全國中小學科展

三等獎

快速合成金屬有機骨架複合材料用於微量工業廢氣吸附移除Rapid synthesis of metal-organic framework composites for removal of trace industrial waste gases

本研究開發一種新穎孔洞性吸附材料:金屬有機骨架 (MOF)。MOF 在反應溶液中自組裝形成孔洞結構,透過物理吸附有效捕捉氣相乙酸分子。研發出綠色、快速可在常溫常壓下大量合成三種MOF(HKUST-1(Cu)、UTSA-280(Ca) 及 A520(Al))方法。此外,為提升材料機械強度和應用價值,採用 PVA 聚合技術製備 MOF 複合物,使其造粒型化更易處理,提升商業和環境應用價值。吸附實驗結果顯示,HKUST-1(Cu) 粉末對乙酸移除率高達98%,而HKUST-1(Cu) PVA 複合物達93%,對比活性碳及其PVA複合物(移除率分別為85%和78%)表現更優異。MOF憑藉優異吸附性能和可大量生產低成本優勢,成為極具潛力有機無機氣體吸附劑,可為半導體產業提供一種維持高標準製程環境精密且簡便解決方案。

Revolutionizing Metabolic Health: The Therapeutic Potential of Next-Generation Probiotic Akkermansia Strains (Z62, IR119) for Metabolic Syndromes

The human gut microbiome is integral to digestion, overall health, and metabolic disorder imbalances. Recent advancements in fecal microbiota transplantation (FMT) have highlighted the therapeutic promise of restoring healthy gut microbiota in populations with high incidences of diseases. Focusing on fecal DNA samples from healthy Asian individuals, this study examines the potential of novel Akkermansia strains, specifically Akkermansia muciniphila (Z62) and Akkermansia massiliensis (IR119), as next-generation probiotics for mitigating metabolic syndrome. A key aspect of the study is the investigation of short-chain fatty acids (SCFAs), which are produced and play a crucial role in regulating metabolic processes. SCFAs such as butyrate, acetate, and propionate are essential for energy provision to colon cells and exerting anti-inflammatory effects. The methodology involves selecting two Akkermansia strains, analyzing them through 16S rRNA and WGS, evaluating their growth and survival rates under acidic and bile-salt conditions, alongside their cell adhesion capabilities. The study focuses on the production of key short-chain fatty acids (SCFAs) and tryptophan derivatives by bacteria in regulating metabolic processes, as well as their anti-inflammatory effects on colon cells. Through in vitro assays, both strains exhibited survival in acidic/bile-rich conditions, though Z62 demonstrated superior adhesion to Caco-2 cells, suggesting a higher colonization potential. Metabolomic analysis revealed both strains produce SCFAs, including propionic and acetic acids, and indole metabolites, such as indole-3-propionic acid and indole-3-acetic acid, which are known to influence lipid metabolism and insulin sensitivity. In adipocyte cell models, IR119 significantly reduced lipid accumulation, while Z62 increased lipid presence. Furthermore, IR119 reduced pro-inflammatory cytokine levels, including IL-6 and TNF-α, suggesting potential for inflammation mitigation. The future potential of IR119 as a therapeutic probiotic is extraordinary in addressing complex metabolic and inflammatory diseases, which open new avenues for managing chronic inflammatory conditions like type 2 diabetes and cardiovascular disease. Future clinical trials could refine IR119’s efficacy, positioning it as a leading probiotic in preventive and therapeutic contexts.

開發回收PET合成UiO-66並應用於催化合成羥甲香豆素

本研究利用乙二醇處理後的聚對苯二甲酸(PET)及氯氧化鋯,以創新的無溶劑方式”solvent-free PET-to-MOF conversion”合成一類金屬有機框架材料(MOF) ── UiO-66(Zr),並發現此材料可用於催化Pechmann condensation、以間苯二酚和乙醯乙酸乙脂合成羥甲香豆素。於190℃之環境下,乙二醇處理6小時的EG-PET可合成出晶型最接近模擬模型的UiO-66晶體;而我們開發的合成方法中,最佳的反應條件為反應物質量比(氯氧化鋯:PET)= 2:1、130℃合成24小時。 對於合成出的UiO-66(Zr),我將其進行了XRD、FTIR、BET、SEM檢測,結果符合UiO-66(Zr)的特徵;唯比表面積僅有約900 平方公尺/克,推測此方法合成出的材料之有機linker數量和一般UiO-66(Zr)有所差異。 對於催化合成羥甲香豆素之反應,我們首先發現UiO-66(Zr)可作為非勻相催化劑參與此反應;且實驗結果顯示,相較於溶劑熱合成的UiO-66(Zr),以本研究的方法所得之UiO-66(Zr)作為催化劑可得到更高產率的羥甲香豆素。

