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臺灣

瓦斯熱水爐一氧化碳觸媒轉化器之研究

瓦斯熱水爐使用大火時廢氣的CO 濃度非常高是導致一氧化碳中毒事件的關鍵原因,要解決這個問題觸媒轉化是一種可行的方式。影響觸媒性能的因素中以活性中心的種類最為重要,我們發現對轉化一氧化碳為二氧化碳的反應而言鈷有最好的催化效果,其次分別為:鎳、銅、鐵。最好的載體是三氧化二鋁,鈷的含量使用10%,煅燒溫度使用300℃可兼顧性能與成本。 本研究中所研發的 Co/Al2O3 觸媒具備有實用的潛力,可以在空間速度高達1000min-1 的情況下將濃度14,632ppm 的CO 百分之百轉化為CO2,而僅需233℃的反應溫度。因此,應該可以應用在瓦斯熱水爐上以降低一氧化碳中毒的風險。 The incorrect usage of a natural gas powered water heater always generates high carbon monoxide concentration in a closed environment. The dangerous CO gas can be fatal to the careless user of the water heater. Catalytic conversion of CO to CO2 can be a convenient method to solve this problem. The effect of the support, the supported metal, loading of the metal, reaction temperature, gas concentration, and reactants flow rate on the performance of the CO oxidation catalysts have been investigated. X-ray diffraction, gas adsorption and Infrared spectroscopy were applied to study the characteristics of catalysts. A 100% conversion of CO to CO2 can be achieved when 1.46% CO/6% oxygen/N2 reactants was catalyzed by a 10% Co/Al2O3 catalyst at 233℃ with a space velocity of 1000min-1 . This reaction condition is sufficient to remove the entire CO generated by a family-sized natural gas water heater.

電話網路全方位監控系統

In this paper, we use telephone network to remote-control household appliances and monitor security system through the implementation of software and hardware. The purpose of developing this system is to build up a system that makes everyone take advantage of the telephones through pay phone network everywhere as and when he needs to set up the household appliances, meanwhile two-ways system of monitoring household security. In addition, due to the advances of communication technology and the remarkable boom of those products, the popularity of cell phones for local people is developing tremendously. We can link the portable cell phones up to the household appliances and monitoring household security through the offer network of communication companies. This system adopts public telephone network via multiple frequency to receive KT31 70 IC which is connected to EM78P45 i p Chip. And then the Chip is connected to the driving external circuit in order to control electric appliances, sensors on doors and windows. The utilization of LEPROM (93C66) memory to set up telephone and mobile phones number equips the telephone network with two-ways system of remote-controlling electric appliances and monitoring household security. In the part of controlling electric appliances, a monitor is used to display the status of electric appliances, to control the appliance switches and to set up the timer. In the part of monitoring household security, we use the system to receive the instant images of the house and to report on the closing or opening of doors and windows. The system will be informed on any occurrence of abnormalities. The memory of the system can record and update new data at any time and is able to set up twenty sets of telephone and mobile phone numbers. Besides, the system adopts identification codes to avoid malfunctioning and thus upgrade system reliability.本文旨在應用電話網路作遠端遙控家用電器及防盜保全歟控系統軟硬體之規劃與設計 。本系統研製的目的,是希望建立一套系統,讓每個人不管身置何處,都能利用電話透過公眾電話網路,輕易地控制家中的電器設備及進行環境設定,以達到控制家電及防盜保全之雙向監控系統。此外,由於通訊的進步與通訊產品的熱賣,使國月雍有手機的普遍性相當高,若能透過隨身攜帶的手機,經由通訊業者所提供的網路通訊管道,連結到家庭自動化與防盜保全系統亦可達到進行遠端遙控的目的,彌補出門在外無法使用室內電話的空檔。本系統利用公眾電話網路經複頻接收 IC ( KT3 170 )連接至單晶片( EM78P45 IP ) ,透過單晶片驅動外部電路與家中電器及門窗的監視感測器連接,再利用 EEPROM ( 93C66 )記憶體設定電話及手機號碼,藉由電話網路傳輸,以達到控制家電及防盜保全之雙向監控系統。在家電控制部份,採用顯示器可隨時瞭解家電使用狀況及控制其開啟或關閉,且可設定使用時問。在防盜保全部份,可隨時監控家中門窗,若有異狀可即時通告。記憶體可隨時記錄或更新資料,並可設定二十組電話及手機號碼。此外,本系統採用確認碼設定,可防止產生誤動作,系統可靠性高。

