奈米複合材料與空氣分子的愛恨情仇-探討奈米碳管對空氣滲透率之影響
本實驗使用聚醚亞醯胺溶液製備基本薄膜，由於玻璃態高分子薄膜過於緻密，一直是高分子薄膜在應用上的一大限制，為了在薄膜上製造缺陷，又不會使薄膜之選擇性降低，因此選擇將酸化之奈米碳管(孔徑10~20nm) 加至聚醚亞醯胺薄膜中。本實驗主要為探討添加不同濃度的酸化奈米碳管對聚醚亞醯胺薄膜的滲透率與選擇率的影響，藉由添加0.5 wt%、1 wt%、1.5 wt%、3 wt%、4 wt%等不同濃度的酸化奈米碳管至15 wt% 的聚醚亞醯胺溶液中，並製作薄膜，測試其基本性質與五種氣體(H2、CO2、O2、N2、CH4)的滲透率及不同空氣分子之間的選擇率。我們總共測試了三種薄膜的性質，分別是表面特性、熱穩定性及結晶型與層間距，薄膜的表面性質，能觀察到奈米碳管在薄膜中製造奈米孔隙結構，增加氣體滲透的孔道，能有效增加氣體的滲透率。增加奈米碳管的量，能有效升高第一階段熱裂解的溫度，雖然熱裂解在本實驗中沒有很大的差異，但是還是可以從熱重分析圖中推測不同量的奈米碳管會影響熱穩定性。在X 光繞射實驗中，添加奈米碳管的薄膜與純聚醚亞醯胺薄膜，在結晶相上都屬非結晶型薄膜，添加了奈米碳管的高分子複合薄膜的層間距明顯增大。在氣體滲透實驗中，我們比較了不同氣體或濃度不同的奈米複合薄膜的氣體滲透率，在不同氣體時，氣體的滲透率會隨著奈米碳管濃度增加有明顯的提升，五種氣體滲透率大致依照H2>CO2>O2>N2>CH4 這個趨勢增減。奈米碳管對1.5%增加到3%或4%的奈米複合薄膜滲透率的影響卻減小，由此可以推斷奈米碳管對空氣滲透率並非無限制的增加，在1.5%以後就漸漸趨近最大值。H2為14.89barrer，CO2 為9.51barrer，O2為6.34barrer，N2為6.48barrer， CH4 為3.75barrer 。本研究總共比較了三組氣體的選擇率，分別是CO2/CH4，O2/N2，H2/CH4，分離率最高的是H2/CH4 的，兩分子的粒徑大小差對分離率有極大影響，差愈大，其分離率也愈高。奈米碳管的量改變並不會使薄膜的氣體選擇率明顯增加或減少，但是加入太多奈米碳管其選擇率會變低。在五片薄膜中，1.5%的薄膜有最好的選擇率，奈米碳管的添加量超過1.5%選擇率就會開始下降。綜合滲透率及選擇率可以分析出，添加1.5%奈米碳管的高分子奈米複合薄膜有較高的滲透率，又不會降低選擇率，在利用上比其他濃度的奈米複合薄膜在有害氣體過濾及空氣的分離回收方面產生更好的效果。;This experiment uses Polyetherimide polymers solution to make basic membranes. Because glassy polymer membranes are too dense for gas permeations, it is one of the limitations in their applications. To increase gas permeability and maintain air selectivity, I made some nanogaps on the surface of the membranes by an acidification multi-wall carbon nanotubes (MWNTs, kinetic diameter 10~20nm) in the PEI membranes. We mainly want to find if it has some influence between the consistency of acidification MWNTs and gas permeability or selectivity. We mixed 0.5wt% 、1wt%、1.5wt%、3wt%、4wt% acidification Carbon nanotube in 15wt% PEI solution, made membranes and tested the character, five kinds of gas permeability (H2、CO2、O2、N2、CH4) and the selectivity between different gases. We have tested the three nature of membranes, including surface characteristic, TGA and XRD. We can see some nanogapes made by carbon nanotube in the membranes. It could availably increase gas permeability. Mixing more carbon nanotube in the membranes could increase the temperature of the first heat-decomposition. Though the heat-decomposition in this experiment didn’t change a lot, we could say that different percent nanotube would affect the membranes’ heat-decomposition. By the experiment of XRD, the membranes with carbon nanotube and the pure PEI membranes attach to amorphous membranes. Nanocomposite’s de-spacing is bigger than pure membranes. In the experiment of air permeability, we compared different kinds of gas or different percent carbon nanotube of nanocomposite if they have some change of permeability. The conclusion is that air permeability increase as the quantity of nanotube increase. The five kinds of permeability the direction：H2>CO2>O2>N2>CH4.The influence of permeability will decrease when the quantity of carbon nanotube increase from 1.5% to 3% or 4%. We can get the conclusion that the increment of gas permeability isn’t limitary. It drifts towards maximal about 1.5%. H2 is 14.89barrer. CO2 is 9.51barrer. O2 is 6.34barrer. N2 is 6.48barrer. CH4 is 3.75 barrer.This experiment totally compared three groups of air selectivity. They ’re CO2/CH4, O2/N2 and H2/CH4. The maximum of selectivity is H2/CH4. The difference of kinetic diameter affects air selectivity a lot. The quantity of nanotube doesn’t associate with the air selectivity, but mixing too much nanotube will decrease air selectivity. The 1.5% nanocomposite has the highest selectivity. If the consistency of the membranes is higher than 1.5%, the air selectivity will decrease. Depend on the gas permeability and the air selectivity, the 1.5% nanocomposite has higher permeability and constant air selectivity. That shows the 1.5% nanocomposite has a better effect on air selectivity and recycling.