探討在秀麗隱桿線蟲中IFE-1經由sRNA路徑對於精子生成機制的影響

sRNA在各種物種的精子功能中起著至關重要的作用。在秀麗隱桿線中,當缺少精子相關的sRNA「ALG-3/4 26G sRNA」會導致其在25度時不孕。此外,IFE-1是人類真核轉譯起始因子EIF4E的直系同源基因,主要表達於雄性生殖細胞系統中。在先前研究中我們觀察到當「真核轉譯起始因子IFE-1有缺陷」或「精子缺少相關sRNA」時,亦會導致精子具有缺陷。由於三者的相似性,我們認為IFE-1和26G sRNA的生成路徑有關。因此我們假設IFE-1參與協助酵素NYN-3辨認並切割msd-1 mRNA模板後促進26G sRNA生成。我們使用Western Blot、IP、螢光顯微鏡等方法,探討了IFE-1和MSD-1::GFP的關係,發現在ife-1正常的情況下,高溫對於MSD-1::GFP的表現量沒有影響。並且因該蛋白只表現在公蟲精子,我們可以推論msd-1:gfp 只作用於公蟲精子。而此疑似可正向調控基因表現的26G sRNA,有望發展成有別於過往sRNA藥物抑制基因表現的一種新基因治療方法。

DSUP: New Research On The Implementation Of Radioresistance In Cellular Systems

In radiation treatments and manned interplanetary space travel, radiation is one of the biggest problems. The radiotolerance of cancer cells makes it necessary to apply high doses to surrounding healthy tissues by subjecting the cells to heavy stress. With regard to space travel (which involves a minimum travel time of 6 months) (1,2) the danger concerns cosmic radiation which is capable of inducing genetic mutations that, in turn, can evolve into very serious pathologies, such as cancer, damage to dendrites consequently compromising synapses. The project is aimed at developing a technology that can address these issues and aims to make human DNA radioresistant. This study involves a nucleosome-binding protein called DSUP (Damage Suppressor Protein) unique to the tardigrade Ramazzottius Varieornatus and the subject of its radioresistance. It can theoretically safeguard genetic material damaged by radiation. *Internship theme at the Pino Torinese Astronomical Observatory and the DISIT-UPO Environmental Molecular Toxicology Laboratory. The study molecule: Numerous tests have been carried out through the "in silico" approach geared toward mathematical modeling of its protein structure and complex mechanisms of action simulated through artificial intelligence systems, followed by direct laboratory analysis involving biosynthesis of DSUP by genetically modified bacteria and related tests. Both approaches, applied synergistically, aim to make it accessible and useful for the protection of human health.

自監督學習在臺灣手語辨識上之應用研究

在臺灣手語辨識,先前研究所使用的監督式學習需要大量標記樣本而限制可辨識詞彙量。為此,本研究借鑒自然語言處理領域中BERT 的遮罩想法,將未標記手語影片隨機遮蓋部分幀數,並讓模型學習預測被遮蓋的幀數以學習臺灣手語的特徵,並透過遷移學習來訓練辨識模型,此作法可克服現有臺灣手語資料缺少的問題。經過實驗,本研究訓練之詞彙辨識模型達成了242 個詞彙量,94.8%的準確率。 此外,先前研究皆未在手語句子翻譯上有成果。因此本研究基於預訓練模型,整合設計手語翻譯的系統,實驗中,系統在100 個句子的翻譯表現達到88%的準,且BLEU-4 分數取得20.98,證明自監督學習的方式在手語辨識、翻譯上是有效的。並展現出樣本需求少與辨識詞彙量可輕易擴大的潛力。

Exploiting the beneficial role of Biochar and Titanium (Ti) as a Sustainable and Green Strategy for Improving Agricultural Output in Saudi Arabia: Wheat as an Using Wheat as a Model