印度莕菜由沉水型轉為浮水型的支撐機制探討

The special life cycle of the Nymphoides indica: The veins and petioles of the pleustonic leaves can asexually reproduce adventitious buds. Pleustonic adventitious buds will change the density of the plants and sink into water. When the root of submersible plants attaches to the bottom of the pool, they will extend stems to the water surface and resume the life cycle. Reticulate sigmons and astral sclerenchyma appears in the process of transformation. Astral sclerenchyma merely appear in the species of which its leaves float above the water surface, and Nymphoides sp. are the most obvious. The cell wall thickness of astral sclerenchyma is even. The cells are hollow and full of water, and they will utilize water to change turgor between axes and spines. This is also proved in imitating experiments. The reticulate sigmons are frequently seen among aguatic plants, and the horizontal structures prevent air space from collapsing. These two structures make the thin stems of Nymphoides indica sustain the leaves instead of being crushed by the floating water. 印度莕菜 ( Nymphoides indica )獨特的生長週期:浮水型葉的葉脈和葉柄可以無性繁殖不定芽,浮水型的不定芽會改變植株的密度而沉入水中,當沉水型植株的根系在池底固著後,便會以莖延伸出水面,再次展開浮水型葉的成長週期。轉變過程中會出現網狀的橫膈和星狀厚壁細胞。星狀厚壁細胞僅出現於葉片需由水中浮出水面生長的植物種類,而莕菜屬植物更明顯。星狀厚壁細胞其細胞壁厚度均勻,細胞中空且充滿水分,會利用水分在中軸與突起的棘間移動來改變膨壓變化,在模擬的實驗中也得到證實。網狀的橫膈在水生植物中是較常見到的構造,水平方向的支撐可以讓氣室不會塌陷,兩種構造的作用下使得印度莕菜細長的莖能夠支撐葉片,不會被流水沖斷。

雞胰臟去氧核醣核酸水解?多型性之探討

去氧核糖核酸水解?,(deoxyribonuclease,簡稱DNase)為一種核酸內切?。目前研究得最透徹的去氧核糖核酸水解?為牛胰臟的DNase I,有四種以上的同功?存在。而牛和雞的DNA序列有極高的相似度,由之前的研究中在等電點焦集電泳法顯示雞胰臟DNase I 具A、B 兩種同功?,本實驗則希望能進一步了解兩種同功?的差異原因。在抽取RNA 後,以RT-PCR 方法合成cDNA,將其以限制?切割,再以大腸桿菌作為載體進行轉殖及繁殖培養,最後將其DNA 定序後進行分析比較。目前已完成第一次定序,但因引子接合過程中有部分位置錯亂造成殖體無法進行表現。另外在此次所得之序列中有發現一個胺基酸的轉變,而其是否為多型性之表現則有待進一步的實驗證實。The most advanced research on deoxyribonuclease in current states is on the bovine pancreatic DNase I, more than four of which isoforms have been found. It is shown that the DNA sequences of chicken and bovine have relatively high similarity. In addition, according to the result of isoelectric focusing from previous researches, chicken pancreatic DNaseI has two isoforms (A and B.) In this research, the author expects to establish more knowledge on the differences on the isoforms and the causes. After receiving the RNA, the RT-PCR is preformed to incorporate the cDNA, which is later cleaved by restriction enzyme and inserted into the plasmid DNA of the E. coli host cell to be cloned. So far a polynucleotide sequence has been deduced from clones of the cDNA, but it cannot be expressed successfully in E.coli due to few random mistaken splicing. There is an alternation of one amino acid, and whether it is the actual state of isoform or not still requires further proof.

推著離子跑

在本次實驗中,我們發現溶液中的帶電離子,會因為離子團的熱運動,和電偶極的庫倫吸引力(electric dipole)的交互作用下,使得電解質溶液的I-V curve(電流-電壓 曲線),具有類似磁滯曲線(Hysteresis curve)的效果,同時我們運用光學干涉的原理,證實此時在電場作用下,離子團會互相順著電場方向作條列鍵結,而加熱實驗也證實,熱運動會使溶液的I-V curve(電流-電壓 曲線)變的不一樣。另一方面,我們也發現,在給予電解質溶液一外加的衝擊電壓時,該溶液的電荷分布,?會因為彼此的互相擠壓以及自由擴散的作用下,而形成一震盪分布,其所顯現出來的,則是電壓的震盪變化。最後由於震盪波紋的變化,在起始時與中段之後有著明顯差異,我們對此變化提出看法和證實,相信內容是精采可期的! In this experiment, with the interaction of the heating action of ionic atmosphere and electric dipole, we find that ionic in the liquor makes the I-V curve in the electrolyte liquor show up with the effect similar to Hysteresis curve. Meanwhile, we practice the principle of interference to prove that at this moment, under the influence of electric field, ionic atmosphere will connect to each other in line following the direction of the electric field. It is also proven that in the heating experiment, heating action will make I-V curve in the liquor different.On the other hand, we also find with extra electric impact, the charge distribution of the liquor will form a oscillation, that is, the changes of the voltage oscillation under the inter-collision and the free spread. We offer our viewpoints and proofs about the obvious changes of oscillation wave in their beginning stage and after their middle stage. We believe that the marvelous content is surely worth of your expectation.

