瓦斯熱水爐一氧化碳觸媒轉化器之研究
瓦斯熱水爐使用大火時廢氣的CO 濃度非常高是導致一氧化碳中毒事件的關鍵原因，要解決這個問題觸媒轉化是一種可行的方式。影響觸媒性能的因素中以活性中心的種類最為重要，我們發現對轉化一氧化碳為二氧化碳的反應而言鈷有最好的催化效果，其次分別為：鎳、銅、鐵。最好的載體是三氧化二鋁，鈷的含量使用10％，煅燒溫度使用300℃可兼顧性能與成本。
本研究中所研發的 Co/Al2O3 觸媒具備有實用的潛力，可以在空間速度高達1000min-1 的情況下將濃度14,632ppm 的CO 百分之百轉化為CO2，而僅需233℃的反應溫度。因此，應該可以應用在瓦斯熱水爐上以降低一氧化碳中毒的風險。
The incorrect usage of a natural gas powered water heater always generates high carbon monoxide concentration in a closed environment. The dangerous CO gas can be fatal to the careless user of the water heater. Catalytic conversion of CO to CO2 can be a convenient method to solve this problem.
The effect of the support, the supported metal, loading of the metal, reaction temperature, gas concentration, and reactants flow rate on the performance of the CO oxidation catalysts have been investigated. X-ray diffraction, gas adsorption and Infrared spectroscopy were applied to study the characteristics of catalysts.
A 100% conversion of CO to CO2 can be achieved when 1.46% CO/6% oxygen/N2 reactants was catalyzed by a 10% Co/Al2O3 catalyst at 233℃ with a space velocity of 1000min-1 .
This reaction condition is sufficient to remove the entire CO generated by a family-sized natural gas water heater.
生生不息-正五邊形的繁衍及算術法則
This study was to explore the nature of two basic constitutes of the regular pentagon,With these two constitutes, the regular pentagon could be multiplied into any times in size. We used four multiplication methodsto show how the regular pentagon enlarge and to verify that the enlarged regular pentagons derived from computer did exist. By integrating these four multiplication rules, we were able to arrange regular pentagon of any length of side, and evidenced the equation was ( If m,n is the number of A,B of a regular pentagon respectively ) When we tried to verify if any regular pentagon could be constituted by other smaller regular pentagons, we found that it was un-dividable only if the length of pentagon side were (the number of A, B were the 2n and 2n-1 item of Lucas Sequence), otherwise, any regular pentagon is able to be constituted by other smaller regular pentagons. The divided forms could be multiple. We also found that any pentagon could be divided by two successive un-dividable pentagons, which is called “standard division rule”. We expected to derive all kinds of division by analysis of two successive un-dividable pentagons in standard division rule.
這個研究起源於一個拼圖玩具：利用兩種黃金三角形排出指定大小的正五邊形。我們的研究動機是：一、 假如無限量供應A 和B，能夠拼出哪些邊長的正五邊形？二、 哪些拼好的正五邊形不能拆成一些較小的正五邊形？我們將研究的主要結果分述如下：
「渦」藏「聖」機--以渦流脫離重新詮釋聖嬰發生的原因
If we place a block in continuous, steadily flowing water, some periodic eddy currents will appear behind it. In my report, I would like to introduce a new way to explain how the periodical movement of eddy currents would help to triggering El Nino. According to my experiment, these eddy currents have a certain life cycle, and the eddy current give a force, which drag water form the area they just went by. It will cause water level became lowest for a period of time. These phenomena are also shown in the real data of “Sea Surface Height Anomaly”, it is a quiescence period, and then changes into the highest one it is interesting that highest one always follows by the starting of El Nino. Another important result from my experiment is that, in the same fluid, the frequency of eddy currents is controlled by 2 variables: Size of the block and velocity of the flow, From this result, then get the frequency of eddy current-occur every 3.2 years. It is just correspond with frequency of historical data the El Nino from the 70’s to the present.
