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臺灣

IF鋼在不同酸液中腐蝕行為之探討

IF鋼在鹽酸溶液中之腐蝕速度隨鹽酸濃度之增加而增加。12M之硝酸溶液對IF鋼具最強腐蝕性,而最低(0.1M)及最高(16M)濃度之硝酸溶液對IF鋼之腐蝕性則相對較弱。硫酸對IF鋼之腐蝕速度則由低濃度至高濃度呈現極大變化,當硫酸濃度由0.1M漸增至3M時腐蝕速度亦隨之增加,爾後腐蝕速率減小,至硫酸濃度由8M時反而呈現極大之重量增加。由於表面腐蝕層不適於XRD分析,故由EDS結合FTIR分析得知H?SO?/8M-24hrs.情況下試片表面之腐蝕層為Fe?O?。由SEM觀察發現腐蝕速率較大之條件,如HCI/12M-1min.及HNO?/12M-1min.處理過後,試片表面甚至出現具晶體對稱性之蝕恐。由本研究之初步成果發現:是溫下可以利用中等濃度(如8M)之硫酸液來處理鋼鐵,使之表面生成一緻密之氧化鐵(Fe?O?),達到防蝕之效果。IF (interstitials free) steel was processed in various aqueous acid solutions to observe the corrosion behavior. The corrosion rate of IF steel in HCI(aq) increases with the concentration of HCI(aq). HNO?(aq) with concentration of 12M was observed to be the most aggressive for IF steel. The corrosion rate of IF steel in H?SO? solution increases from 0.1M to 3M and then decreases gradually with the concentration. A large amount of weight gain even observed when the concentration was 8M. The protective layer produced during H?SO?/8M-24hurs. treatment was analyzed to be Fe?O? by using SEM (Scanning Electron Microscope), EDS (Energy Dispersive Spectroscopy) and FTIR (Fourier Transform infrared). Etch pits with crystallographic symmetry were observed on the specimens treated with conditions HCI/12M-imin. and HNO?/12M-1min. Processing condition H?SO?/8M-24hrs. could be employed in corrosion prevention for IF steel under ambient environment.

螺旋狀剝皮對樹木影響之初步研究

本研究的目的在於探討螺旋狀剝皮對植物生存以及芭樂果實的影響。實驗的設計是將選擇的植株或其枝幹分成四組,分別施予環狀剝皮、螺旋狀剝皮一圈、螺旋狀剝皮三圈及不剝皮等處理。 研究結果顯示,螺旋狀剝皮不會導致植株死亡,且於處理部位下方會長出新的枝葉。芭樂果實經100 天的生長之後,不剝皮處理之枝幹長出的芭樂重量都在 300g 以下,而螺旋狀剝皮一圈之枝幹長出的芭樂有重達300-400g(5%)及 400-500g(5%),最重的達 490g;螺旋狀剝皮三圈之枝幹長出的芭樂也有重達 300-400g(占 7.7%)。此外,與不剝皮處理者比較之,螺旋狀剝皮也有助於高甜度芭樂比例的提升。 本研究成果若能成功應用在其他果樹上,有助於提高果農產收的經濟價值。 The purpose of our study is to examine spiral bark-stripping’s effects on trees, and observe what will happen with this treatment, especially in the survival of trees and fruit of Guava. The experimental design is as below. First, we divided tree samples or branches into 4 groups randomly, and then treated each group differently with girdling, spiral bark-stripping a circle, spiral bark-stripping 3 circles, or non-stripping on the trunks or branches. As a result, spiral bark-stripping did not cause death of trees. Instead, new green leaves grew below treated area. After 100 days of growth, the fruit of Guava treated with non-stripping weighed below 300 grams, while some fruit weighing above 300-400 grams(5%) and 400-500 grams(5%) grew on those trees treated with spiral bark-stripping a circle, with the heaviest of 490 grams. Besides, there are some fruit weighing 300-400 grams(7.7%) growing on those trees treated with piral bark-stripping 3 circles. The result shows that spiral bark-stripping, compared to non-stripping, promoted the proportion of high-sugar fruit. This study provides a possible way to increase the economic value of fruit harvest if applied to other kinds of fruit trees.

