全國中小學科展

四等獎

不同氮源的氮氧化鈦可見光光觸媒之製備與性質探討

本研究擬利用液態合成法,以尿素(urea)、硫脲(thiourea)與氨作為摻雜物與市售之TiO2粉末均勻混合,製備高活性於可見光下應答之氮掺雜的二氧化鈦奈米光觸媒(TiOxNy)。探討氮物質來源與濃度、合成時間與鍛燒程序對於生產之氮氧化鈦的性質影響。合成之氮氧化鈦粉末將利用X光繞射儀(XRD)、掃瞄式電子顯微鏡 (SEM)、紫外光-可見光分析儀(UV-Visible analyzer)進行材料特性分析(如結晶型態、表面型態與能階)。在實際光觸媒分解污染物之應用方面,由於亞甲基藍呈色容易且較易量測,將作為污染物用於做氮氧化鈦之初步效能評估。研究結果發現:摻雜不同氮源之氮氧化鈦光觸媒與純二氧化鈦結晶相似,且並未發現其他雜相形成。透過EDS N Mapping,可證實氮原子確實分佈在二氧化鈦上。本研究製備之不同氮源的氮氧化鈦可見光光觸媒的吸收範圍確實提升。其中,又以硫脲(Thiourea)為最佳,且其光降解效能最佳。

聖嬰現象與西北太平洋颱風之關係

我們透過1970~2010 年西北太平洋颱風的資料分析,探討聖嬰現象與颱風生成、路徑、強 度和消亡的關係。我們發現,聖嬰現象發生時颱風較晚生成,颱風季較短,且生成後路徑偏 北,東北亞國家受到颱風侵襲機率增加,反聖嬰時期颱風則較易侵襲東南亞。在夏季,臺灣 於正常期比較容易受到颱風的侵襲,而反聖嬰現象發生時,秋颱侵台的機率增加,臺灣須嚴 防秋颱的威脅。雖然聖嬰期颱風生成月份較晚,但生成位置遠離陸地,使平均壽命較長,颱 風強度也易增強。統計結果也顯示,颱風的消亡與聖嬰現象無明顯關聯性。

利用I.M.S.即時顯示系統建立資料庫,在重金屬污染監測上之應用

本研究以設計即時監測系統(Instant Monitoring System 簡稱 I.M.S.) 為目標,利用電解質導電原理,設計LED顯示系統,即時顯示土壤與河川受到重金屬污染。 電解質水溶液,在通電發生電泳運動時,不同的離子的水溶液電阻,會呈現出振盪的特殊性,可作為離子種類的判斷條件。藉由約105筆實驗數據,作七種重金屬離子的定性比對, 可以快速的比對出不同重金屬離子的濃度與種類。本實驗的設計與使用有以下的優點 : 一、 無論樣品電阻大小均可使用。二、 利用簡易工具,可輕易檢測出廢水內離子濃度的範圍與種類。三、 可作為檢測電泳與導電性質的輔助工具。四、 操作簡便,可廣泛使用。

多層元件含末端雙鍵官能基的電洞傳輸應用於OLED

使用濕式製程在製備多層元件時,最大的困難是如何避免前一層的薄膜被後一層的溶液溶解。本研究合成末端具有雙鍵且可熱交聯之材料(FTV),經熱處理後形成具有溶劑阻抗性之網狀結構,再塗佈發光層做多層元件,使得製程上較簡易,成本也較便宜,較於傳統製備多層元件需以蒸鍍方式來製作,濕式製程是更為方便。 FTV作為電洞傳輸層,元件結構為ITO/PEDOT:PSS/ FTV/PF/LiF(0.5 nm)/Ca(50 nm)/Al(100 nm),製備為濕式製成的多層元件。並且嘗試不同濃度和轉速尋找電洞傳輸層FTV的最適化條件。本次實驗找出濃度為0.25%,轉速3000 rpm條件最佳,亮度和效率分別為2625cd/m2 and 0.17cd/A,效果遠高於沒有添加電洞傳輸層FTV的元件(795 cd/m2,0.04 cd/A),為重要發現。 

Construction of an Emergency Portable Dynamo Mobile Phone Charging Station by Means of a Hand-Crank Gear Mechanism/ Solar Panels

The researchers aim to construct an emergency mobile phone charging station that runs on renewable energy and will serve as a cost-efficient alternative to more traditional power banks. Circuit components include a 20V / 6W solar panel supplemented by a hand-crank gear mechanism integrated with a 6V / 1A lead-acid battery, a usb output and an adjustable switch-mode power supply (SMPS) to convert excess voltage into current. Initial voltage and current outputs were measured under varying resistances. It was determined that the set-up satisfied the minimum voltage and current requirement for charging a mobile phone (5V / 1A). A subsequent phone charging test was executed using a Samsung Galaxy J2 (3.85V Li-ion battery 7.70W, Charge Voltage: 4.4V / 2000mAh) wherein it charged on an average of 0.277% per minute for the solar panel and an average of 0.263% per minute for the hand crank gear mechanism. A Mann-Whitney U statistical test was conducted to determine if the charging rate of the charging station had a significant difference from a commercially available power bank’s. The calculated UA: (4) from the test was below the lower limit and the UB: (217) was above the upper limit which indicated that there was a significant difference between the charging rates. While the efficiency was lower than the commercial power bank’s, it can still be used as an alternative charging method especially during emergencies and disasters.