Geo-engineering CO2 Scrubber
On account of the rapid development of human activities, much more fossil fuel is burnt and thus a greater amount of greenhouse gases are emitted to the atmosphere including carbon dioxide (CO2). CO2, is considered as the major cause of the exacerbating global warming. “Geo-engineering”, literally, means the options that would involve large-scale engineering of our environment in order to combat or counteract the effects of changes in our atmosphere. As a carbon neutral CO2 scrubber is proposed to be a large-scale scheme to fix carbon globally through reducing the CO2 emitted to the atmosphere and our ultimate goal is to implement the CO2 scrubber scheme to the whole globe, that is, a large-scale scheme to our environment, it is a project of geo-engineering. The procedures of the project are as the following: (a)Investigating on the absorption of CO2 produced by calcium carbonate (CaCO3), using different basic substances at different temperatures (b)Investigating the absorption of CO2 in car exhaust produced by combustion of petrol in car engine using basic solid (c)Feasibility of using a prototype of CO2 scrubber in exhaust pipe of car (d)Feasibility of fixing carbon by turning CO2 into dry ice and stored in deep water (e)Feasibility of growing plant in used basic solution Results: 1.The CO2 scrubber prototype had an average CO2 removal ability over 50%, which was considered to be efficient. The concentration of CO2 (561ppm) was even lower than that in the ambient air (CO2 612ppm). During the experiment, the prototype was closely attached to the exhaust pipe and did not fall down. Thus, a CO2 scrubber was feasible to be used in the vehicles. Besides, our prototype was more energy efficient than LM2500 PE simple cycle gas turbine (consumed 21MW electricity) though our prototype had a lower CO2 removal efficiency. The cost of our prototype would be much lower than membrane technology as the production cost of the membrane was high. 2.Unlike existing CO2 scrubber prototype installed in open area (with electric fan installed), our CO2 scrubbers installed in the chimneys of power stations and exhaust pipes of cars are carbon neutral as exhaust gas has high kinetic energy and would pass into the scrubber. 3.dry ice would not evolve carbon dioxide gas at high water pressure such as at the bottom of the ocean. 4.Plants grew well in alkaline environment, it was feasible to grow plants in basic solution. Conclusion: CO2 scrubber is a suitable choice in combating the climate change through absorbing the excess carbon dioxide, with the utilization of the carbonates produced in the reaction, it is hoped that the climate change can be relieved using an environmentally-friendly device.