小魚接招--不同因子對朱文錦環境偏好的影響

This research analyzes goldfish’ (Carassius auratus) environmental preference behavior by setting up different environmental color-models to spur goldfish’reactions. It is investigated that pre-conditioned preference of goldfish was stressed by electric shock or high osmotic pressure. We’re interested in how stress experience modulate goldfish’ exploring behavior and its environmental preference. Goldfish that prefers brown-colored environment (compared with white) is suitable for being an model animal to investigate fish’s environmental preference. Both electric shocks and high osmotic pressure, two different kinds of stress, can affect goldfish’ behavior. It shows that fish have the ability to learn and memorize the stress experience. Besides, different stress has different effects on fish’ environmental preference behavior. It proves that there are complicated interactions among environmental stimulus, memories of stress and behavior caused by different kinds of stress.本研究利用環境色彩特徵的差異,建立朱文錦(Carassius auratus)環境偏好行為之動物模式,探討不同逆境刺激經驗(施予電擊或高滲透壓環境),與魚類環境偏好行為的交互作用,以研究魚類的逆境經驗,是否可形成記憶,並影響其行為。我們發現朱文錦偏好土色環境(相對於白色環境),適合作為探討魚類對環境偏好的實驗動物。電擊與高滲透壓兩種不同性質的逆境經驗,皆可影響朱文錦的環境偏好,顯示魚類具有記憶逆境環境的學習能力。此外,不同性質的逆境經驗,對魚類的環境偏好行為具有不同的影響。證明「環境刺激—經驗(記憶)—行為表現」三者之間具複雜的交互作用。

共點圓、共圓點

我的研究是利用一些特殊的手法來探討所有情況皆會產生共點圓或共圓點。在一個由四條直線(無平行線組、無共點)所構成的圖形中,可以找到四個三角形及它們的外接圓。我知道它會共點,在此稱其為限制點。且若再添加一條直線,則可以任意的取出四條直線,分別找出它的限制點,而這些限制點又會共圓,吾稱其為限制圓。我欲證明此種情況會不斷延續下去。即是六條線時又會有限制點,七條線時又會有限制圓…。在本研究中,我利用了數學歸納法、特殊的編號方法以及「方向角」來做出此證明。由於固定的線組對應至固定的限制點或限制圓,希望能向找出其性質的方向發展。In my study, I use some skills to discuss all the situations which satisfy following conditions. The result is that concurrent circles or concyclic points will be found in every situation. In a graph consisting of four lines, conforming to conditions that any three lines won’t be parallel or intersect at one point, I can find out four triangles and their circumscribed circles. I know these circumscribed circles will be concurrent and I call the point at which all the circles meet “restricted point”. If another line is additionally added in the graph, I can discover that restricted points determined by any four lines in the graph will be concyclic. I call the circle “restricted circle”. What I want to prove is that the above situation will go on. In other words, restricted points will exist when I have six lines, and restricted circles will exist when I have seven lines and so on. In my study, I used Principal of Mathematical Induction, special ways of numbering points and circles, and “orientated angle” to prove my hypothesis. Because of particular line groups corresponding with particular restricted points or restricted circles, the further work I want to attain is to find the relation of them.

『凍』人心『鹹』,『黃』金Style~以冷凍凝膠法創作速成鹹蛋黃之新『蛋』生

蛋黃酥所使用鹹蛋黃來自於鴨蛋鹽漬而成,取出鹹蛋黃剩餘之蛋白因鹽度高,無法再利用只能拋棄相當不環保,本實驗利用將蛋冷凍再解凍以分離出蛋白及蛋黃,蛋白可加工再利用,凝膠蛋黃則可鹽漬成鹹蛋黃。結果發現蛋黃在-18℃冷凍3天可完全凝膠,以30%食鹽水鹽漬40-60分鐘,其鹽度已與市售鹹蛋黃相當。在喜好性感官品評發現,鹹味、口感及整體喜好性均與傳統鹹蛋黃相似。解凍蛋白製成蛋糕在喜好性感官品評發現,色澤及口感評分最高優於新鮮蛋白,在香味及整體喜好性則與新鮮蛋白無差異。速成鹹蛋黃僅須1/10生產時間且蛋白可回收再利用並減少鹹蛋白廢棄物。