Beautiful Butterfly: The Physics Behind The Colors

Even as a child, I was fascinated by the colors in nature, such as rainbows, butterflies and flowers. This fascination developed into curiosity with age, and as my school studies developed, I became particularly interested in the scientific aspects of the origin and development of colors. I wanted to answer the question: How are the different colors of the butterfly wings related to the nanostructures of scales and pigments? The color on the butterfly wings results either from the pigmentation (chemical color) or from the structure (physical color) of the wing scales. Colors such as yellow, black, red and brown are mainly created by pigments. The interaction of light and structures in and on the surface of butterfly wings, often the size of the wavelength of the light, results in physical colors. These colors are usually bright and dependent on the viewing angle (unlike chemical pigments that spread light diffusely). The colors produced here are usually golden, green, purple and blue. But, where do these colors come from and why do certain species dazzle more than others? To get to the heart of the matter, I identified two key questions: • How are the different colors of the butterfly wings related to the nanostructures of scales and to the pigments? • Using the nanostructure, can you find out the wavelength of the reflected light? In this work, I focus on the structural colors of butterflies and study the physics behind them. This includes parachuting in areas such as diffraction gratings, scattering of light, interference in thin films, and multilayer interference. In order to experience the greatest possible diversity, I selected butterflies from different species for the measurements. Using the spectrometer, I measured the light reflected from butterflies. High-resolution microscopes such as the laser microscope and the scanning electron microscope gave me the opportunity to study the detailed nanostructures of the wing. In addition, I was able to analyze and evaluate my results using existing physical models and MATLAB simulations (Maxwell equations).

Application of molecular templates on magnetic particles for adsorption and desorption of heavy metals

This study investigated the production of novel molecular templates, and analyze their adsorption effect on four heavy metal ions (Cu+2, Pb+2, Zn+2, Mn+2), which commonly exist in Taiwan's rivers. Different operating conditions (such as competitive adsorption, pH value and other factors) were explored to compare their adsorption effect of heavy metal ions by using the synthesized template molecules. The molecular templates were found to be specific towards their target metal ions with a high adsorption effect. Then combined with the idea of magnetic particles to produce magnetic molecule templates, a maximum amount of adsorption of heavy metal ions up to 95% through the molecular template was achieved while the effect of heavy metals desorption of up to 83% could be also successfully obtained. Experimental results showed that the magnetic molecule templates did not affect the adsorption of heavy metal ions. Not only can they speed up the recovery time of adsorption but the template molecules can also be collected more efficiently. We also proposed three different applications for the developed molecular templates. The development of magnetic molecular template may provide an affordable, highly-efficient way for dealing with heavy metal pollutions.

昆蟲拍翅的氣流研究

本實驗藉由肥皂泡膜色彩擾動觀察拍翼機拍翅時周圍的氣場流動,用以模擬昆蟲拍翅時流場模式,利用肥皂泡膜黏滯係數和空氣相似,且有色彩擾動等特性觀測拍翅機的渦流流場。並利用泡膜厚度與顏色關係,畫出厚度梯度圖分析渦流相較於風洞,肥皂泡膜的流場即便在拍翅機經過的後方依舊能清楚呈現,但風洞在拍翼機後方的流場則會因為擴散而消失。

勻稱分割

本研究主要透過不同的向度與規則,延續之前的研究。我們證明了頂點組態僅含有單一種秩數的 勻稱分割共有5種;頂點組態中含有兩種不同秩數的 勻稱分割,其 的最大值為5,共有13種;頂點組態中含有三種不同秩數的 勻稱分割,其 的最大值為4,共有3種;而頂點組態中含有 種不同的秩數的 勻稱分割在 時無解;最後,我們透過GSP軟體將所有解的圖形繪製出。

使用機械手臂實現黑白棋之人機對弈

由工業4.0智慧生產的啟發,建構機械手臂進行人工智慧黑白棋之對弈系統,透過視訊分析棋面資料,輸入人工智慧黑白棋遊戲判斷。依據結果指揮機械手臂進行落子、取子的動作,人機對奕過程亦會判斷有無不合理的地方,以維持棋奕的規則公平。擷取雲端攝影機的盤面影像,使用霍夫找圓演算法取得棋目位置,透過彩度與明度分析黑子、白子或無子,黑白棋AI程式再透過遊戲樹演算決定落子、取子位置。透過畢氏定理及餘弦定理將棋子位置的立體座標轉成工具座標,再傳送至主控伺服器以指揮機械手臂進行正確的動作。透過減輕重量及使用彈力平衡力矩改善,機械手臂可改善硬體準確度,重現率測試達85%以上。黑白棋AI程式棋力可以與黑白棋app的3級力敵。視訊判斷棋局在調整適當彩度明度後可達100%正確率。透過演算法指揮機器手臂下棋,棋局中完成正確動作可達80%以上的成功率。