The present research work aimed to assess the impact of biochar (BC) amendment (5%) and foliar supplementation of titanium (Ti) at a concentration of 50 mg L-1 TiO2 on the growth, chlorophyll content, and biochemical parameters of wheat (Triticum aestivum L). The results demonstrated significant improvements in several aspects of wheat physiology due to these treatments, both individually and in combination. Plant height, as well as fresh and dry weight of wheat, exhibited substantial increases when subjected to Ti and BC treatments, with the highest enhancements observed in plants treated with both Ti and BC. Furthermore, chlorophyll content, including chlorophyll a, chlorophyll b, total chlorophylls, and carotenoids, showed marked increases in response to individual Ti and BC treatments, with even greater improvements when both treatments were combined. In terms of biochemical parameters, the content of proline, sugars, and free amino acids significantly increased in plants grown in soils amended with BC. Additionally, foliar Ti treatment led to elevated levels of these biochemical constituents. The combined treatment of Ti and BC resulted in the most pronounced effects. Moreover, oxidative damage parameters, such as hydrogen peroxide, lipid peroxide, and electrolyte leakage, were notably reduced in plants subjected to Ti and BC treatments, either individually or together. The activity of antioxidant enzymes, including superoxide dismutase, catalase, and ascorbate peroxidase, exhibited significant increases in response to Ti and BC treatments, further emphasizing their beneficial effects on wheat plants. Overall, this investigation shows that biochar amendment and titanium foliar supplementation both have beneficial effects on wheat development and biochemical parameters; these findings may be relevant to efforts to increase crop productivity and stress tolerance.

雙向隨機生成數列的長度探討

本研究探討隨機生成數列的長度期望值。一個籤筒中有n支籤,編號分別為1,2,3,…,n,每抽出一支籤,就將抽取的編號寫在紙上,形成一個數列。數列只能向左右兩端添加項,不能從中插入。抽出的籤若大於目前數列的最大項,則將抽出的數寫在目前數列右邊;抽出的籤若小於目前數列的最小項,則將抽出的數寫在目前數列左邊;抽出的籤若介於目前數列的最小與最大項之間,則操作結束。基於此想法,研究者將數列依照添加項的方向分為「單向數列」與「雙向數列」兩類。顧名思義,單向數列只能向一端延伸(本研究不失一般性討論往右延伸),雙向數列代表可以向左右兩端延伸。此外,研究者又將數列分為「嚴格遞增減」和「非嚴格遞增減」兩類。在生成原理上,嚴格遞增減等價於「抽後不放回」;非嚴格遞增減等價於「抽後放回」。在這樣的規則下,本研究探討了n支籤抽完放回與不放回時,單雙向隨機生成數列的長度期望值之通解,並成功證明了一些恆等式及性質。

攻角對水漂跳動行為的力學分析

此研究是以實驗方式,驗證理論模擬中指出水漂在不同入水模式下,入水攻角為 20 度時皆可產生最佳的彈跳效果。因此我以壓克力板作為模擬水漂的模型,設計了以下四組操作變因,分別是入水攻角、水的流速、水漂邊界形狀以及接觸面的粗糙程度,接著透過Tracker 分析壓克力板的質心彈跳高度及運動軌跡,再利用 Excel 分析數據,找出其中的運動相關性。最後透過座標轉換,可以利用此實驗來分析打水漂的運動行為,成功發現入水攻角在 20 度時的確有最佳的彈跳效果,並以此實驗結果來優化打水漂的運動行為。

矩形密鋪及其應用

「在格狀平面中用矩形以互不重疊的方式鋪滿(2D rectangle tiling problem)」為一NP-complete問題(Dani`ele Beauquier et al ,1995),目前多項式時間只能求出盡可能覆蓋最大面積的近似解。本研究所創的階梯演算法 stair algorithm 透過改變動態規劃紀錄狀態的方式,使狀態數大幅減少,進而改善求準確解的時間複雜度,也成功證明此演算法的正確性。本研究的演算法可被應用於平行計算中的負載平衡、積體電路設計等方面。隨後,本研究寫了一個互動展示品清楚呈現此演算法的功能。且以階梯演算法成功檢驗並比較 RTILE PROBLEM 的 7/3-approximation algorithm (Krzysztof Lorys and Katarzyna E. Paluch,2000 [4]) 與 11/5-approximation algorithm (Piotr Berman et al,2001[7])進行比較與分析。