太陽能熱動力發電與效益的改進方法

在綠色能源中太陽能的利用充滿了無限的機會,其中利用太陽熱能發電的太陽能煙囪觀念有很大的潛力。在本研究中,我們以實驗的方法討論煙囪高度、入風口大小、管型等因素對solar chimney 效益的影響,發現就原先的觀念設計中,有相當大的改進空間。整體實驗而言,所改變的各項變數中,以管型之改變有最大的改進效益。就同長度直管與漸擴管而言,漸擴管在風速上有明顯改進效果,且以流速與截面積換算成效率,較原直管設計之效率高出約20 倍,因此推測漸擴管應用在現行之solar chimney 以改進效能是極有可行性的。研究中也發現煙囪管壁的熱傳導也會影響氣體的總體流動,使效率降低。相信此實驗之數據對日後嘗試對solar chimney 進行改進的研究者有相當之參考價值。Solar energy has a great market potential among many clean energies. The new solar chimney concept using solar thermal power in power generation may have a bright future. Experimental work was performed to study the energy conversion characteristics of a solar chimney. The air moving capability and the influences of chimney height, the shape of chimney and air entrance dimension were studied. It was found that there is a great room to improve the current solar chimney design and thus the efficiency. Overall speaking, the chimney pipe geometry may have the most significant impact on the improvement of performance. A diverged pipe configuration can induce nearly 20 times more flow than a traditional straight pipe. Another finding is the heat transfer effect on the chimney pipe may have the effect in reducing the flow. It is believed that the present study0 is valuable for those people in designing a future solar chimney.

線蟲補捉菌Arthrobotrys musiformis 黏液相關基因之選殖與功能界定

線蟲捕捉菌Arthrobotrys musiformis 是一種可經線蟲誘導產生捕捉網來捕捉線蟲的真菌,本實驗即針對A. musiformis 的捕捉網黏液相關基因:Manosyltransferase(AH73), β-1,3-glucan transferase(AH102), fimbrin(AH121)及mannose-specific lectin precursor(AH338)進行選殖與功能界定,希望建立這方面的研究基礎,將來能應用在松材線蟲的生物防治上。首先我們大量培養A. musiformis,萃取菌絲體的DNA;接著進行聚合?連鎖反應 (Polymerase Chain Reaction,PCR) ,利用專一性引子對 (primer) 大量增幅AH73、AH102、AH121 及AH338之基因片段;增幅後的產物經過純化、選殖,定序並進行分析比對,確認增幅之序列無誤後,以 Digoxigenin (DIG) 標示當為探針,篩檢A. musiformis 的Fosmid Library﹔目前已成功選殖出AH73 之可能基因,完成AH73 之探針製備,並以其篩檢A. musiformis 的Fosmid Library﹔呈雜合正反應之選殖株 (clones) 將以散彈槍方法(shotgun)定序,作序列組合,探索相關的基因;接下來用 Rapid Amplification of cDNA Ends(RACE) 做出互補DNA (complementary DNA , cDNA) 全長度後;最後建構基因缺失株,驗證此基因所調控的生理以及生化機能。 Nematode trapping fungus Arthrobotrys musiformis can capture nematodes by producing adhesive nets when nematodes go through. Many kinds of nematodes, including pine wood nematode (Bursaphelencus xylophilus), can be captured. Pine wood nematode causes serious pine wood disease. Therefore, A. musiformis has the potential of biocontrol in pine wood nematode. Our research focused on adhesion and adhesive relevant genes of A. musiformis :Manosyltransferase (AH73), β-1,3-glucan transferase (AH102), fimbrin (AH121), and mannose-specific lectin precursor (AH338). We try to clone these genes and carry out functional analysis. In order to achieve this goal, we used specific primers derived from previously obtained complementary DNA (cDNA), by Polymerase Chain Reaction (PCR) to amplify these genes and gained adequate quantity of genomic DNA products. After sequencing and verifying of the identity of the genomic DNA, we use Digoxigenin (DIG) to label them and use them as probes to screen the constructed A. musiformis Fosmid Library. Currently, the Southern colony hybridization is undergoing. The positive Fosmid clones against the specific probes will be sequenced completely by shotgun library to monitor the existence of adhesion related gene cluster. After working out the full length cDNA of these genes, we will use them to construct replacement vectors to knockout the adhesion related genes, creating mutants and further verify their functions through genotype or phenotype bioassay.