節能減碳-波浪發電機模型之創作與應用

隨著全球石油能源短缺,世界各國無不積極尋求永續開發且無公害污染之能源方案,而利用海洋能量發電的形式已成為世界諸國積極研究之重要課題。本研究利用近海岸浮體式波浪發電設計,並利用波浪理論推導與波浪實境測試之方式,創作出在波浪中之發電系統。發電過程為波浪推動浮體,浮體拉動水下的掛重移動,透過掛重上的橡膠管經由摩擦力效應拉動波浪發電機模型的旋轉輪,此刻旋轉輪的轉動與波浪的波高、週期產生連動效應,進而轉換擷取波浪能量,並利用此波浪發電方式,設計研發出『危險水域波浪警示燈』模型,且能在海中真實運作良好成功。

蟹殼幾丁凝膠應用在金屬氧化物奈米顆粒的製備與燒結

筆者利用自製的幾丁質與不同金屬的混合溶液而燒結出的奈米顆粒成效極佳,不但粒徑大小符合,在燒結的過程中也不需經過物理研磨及介面活性劑的輔助,並且在低溫下即可燒結,可以增加實用性以及商業價值。此外,在分解亞甲藍方面也有不錯的效率,並進一步從金屬氧化物之奈米膠體混合溶液比例的不同,決定其粗糙度(以AFM測定)及能隙改變,在陽光下有更高的應用效率。而在實驗的延伸研究上,希望應用在防菌、除污、甚至光電池。 We make use of self-made chitin with the mixed solutions of different metals to solder nano particles, and the result is excellent. The particle radius not only matches up to the size, but in the process of soldering nano particles, it doesn’t need any physical pulverizing or surfactant assistance. Also, it can solder in low temperature. And we could raise its practicality and the business value. What’s more, there is a good efficiency in decomposing Methylene Blue. We can further decide the roughness (measured with AFM) and the variation of the band gap from nano colloid of different metal oxide mixed ratios.Our experiment in the extending research aims to apply it to the defense of bacteria and pollution, and even photoelectric cell.

在浪碎之前

本研究以模擬實驗探討波浪在斜坡海灘上的行為。實驗在長1.8公尺、寬0.75公尺的透明水波槽中進行,以長0.90公尺、寬0.60公尺的木板在深水區產生單峰波向淺水區前進,同時以數位錄影機錄影後進行分析。結果發現單峰波由深水進入淺水,波速會變慢,但當波高對水深的比值增加到一定值時,波速隨水深變淺而變快,波高也變高。當比值繼續增加,波前方的水面形成垂直的水牆,接著波就碎了。如果坡度較緩,碎波點會離水岸線較遠,水牆維持的時間也較長。有趣的是,水波槽中的單峰波移動時,有蠕動現象,波寬會伸縮,波高會起伏,波速也會些微地忽快忽慢。 ;This study simulates the behavior of the wave on a sloping beach. Experiments are performed in a sloping wave tank. A paddle wave maker at the deeper end generates single crest waves. To analyze the wave height, speed and breaking point, a digital camera is used. The results show that when the wave moves toward the coast, the shallower the water is, the slower the wave moves. But when the ratio (wave-height/water-depth) exceeds a critical value, it turns out that when the water is shallower, the wave speed becomes faster and the wave height, higher. As the ratio keeps on increasing, the front part of wave becomes a vertical water-wall, and then breaks. If the slope is gentler, the breaking point will be farther from the coast and the water-wall will keep for a longer time. An interesting phenomenon is also found that a single crest wave squirms with slightly undulated changing of width, height, and speed while it propagates in the sloping wave tank.