本報告嘗試以南極繞極環流在南美洲南端產生週期性渦流脫離的現象來解釋聖嬰的發生根據水槽實驗的結果，水流在通過障礙物後渦流脫離瞬間，會形成一水位低的空區，之後在周圍的水大量湧入，水位突然升高，並有一段時間的振盪。另外，實驗結果也顯示，渦流形成和脫離頻率大致上和注水流速成正比，且和障礙物的大小成反比。根據此結果，對照實驗結果，我認為1993 年3-4 月，1996 年1-6 月及2001 年7-10 月三個「海平面高度異常」的最低值密集帶，此極可能是渦流脫離的時段。且對照「海平面高度異常」實際資料後，發現「海平面高度異常」的「最低值密集帶」後均伴隨水面「寧靜期」，接著就出現周圍暖水流大量湧入的「最高值密集帶」，此時南美洲東南側海水溫度驟增，接著馬上接續著聖嬰的到來。「海平面高度異常」分析的結果，指示渦流脫離的「最低值密集帶」和顯示著聖嬰到來的「最高密值密集帶」間約間隔半年左右。我們推算水的史托爾數約為1，以這個值代入實際南極繞極環流通過南美洲南端，得到渦流脫離的頻率約每3.2 年一次，和長期聖嬰發生的平均頻率非常接近。
灰色預測在雨量長期趨勢分析之應用
灰色理論近來廣泛應用於各行各業的管理資訊科學上，本研究乃應用灰色理論的一階微分中輸入變數為一項之 GM ( 1 , 1 ）模型，來預測台灣中部地區土石流主要因素雨量的月平均量值。本文運用三筆以上的歷史資料，作最近一年歷史性資料的預測，藉以驗證獲得其誤差（±△e）之校止參考依據值，比利用殘差檢驗所得的誤差校止數據，更能修止出精確的預測值，接著再做台灣中部雨量未來之預測，以作為未來雨水、土石流防治之參考 · 為了能迅速產生所要的灰色預測值，研究中並以 VB 程式語言及以Petri-net分析其動態處理行為，藉 GM ( 1 , 1 ）模型的專屬處理支援程式，以做為未來雨輦自動化處理警示與預測之支援機制。Recently Grey Theory has been widely applied to management information science in all kinds of areas. This research applies the first Level differential of the Grey Theory to put a variable in GM( 1,1) model to forecast the monthly average value of the most common precipitation, in the midland Taiwan earth-stone flood zone. This paper uses more than three historical data to forecast the most recent year’s historical data, which can be used to verify and acquire referential correction data of its errors ( ±△e). The aforementioned method can correct forecast data more precisely than the differential inspection. In addition, this method can then forecast future precipitation in midland Taiwan earth-stone flood zone and the results can serve as reference for future precipitation control. To rapidly receive the needed Grey forecast values, the research analyzes its dynamic process method by utilizing VB program and Petri-net to build a dedicated process-support program of GM( I , 1) model. This program will serve as a support mechanism for future automatic precipitation warning and forecast.
海格的爆尾釘蝦－鹼性電池的探討
鹼性電池使用的電解液均為強鹼，電池中的鋅極會與其發生腐蝕反應，使得電池放電壽命降低，並產生氫氣，而大量氫氣使得電池有爆裂的危險，為了改善上述問題，我們自行設計了氣體觀測儀器，用來檢測銀鋅電池充放電與靜置時之氣體產生量，更藉由探討影響變因的過程找出銀鋅電池較合適之使用條件，其中包含電解液種類及濃度之選擇、電極面積與充電電流對使用效果之影響，並改善電池腐蝕程度；我們將鋅極以浸鍍處理(Sn:Pb ＝1:1 )並搭配電解液添加物(KOH:Zn(OH)42 －＝ 2:1) 可效率地抑制氣體產生；更用氯化銀粉末取代傳統氧化銀極片為正極，發現氯化銀可代替氧化銀電極，且有不錯的放電效果。;As we know, the electrolyte solution used in an alkalinebattery is a concentrated alkaline solution, which corrodes the zinc electrode in a battery of this kind. The corrosive reaction not only reduces the lifespan of the battery but also produces hydrogen, causing the battery to explode. This study is intended to help us design a device to measure the quantity of hydrogen gas generated in the charging of a zinc-silver battery. We have studied several factors affecting zinc-silver battery, including the variety of electrolyte, the concentration of alkaline solution, the surface of electrode, and the density of charging current, etc. To reduce the corrosion of zinc electrode, we plate the zinc electrode by the immersion electroless plating method, using several kinds of low-polluting anti-corrosive additives (metallic compounds such as lead and tin). We also add zincate ion into electrolyte solution to further reduce the quantity of hydrogen produced. The experiments show a zinc-silver alkaline battery works most efficiently, if the powder of silver chloride is used instead of silver oxide.