攀蜥，攀棲－由台北市內湖金面山區生態因子分析夜晚黃口攀蜥之停棲策略
For this research, the nocturnal perching habits of the lizard, Japalura Polygonata Xantbostona, were examined. Nighttime observations were made from July 2002 to March 2003 in the area along the mountain brook in the south valley of the King-Mien Mountain in Nei-Hu District. The study comprised a series of analysis with discussion of the lizard’s (Japalura Polygonata Xantbostona) perch based on the temperature of living environment and the manner of perch including the dissimilarity between male and female, adults and juvenile lizards in selecting their perch conditions. During the period of study 452 lizards were marked and examined. 163 were female, 168 were male, and 121 were young lizards. The study considered four particulars: (1) orientation, (2) angle, (3) manner of perch, and (4) height of the perch above ground. As for the orientation, most of the lizards chose to perch in an inward (towards the tree) and in an upward direction; the angle of perch was mainly within 1°~ 45° and slanted to 180°. Second, the manner of perch chosen by most of the lizards was holding the stem or trunk by arms. All four groups of lizards exhibited no difference in the orientation, angle and manner of perch. However, male lizards tended to perch at a greater height above ground than the female and juvenile lizards did. The study produced other findings as well: A tendency correlation curve was plotted showing that temperature related with the number of lizards taking perch, and from the curve the optimal temperature of the living environment was determined to be approximately within the range of 19° ~24°. Additionally, there was a relationship between temperature of living environment and the size of lizard and the number of lizards taking perch. A further positive relationship was observed between temperature and the height of perch above ground. Also, the study showed an apparent positive relationship between the temperature of sample living area and the snout-vent length(SVL) of the lizard. Finally, the Japalura Polygonata Xantbostona tended to take their nocturnal perches within a rather fixed home range. 本研究由2002 年7 月至2003 年3 月，於臺北市內湖區金面山南麓溪谷進行黃口攀蜥夜 晚停棲策略研究，以溫度和各項停棲行為進行來分析探討，包括黃口攀蜥的成幼蜥、雌雄蜥 停棲選擇上的差異。 研究期間，共標記到452 隻攀蜥，其中雌蜥163 隻、雄蜥168 隻、幼蜥121 隻。將停棲 的情況分為方向、角度、停棲型態、離地高度四項來分析，在方向上多以朝內、向上為主； 角度多以小角度的1°~45°及180°為主；在停棲型式多以環抱莖枝為主。進一步分析成幼蜥、 雌雄蜥不論在方向、角度、停棲型式的選擇上皆無差異。離地高度的部分則以成蜥及雄蜥的 停棲高度較高；以溫度分析黃口攀蜥的成幼蜥出現停棲隻次、停棲高度、出現停棲攀蜥體型 的相關性，溫度對出現停棲隻次可以做出趨勢相關曲線，估算攀蜥的停棲有一最適宜溫度範 圍約在19~24℃間；溫度與其停棲高度呈現正相關性；每次測得樣區溫度與出現停棲攀蜥平 均吻肛長有顯著的正相關。而黃口攀蜥夜晚婷棲時則會傾向於較固定的範圍內。
台灣水生食蟲植物~ 絲葉狸藻捕蟲行為及消化功能的進階探索
The “Insectivorous Plants”﹐ the first historical publication by Charles Darwin﹐contained the detailed observations and meticulous descriptions of various carnivorous plants and had become the most important reference for the study of carnivorous plants﹒ But the prey mechanism and digestive function of the bladder traps of the Utricularia were not well described﹒ The present study has a great success in these fields which include the volume change of bladder traps before and after firing﹐the spontaneous pressure relief of the bladder traps even without being triggered by prey, and the quadriceps visible absorption process﹒ The last two findings are not yet publicated. This laboratory experiment is carried out with Utricularia Gibba﹐a native species of Utricularia in Taiwan﹒ Through static and dynamic observation﹐we find that bladder traps suck in water by 12-25% of body volume change, and the bladder traps release internal pressure spontaneously under long period of waiting, despite not being triggered﹒ We can also easily demonstrate the absorption process of quadriceps by manually triggering the bladder traps to suck food color solutions. All the events above can be clearly seen under microscopy﹒達爾文是最先對食蟲植物作深入且完整研究的科學家，至今他的著作仍是研究食蟲植物的重要資料，但在其內容中對狸藻捕蟲囊捕蟲行為及消化功能的研究觀察並不完整。本實驗使用簡單的方法，在這方面有突破性的進展，包括捕蟲囊捕食前後的體積變化，自發性舒張及囊內腺毛對於食用色素的消化吸收，後兩項發現及實驗均未曾出現在文獻資料中。 本實驗以台灣本土水生食蟲植物絲葉狸藻(Utricularia gibba)為研究對象，由靜態及動態觀察，顯示捕蟲囊捕食前後體積變化為12~25%，且即使在沒有捕到水中生物的情況下，也會有自發性舒張以解除囊內壓力的現象。捕蟲囊內四爪腺毛消化吸收功能的整個過程，可藉由食用色素加以呈現，並清楚的在顯微鏡下觀察到這些現象。
月亮太陽斜斜掛
In this project, we mainly employ the self-made “positioning system for celestial objects” (PSFCO) to investigate the relations among Sun, Moon, and Earth. Based on the observational data, we then construct a three-dimensional (3D) model to further understand the hidden mystery. We first use the PSFCO, which was developed through four generations (see figure 1), to measure the change for a whole year in the North Polar Distance (NPD) of Sun and Moon individually. From the data analysis, we find that: 1. This change in NPD is very close to a sinusoidal function. 2. The date when the NPD of Moon is the largest in a month shifts earlier by 2.26 days every month on average. 3. The angle between the equatorial axis (EA) and the lunar orbital plane (LOP) is about 63.5 degrees, while the angle between the EA and the ecliptic plane (EP) is about 66.5 degrees. 4. The angle between the LOP and the EP is about 5 degrees. This is exactly why the solar eclipse and the lunar eclipse do not happen every month. 