全國中小學科展

四等獎

In Silico Carotenoid Compound with Protein in Durian (Durio zibethinus Murr.) Seed Waste and Hedonic Test Innovation in Making Healthy Cereal Organic (HCO) (Nutrient-rich Functional Food Alternative)

Durians’ seeds have potential as a food source due to their content and nutrients. Durians’ seeds contain fiber, minerals, vitamins A, B1, B2, C, carbohydrates, folate, potassium and copper. Nutrients are needed for the body's health and growth and development process. Durians’ seeds have the potential as a nutrient-rich food alternative. Researchers made an innovation in the form of cereal, Healthy Cereal Organic (HCO). Analysis of durians’ seed content through two stages. First, wet lab examination and second, in silico method. The wet lab examination shows the results that durians’ seeds contain 10.17 Kcal of fat energy, 4.09% ash content, 11.25% water content, 72.79% carbohydrates, 1.13% total fat and 10.74% protein and the in silico method shows the content of carotenoid compounds (vitamin A, quercetin, beta-carotene, zeaxanthin) as a drug delivery system which means that this compound is able to be absorbed by the body with the help of albumin as a carrier that maintains stability and increases its activity. Feasibility analysis based on toxicity tests, Durians’ seed compounds show inactive (non-toxic) results. Allergenicity test showed non-allergen durians’ seed content. Hedonic test was conducted on 20 panelists dominant to the HCO1 sample for aroma by 60%, texture 90%, taste 40%. It can be concluded that durians’seeds can be used as a basic ingredient for making nutrient-rich Healthy Cereal Organic (HCO).

石墨烯-銀異質結構的優化與功能開發 The Optimization and Development of Graphene/Ag-doped heterostructure

從家用微波爐到3C產品,皆有微波電磁干擾 (Microwave Electromagnetic Interference, MWEMI)的防蔽設計需求。依據2020年科展競賽作品中的薄層微量雙金屬催化技術可製得 Graphene/Ag-doped異質結構,但該作品未曾研究此材料的防蔽 EMI 能力。本研究優化此技術,成功將銀奈米結構沉積在石墨烯的缺陷及晶界邊緣,相關技術與實驗參數(化學氣相沉積法的加熱溫度、時長和通氣量)已發表於2023年科展競賽作品。本研究進階發現 Graphene/Ag-doped異質結構具高透明度和屏蔽 MWEMI 的能力,單層膜可屏蔽60%之 MWEMI,效能優於文獻上記載的2~3層石墨烯。而依據2023年文獻說明單層奈米碳管 (MWCNTs)異質結構經氟化處理後,可大幅提升 MWEMI 屏蔽效能,因此我們也將 Graphene/Ag-doped材料經由四氟化碳電漿處理,氟化後的屏蔽效能又比單層石墨烯-銀高出15倍,可遮蔽高達99.9%的 MWEMI。

A Study on Hybrid Electromechanical Actuators

An actuator [7,22,28,29] is a motion control mechanism. Depending on the type of actuator, it can convert one type of energy (e.g. chemical, electromagnetic, thermal) into mechanical energy. The field that laid the foundations for the realization of actuators is the field of electromechanics, whose evolution was common with that of actuators. Thus, a periodization of the electromechanics paradigm includes 3 major stages [7,6,25,28,29]: I.1830-1950 Old electromechanics. It is the period when the development of electric cars is significant, which imposed the appearance of classical or primary electromechanical drives. It was a generous nineteenth century, dominated by the scientific results of the triumvirate: Michel Faraday (initiator of fundamental empirical experiments in the history of electricity; the law of induction, of the principle of electric motor, of the magnetic circuit, initiator of electro-chemistry), James Clerk Maxwell, (the genius theorist who put into mathematical form the equations of electric and magnetic fields, as well as the connection between them), and Werner Siemens (engineer and capitalist genius manager who managed to exploit and validate the relationship research-technology-economic development), triumvirate that can be disputed in the sense that other scientists also made outstanding contributions to the history of electricity: Edison, Ampere, Ohm (to name but a few who do not exhaust a significant list). Industrial production of electric machines also appeared and the first signs that will announce the emergence of electromechanical actuators as a basis for military applications. II.1950-1970, Traditional electromechanics, in which electrical power drives appear, a theoretical and experimental development on the emergence of new material and electromechanical principles. Much military research (such as missile control or ship and torpedo control) influences and produces the transfer of applications in ordinary life, including the actuator subfield. III. 1970-2020, Avant-garde electromechanics, representing according to Thomas Kuhn's theory, a paradigm forcing [30]. It is worth noting the contributions of the new scientific revolution. - Specific technologies of miniaturization, by material deposition. - Elastomeric polymeric materials with the help of which it was possible to make electrostrictive actuators, - Very special means of investigation, mainly the development of microscopy, - Gradient of applications in the field of medical engineering, with outstanding contributions both in investigation and microsurgery, applications of actuators in biological micropumps, etc. [25,27,28,29].