顛倒一族
一 Motivation and Purpose: In this study, we want to completely know about “The number abc…de, which times m/n, 1≦n≦m≦9?N can get ed… cba?”, and also expect to find out “The good rule within them”. 二 Procedure:Using method of enumeration, induction to collect sample of all and beginning from two digits to get information “good rule”. When get some useful idea, put them into the following research for the step easy go on, the method try and error is a very tiresome works, especially when we deal higher digits. till enough information is obtained, we solve problem and find new one, then likewise again research steps, just the basic science research ways, we are glad have the key of these problem. 三 Result and conclusion :Those number we named “converse No.” There are two groups: S=m+n=10 and 11 S=11, then Q=m/n=9/2,8/3,7/4,6/5=4.5,2.6,1.75,1.2 S=10, then Q=m/n=9/1,8/2,7/3,6/4=9,4,2.3,1.5 Each group have four type. When S=11,Q=7/4=1.75,if converse No.each digit is a multiple of 3, then can cancellation or extension of fraction to get another 3 or 4. Growth up rule: Converse No. = type factor x heritable factor x growth factor=rx hx g S=11,r=2~5,h=9, s=10, r=1~4, h=99 一 研究目的：盼能找出”顛倒一族”的族譜。二 研究過程：確定研究題目為ab…cde×m/n=edc...ba,0≦n≦m≦9?N 求ab… cde？以窮舉法收集觀察資料，歸納演繹尋求規律。1.先觀察兩位數，分析共有顛倒對36對。2.建立乘數Q=m/n一覽表，共有27個3.設計顛倒對大/小及其商一覽表，以利觀察、歸納獲得規律。4.接著觀察三位數，共有360對，綜合二、三位數規律，找出選擇式窮舉法：9之倍數法。5.再接著找出四位數，再綜合而知另有 全調法 重現法 半調法 GCD遺傳基因法等來繁衍高位數顛倒數。6.於是依諸法找得六位數資料，得知GCD遺傳基因法為繁衍通則，完成族譜建立模式。7.研究顛倒數位數與其個數間關係式，完成研究。研究結論：1.顛倒一族有兩大類：S=10與S=11 S=m+n。2.每一大類有四型： S=10中，Q =9/1,8/2,7/3,6/4(9,4,2.3,1.5)S=11中，Q =9/2,8/3,7/4,6/5(4.5,2.6,1.75,1.2)3.每一型均有一個顛倒數，除了S=11中，Q=7/4=1.75者可約、擴分而得3or4個。4.顛倒數原則上均為9之倍數，除了Q=7/4經約、擴分可能得非9倍數者。
創新儀器測量光的繞射與干涉之強度分佈
Light diffraction and interference are two of most basic experiments, but they’re the most powerful evident of wave properties of light. Due to the lack of high-quality and fairly accurate equipment, these important experiments are limited to the simple demonstration of the phenomena. Especially, the spatial intensity variations of diffraction and interference patterns are, however, completely not drawn to scale. In order to precisely measure the diffraction and interference patterns intensity, we consult lots of reference, search for suitable materials and reuse waste old and useless laser printers. Finally, overcoming disadvantages of time consumption and poor spatial resolution, we develop two accurate, practical and delicate methods. We use optical power control circuit created on our own to steady the brightness emitting of laser diode. Then the high linear photoelectric detector is stored on XYZ axis micro movement control platform. Next high degree of reflection rotating polygon mirror employing optical lever is collocated with low vibration blushless motor. Thus, a self-scanning intensity pattern plotter is accomplished. At the same time, it overcome difficulties like time wasting and low reliability during doing these kind of optical experiments. In this article these two dependable and worth popularizing measurements of light diffraction and interference is going to be introduced. 光的繞射與干涉實驗是光學中最基本的實驗之一，也是證明光的波動性質之最主要的依據。在一般的高中物理實驗室中受限於器材的等級與精度，只能對光的繞射與干涉做近似定性的實驗，尤其是繞射、干涉圖形上的光能量分佈，完全無法以現有的器材做精準的測量。 在這一年的專題研究中，我們小組針對測量光的繞射、干涉能量分佈為目標，參閱許多相關文獻，四處尋找適用的材料及零件，發揮廢物利用的精神，克服萬難，發展出兩種精巧、實用又準確的測量方法，我們以自行發展的光功率控制電路使雷射二極體的光度穩定，並且以高線性度的光感測元件裝載在自行設計的X.Y.Z微動機台上，同時利用光槓桿原理所構成的高反射度的旋轉六面鏡，配合低震動的無刷馬達，完成了一套能自動掃瞄繞射能量分佈曲線的測試儀，經實際使用相當地穩定可靠，可以快速而精確地獲得大量的實驗數據，比對這些數據不僅能驗證繞射理論，並能更深入地延伸理論的探討。