5. Time for a celestial object to be above the horizon = 1080 minutes – 4 (minute/degree) x NPD of the object. We geographically prove this empirical formula. With this formula and the PSFCO, we can accurately predict the times when an object rises and sets. We finally make a 3D model for Sun, Moon, and Earth. In this process, we confronted and then solved several difficult questions in mathematics and astronomy. This research dramatically enhances our understanding in our local planetary system. 主要利用自製的“天體定位儀”來詳細探討月亮、太陽及地球之間的位置及軌道關 係，並藉由三度空間模型的製作來進一步了解其中的奧妙。 首先利用天體定位儀 (共研發出四代，見圖1) 來量測月亮及太陽各自與北極的夾角 在1 年內的變化，經數據分析發現： 一、這個變化很像sin 函數。 二、月亮與北極的夾角發生極大值的農曆日數，每月平均提早約2.26 日。 三、白道面與赤道軸的夾角約為63.5 度，黃道面與赤道軸的夾角約為66.5 度。 四、白道面與黃道面之間的夾角約為5 度。這正是日蝕及月蝕不常發生的主要原因。 五、天體在地平線上的時間(分) = 1080 分－４(分/度) x 天體與北極夾角(度)。我們用幾 何定理證明了這個觀測到的關係式，且配合天體定位儀可準確預測任何可見天體 升上及落下地平線的時間。 最後製作月亮、太陽及地球的3D 軌道模型。過程中遭遇並解決了各種數學及天文 難題，使我們對這個行星系統有了更深一層的認識。
CryptoDefender - afast way to encrypt your files
1. Purpose of the research\r Nowadays, many encryption software are available to computer user. However, very few people use them which result in many cases of information and data leakage due mainly over the Internet. Most people use USB Flash Drive to store and carry confident files back home to work on. When the USB Drive is lost, the files stored are often leaked. To prevent this type of incident occurring, “CryptoDefender” is developed to enhance files protection and to change user’s habit in handling confidential information. \r 2. Procedures\r “CryptoDefender” is an add-in for common application software, e.g. Word, Excel, etc. It will appear as a new tab in the ribbon which provides the software an alternative for saving and opening a file. It protects the files in two ways: encryption and steganography. The data is first encrypted into cipher text as these encrypted data will be hidden in an image file to lower suspicion of readers. All of these procedures will be done by one click. For encrypt and decrypt, the user just needs to click the “Protect” and “Decrypt”. An extremely fast way to encrypt the file is “Quick Protect”. It will randomly choose an image from the image folder according to their file size. This function saves the time for choosing an image.\r 3. Data\r The method for steganography is using last two bit of R, last three bit of G and B to store the encrypted data. In 24-bit bitmap, RGB is represented the color of each pixel and each of them is 8-bit. The leftmost bit of each byte contains the highest value, and the right one contains the lowest value. Therefore, any change in the rightmost byte will only cause a minimal change in a byte value, and the color as well. 2-3-3 method is adopted to replace the pixels as encrypted data. It is used because it is in coordination with the program’s fluency. 2-3-3 is obtained so that 1 pixel will contain 1 byte of encrypted data. For R, the last two bit will be replaced by encrypted data. For G and B, the last 3 bit will be replaced by encrypted data. If the Bitmap size is larger than the encrypted data, random data will be replaced into the remaining pixels.\r 4. Conclusion \r “CryptoDefender” is user-friendly and efficient way to protect important and confidential digital files on most personal computers. This software will help to change the user’s habit in securing their information as to avoid data leakage even when they are accidentally lost.
Transformer Robot
Nicholas’s project is a transforming robot, who he has named Reggie. He's about a foot tall and can transform from a biped into a vehicle and vice versa?\r Reggie has been Nick’s project for just under a year now, mainly working on him in technology classes. He operates without physical connection to anything else, so everything he needs from micro controllers to power is stored somewhere on Reggie’s body?\r Reggie is controlled through a programmable Arduino board (programmed in C++) that is connected up to a motor driver, for controlling the two driving motors and an SSC-32 servo controller for controlling the 14 servos via serial port. The Arduino uses the SSC-32 to coordinate the servos movements using pre-programmed sets of movements stored in procedures in order to complete all actions.\r All the parts were produced on a 3D CAD system to begin with, as well as the robot as a whole, although the design did change drastically over the course of its construction and now is considerably different from the original design as there were many problems and complications ranging from space to torque issues that called for a change in design.\r Most of the parts were from the servo erector set from lynx motion, although some of them were used in the way they were intended to and most of them were modified slightly. Some parts Nick manufactured himself either on a rapid prototyping machine, a lathe or milling machine and sometimes a combination of them or even high temperature soldiering?\r Currently Reggie is capable of driving and standing up and is currently radio controlled. He will eventually be capable of walking and modifications to allow him to (such as stronger leg servos) have been made to facilitate that, but it is possible more may have to be made.