探討自我參照和社會訊息對不同年齡、性別連結記憶的影響

連結記憶(Associative Memory)為記憶兩物體之間關係的能力,會隨著年齡增加而衰退。先前研究顯示不同性別在記憶的老化程度存在差異,然而針對連結記憶在不同性別的老化未被討論。過去研究發現自我參照效應以及改變刺激材料的社會訊息程度可提升連結記憶的表現。然而缺乏同時使用兩種方法研究,兩者之間的交互作用尚不清楚。本實驗分別針對不同年齡與性別的群體進行連結記憶測驗。我們引導受試者使用自我參照記憶具有不同社會訊息程度的圖片,測量其連結記憶表現。結果顯示,女性有顯著的連結記憶衰退;而男性沒有顯著的連結記憶衰退,其記憶衰退可能與項目記憶有關。另外,我們也觀察到參照與社會訊息對連結記憶的影響具有交互作用,在未來實驗中有必要注意兩者之間的互相影響。

ZIFs與釩氧化物作為鋅電池陰極材料之應用與性能研究

本研究旨在優化鋅離子電池陰極材料的性能,選用沸石咪唑酯骨架材料(ZIFs)與釩氧化物(V6O13)進行複合材料的合成與應用。隨著鋰電池成本的上升,鋅離子電池因其安全性與成本效益逐漸受到重視。ZIFs 具有高比表面積及良好的離子導電性,而V6O13則因多價態和優良導電性而成為潛力材料。通過結合這兩種材料,我們開發了具有多孔結構和優異穩定性的複合陰極材料,再使用 PXRD、SEM 及 EDX 對材料進行結構表徵,並使用此新材料製作鋅離子電池進行電化學性能測試。結果顯示,熱裂解後的 PY-VxOy@ZIF-Zn/Co具有最佳的克容量及穩定性,且在500次循環後保持良好的穩定性。本研究展示了ZIFs和V6O13結合在鋅離子電池中的應用潛力,為低成本、高效能的儲能解決方案提供了新的方向。

The Effects of Background Color on Color Preference 探討不同背景顏色對色彩偏好的影響

色彩偏好影響生活的許多決策,對於背景對色彩偏好的影響,現行兩個色覺理論(對比理論與生態價理論)有不同的解釋,本研究以高中生為對象,旨在探討背景對色彩偏好影響與支持理論,並提出運用方向。 之前色彩定量方式缺乏對敏感度與視錐細胞的考量,本研究發展以中性灰為基礎對不同色彩的定量方法,並以此進行色彩偏好測試。實驗結果發現:顏色偏好會受到背景影響(支持對比理論),背景對各色彩具不同影響力,偏黃偏綠顏色受背景影響較大;綠色與藍色背景提升偏黃與偏綠之顏色偏好而紅色背景則會下降(支持生態價理論),背景亮度不影響顏色偏好。期望研究結果有助於青少年環境與產品設計配色參考,並對未來背景影響顏色的神經機制研究提供基礎。