台灣的黯化現象與形成因素探討

本研究在探討台灣的黯化現象與形成因素,黯化現象為太陽輻射量到達地表的減少現象。我們藉由比較西元1961~ 2008年間,台北、台中、台南、大武、蘭嶼、花蓮六個測站的各項氣象因子進行分析處理並探討其變化情形與成因。 \r 研究結果顯示,台灣地區的都市測站(台北、台中、台南)日照時數、日照率、全天空輻射量均呈現先下降後上升的趨勢,顯示1961至2000年間確實存在黯化現象,而在鄉村測站(大武、蘭嶼)則有微幅改變但較不顯著。並藉由可能影響黯化現象各氣象因子的比對,發現最高溫的增加幅度遠小於最低溫,可能表示黯化現象部分削弱了暖化現象。另外,溫度均較差也逐年縮小,亦可以當成黯化現象的一個顯著的指摽。在造成黯化現象成因中,污染物和雲量最為明顯。在有雲量的影響下,台灣地區汙染物濃度對黯化現象的影響程度,依序為硝酸鹽類>PM10>二氧化硫,此外少量污染物也會使雲量大幅增加,故兩者對黯化現象會產生交互影響。由雲量改變量對應日照時數改變量/雲量改變量的分析圖中,可看出都市地區年平均雲量改變量大於15%時,其雲量每減少10%,日照時數約減少3~22%;若年平均雲量改變量小於15%時,則對黯化現象不具統計意義。取每年十月中雲量在1以下的天數來分析各污染物對全天空輻射量影響,可發現雲量極低時,單位污染物濃度對黯化現象影響,SO2最大,NOx次之,PM10最小。

雙叉桿菌於不同優酪乳中抗氧化性之研究

The objectives of this investigation were to evaluate the growth conditions and the antioxidant activities of fermented black bean soy milk(BBSM) with Bifidobacterium longum B6 and 15708 cultured in four media, namely, ( BBSM ( 100%)+ 1% glucose ), ( BBSM (100%)), ( BBSM (50%) + milk (50%)), (milk (100%)) . These results indicated that; (1) both strains attained viable cell numbers about 7.19~9.53 log CFU/ml after 18 hrs of incubation and were in the order of ( milk (100%))>( BBSM (50%) + milk (50%))> ( BBSM (100%) + 1% glucose)>( BBSM (100%)), (2) both strains in ( BBSM (100%)) exhibited higher pH value ranging from 4.79 to 5.50 , but lower titratable acidity(%) ranging from 0.27% to 0.61% than the three other media after 48h of fermentation, (3) both strains displayed an even smaller tolerance to simulated gastric juice at pH = 2.0 for 3h, especially in ( BBSM(100%)), while in simulated gastric juice at pH =3.0 for 3h had higher tolerance , (4) both strains had high resistance ranging from 72.51% to 92.62% to 0.3% bile solution for 12h, (5) the reducing power of ( BBSM (100%)) was more excellent than that of ( milk (100%)), (6) the scavenging effect of yogurt (BBSM ( 100%) + 1% glucose) on DPPH radicals was significantly higher than that of ( milk (100%)), (7) In general, at ten- fold dilution the chelating effect on copper ions of these four un-fermented media except ( milk (100%)) was significantly higher than that of fermented media with B.longum B6 or 15708. 本研究是探討雙叉桿菌(Bifidobacterium longum B6及15708)在四種發酵基質(【黑豆奶(100%)+1%葡萄糖】、【黑豆奶(100%)】、【黑豆奶(50%)+牛奶(50%)】、【牛奶(100%)】)中的生長情形及抗氧化活性。結果顯示: (一) 兩株菌在四種培養基中的生長菌數大小順序如下:【牛奶(100%)】>【黑豆奶(50%)+牛奶(50%)】>【黑豆奶(100%)+1%葡萄糖】>【黑豆奶(100%)】。 (二) 兩株菌在【黑豆奶(100%)】的pH值比較高於其他三種優酪乳,而最終發酵可滴定酸度比較低於其他三種優酪乳。(三) 兩株菌於pH2.0環境下,在【黑豆奶(100%)】優酪乳中耐酸性很低,而於pH3.0環境下卻有很高的耐酸性。(四) 兩株菌對0.3%膽鹽之耐受性均很高為72.52%~92.62%。(五) 在稀釋10倍的四種基質中,不論發酵前或發酵後的還原力皆以【黑豆奶(100%)】為最高,【牛奶(100%)】為最低。(六) 在濃度稀釋10倍時,【黑豆奶(100%)+1%葡萄糖】對DPPH‧自由基清除率明顯比【牛奶(100%)】高。(七) 在濃度稀釋10倍的四種優酪乳中,除【牛奶(100%)】外,發酵後比未發酵的銅離子螯合率明顯降低。