裝消能設施亦能減震,但設計極其不易。 The research includes two parts. In the first part the work is concentrated on on-site visiting and investigation such as understanding the cause of earthquake, the damage and the preventive method currently available, investigating the different types of building and the phenomenon of altering the structure of an existing building without permission by government authorities which is popularly seen in Taiwan. These are considered as the basis of the research. The second part is the experimental study of earthquake resistance of a building. The test results showed that weak-point can be caused at the place where the existing wall is moved or an extra building is attached to the roof or the structure of building has extended space between floors, and fracture always occurs at the weak-point. If the number of columns of a building is the same, then the scattering arranged location of columns is weaker than concentrating type of arrangement of columns. The building having unsymmetrical structure will twist in uneven fashion that causes the building apt to collapse in case of earthquake. Employing proper vibration-absorption material can effectively increase earthquake resistance. Sliding rails and balls can provide satisfiable vibration-isolation effect, but can also cause too much displacement of building structure. Install damping material beneath the building can absorb part of the energy of earthquake, and decrease the damage, and can solve the problem of displacement of building, therefore, damping material can be considered as an ideal vibration-isolation material. Install energy-attenuation equipment can also reduce vibration but the design of the equipment is extremely difficult.