創新儀器測量光的繞射與干涉之強度分佈

Light diffraction and interference are two of most basic experiments, but they’re the most powerful evident of wave properties of light. Due to the lack of high-quality and fairly accurate equipment, these important experiments are limited to the simple demonstration of the phenomena. Especially, the spatial intensity variations of diffraction and interference patterns are, however, completely not drawn to scale. In order to precisely measure the diffraction and interference patterns intensity, we consult lots of reference, search for suitable materials and reuse waste old and useless laser printers. Finally, overcoming disadvantages of time consumption and poor spatial resolution, we develop two accurate, practical and delicate methods. We use optical power control circuit created on our own to steady the brightness emitting of laser diode. Then the high linear photoelectric detector is stored on XYZ axis micro movement control platform. Next high degree of reflection rotating polygon mirror employing optical lever is collocated with low vibration blushless motor. Thus, a self-scanning intensity pattern plotter is accomplished. At the same time, it overcome difficulties like time wasting and low reliability during doing these kind of optical experiments. In this article these two dependable and worth popularizing measurements of light diffraction and interference is going to be introduced. 光的繞射與干涉實驗是光學中最基本的實驗之一,也是證明光的波動性質之最主要的依據。在一般的高中物理實驗室中受限於器材的等級與精度,只能對光的繞射與干涉做近似定性的實驗,尤其是繞射、干涉圖形上的光能量分佈,完全無法以現有的器材做精準的測量。 在這一年的專題研究中,我們小組針對測量光的繞射、干涉能量分佈為目標,參閱許多相關文獻,四處尋找適用的材料及零件,發揮廢物利用的精神,克服萬難,發展出兩種精巧、實用又準確的測量方法,我們以自行發展的光功率控制電路使雷射二極體的光度穩定,並且以高線性度的光感測元件裝載在自行設計的X.Y.Z微動機台上,同時利用光槓桿原理所構成的高反射度的旋轉六面鏡,配合低震動的無刷馬達,完成了一套能自動掃瞄繞射能量分佈曲線的測試儀,經實際使用相當地穩定可靠,可以快速而精確地獲得大量的實驗數據,比對這些數據不僅能驗證繞射理論,並能更深入地延伸理論的探討。

螞蟻吊大象

為了解「螞蟻吊大象」課程中脆弱的火柴棒如何撐起六、七瓶礦泉水,我們設計實驗包括三根木棒的粗細或長度改變、木棒接觸面的材質、載重系統的整體環境等,探討承載架運用什麼方法撐起重物、如何增加承載架負重能力,發現改變各種變因能影響承載架負重效果:當木棒纖維強度不足時,承載架倒塌的原因為木棒斷裂,當木棒纖維強度足夠時,會因繩子受力拉長,最終導致傾斜倒塌。在實驗過程中了解承載架載重原理,嘗試應用於生活之中,設計能夠隨處掛起的環保杯袋,並且對力學有更深入的了解。

無孤力點無交錯分割的區塊細分及五個新的Riordan組合結構

將一個集合{1,2,...,n}分成數個非空的集合(組,區塊),稱為此集合的一個分割。如果可以找到1 ≦ a 已知無孤立點無交錯分割以Riordan 數{rn}n≥0 =1,0,1,1,3,6,15,36,... 來計數。在這篇文章中我們研究無孤立點無交錯分割的一些性質。 首先我們考慮無孤立點的無交錯分割按區塊的細分。我們得出:集合{1,2,...,n}恰含k個區塊的無孤立點的無交錯分割的個數為: 其次,我們證明bn,k和多邊形的剖分有令人訝異的關連。令dn,k是用不相交對角線將凸n 邊形分成k 塊的方法。我們用代數方法證出 bn,k = dn+2−k ,k,也給了一個新的組合證明。 最後,透過對應的方法,我們找出了七個嶄新的組合結構,這些結構都是以Riordan 數來計數。 Partition the set {1,2,...,n} into several nonempty sets (blocks) and call it a partition. If there exists 1 ≦ a It is known that the nonsingleton noncrossing partitions are counted by Riordan numbers {rn}n≥0 =1,0,1,1,3,6,15,36,... In this paper we study the properties of them. First we consider the enumeration of nonsingleton noncrossing partitions in respect to the blocks. We prove that the number of nonsingleton noncrossing partitions of {1,2,...,n} with k blocks is Then we give a connection between nonsingleton noncrossing partitions and polygon dissections. Let dn,k be the ways to dissect an n –gon with noncrossing diagonals. We prove that bn,k = dn+2−k ,k We also give a combinatorial proof. Furthermore, by way of the technic of bijection, we find 7 new combinatorial structures counted by Riordan numbers.