觀音山火山熔岩與其礦物比例研究 A Study on the Mineral Ratios of Guanyinshan Volcanic Rock

透過親手磨製岩石薄片及礦物比例數據,探討觀音火山熔岩的差異與其差異原因。根據前人研究得知,觀音山經過五次噴發,共有七種不同的火山岩。比對地質圖,尋找各層出露地點共17處,進行田野調查、空拍記錄及樣本採集,並磨製岩石薄片共14片,進行岩相觀察與礦物面積比例計算。 本研究觀察到觀音山熔岩有漸變關係,符合鮑氏反應序列。從橄欖石玄武岩→普通輝石玄武岩→普通輝石安山岩→兩輝石安山岩→紫蘇輝石安山岩→黑雲母角閃石安山岩。 並依據新的田野調查資料,修正觀音山的地質圖資;建立火山噴發歷程模擬動畫;製作立體地形模型,以瞭解對地質地貌關係,皆可做為日後觀音山地球科學教育之參考。

Application of Carbon Aerogels in Lithium-Air Batteries

One of the main challenges with today’s batteries is their relatively low volumetric and specific capacities. The highest specific capacity can be achieved with lithium-air batteries, which use metallic lithium as the anode and typically some form of porous carbon as the cathode. To enhance performance, aerogels—among the world’s lightest solid materials—are ideal candidates for cathodes. Resorcinol-formaldehyde (RF)-based carbon aerogels, for example, serve this purpose well. In my work, I utilized two types of carbon aerogels as cathode materials: one derived from pyrolyzed resorcinol-formaldehyde polymer and the other a graphene-oxide-modified version of this carbon gel. I integrated the carbon aerogels I had pyrolyzed into lithium-air batteries to improve the cell’s performance, energy density, and capacity compared to cells using activated carbon. In my research, I examined the pore structure and surface properties of these materials in aqueous media using NMR (nuclear magnetic resonance) relaxometry and cryoporometry, exploring their impact on battery efficiency. I found that the graphene-oxide-containing sample's pores filled with water in a layered manner, indicating a more hydrophilic surface, which suggests a denser arrangement of oxygen-containing functional groups compared to the unmodified carbon aerogel. The pore sizes were reduced after adding graphene oxide, resulting in an increased specific surface area for the sample. Incorporating the reduced graphene-oxide-containing carbon aerogel enabled the creation of a more efficient, higher-capacity battery than with the RF carbon aerogel. This improved performance is likely due to the aerogel’s higher oxygen content and altered morphology. The increased oxygen content provides more active sites for oxygen reduction, meaning that a greater specific power output can be obtained from the battery.

In silico Screening of Forty Antiviral Phytochemicals as Inhibitors to the Envelope Protein of Dengue Virus Serotype 2 (DENV-2)

Infections by the Dengue virus (DENV) cause a disease amonghumansreferred to as Dengue fever, which causes thousands of fatalities globally. There is no existing treatment as of yet that successfully targets DENV. Among the factors thatdeterminetheentry of the virus and severity of the disease is the envelope(E) protein of DENV. This study aimed to examine forty antiviral phytochemicals enumeratedinpaststudiesaspossibleinhibitorstotheEprotein of DENV to provide candidates to aid in drug discovery against DENV. The phytochemicals were screened for their likelihood of inhibition of the E protein using AutoDock Suite and LigPlot+. Seven phytochemicals produced favorable binding affinities to the E protein, which are based on the interactions between the phytochemicals and amino acidsintheactivesiteoftheEprotein.Lipinski’s rule of 5 was then used to screen the seven phytochemicals for oral bioavailability. Glabridin has a binding affinity of -7.6 kcal/mol and was predicted to be orally bioavailable. This phytochemical interacts with amino acids in the E protein active site through hydrogen bonds to Asn355, andPhe337, as well as ten hydrophobic interactions. These interactions ensure that glabridin is able to specifically target and fit intotheactivesiteoftheEprotein, preventing its binding to the host cell and activating its viral proliferation. Glabridin is known to be found in the roots of licorice plants, providing anatural source for a possible cure for Dengue fever.

從幾何分析到正n邊形線段n次方和之探討

本研究要探討在兩同心圓,大圓的內接大正五邊形和中心在小圓上移動的小正五邊形在固定邊長、圓半徑的情況下,不論小正五邊形在圓上如何移動,其對應頂點的距離平方和、四次方和為定值以及頂點至對應邊的距離的總和、平方和為定值並試著推廣至正n 邊形並找出它們的定值為何 。