全國中小學科展

四等獎

不同種類與濃度的金屬奈米粒子輔佐NaBH4還原對-硝基苯胺反應速率常數的研究

L-多巴在酪氨酸酶的作用下,可以轉換成多巴醌,多巴醌繼而自發轉變為黑色素,在此實驗當中,利用帶有青枯病菌的酪胺酸酶基因片段pBAD-518458-bbr的大腸桿菌(E. coli DH5α)將L-多巴轉換成黑色素,然後將微生物去除,只保留黑色素,以避免之後的實驗受到細菌的干擾。 分別將四種金屬離子,Au3+、Cu2+、Co2+、Pd2+ 以1.0 mM的濃度加入黑色素中,使黑色素將金屬離子還原成金屬奈米粒子,形成含有黑色素與金屬奈米粒子的混合溶液。將黑色素去除,避免之後測吸收時受到干擾。再以冷凍乾燥機抽乾乾燥,去除水分以利保存。 將對-硝基苯胺與已乾燥的金屬依照一定濃度加入96孔盤中,再加入硼氫化鈉當作還原劑,也是提供氫陰離子的來源,將對-硝基苯胺還原成對-苯二胺,用Multi-Mode Microplate Reader (BioTeK)測每隔10秒波長385 nm的吸收,再將數據整理成反應速率常數。在四種金屬當中,奈米金的催化速率最佳,所以選擇金屬金以濃度0.1、0.5、1.0 mM作濃度的探討。

Physical Characterization of a Wide Aperture Segmented Reflector Telescope

Characterization of telescope lenses using physical optics and selection of the optimal physical parameters of a reflecting telescope’s optical units were done to improve the design, cost-efficiency, and quality of the 64-cm telescope (named Oof) housed at the National Institute of Physics. Characterization has been done through numerical modeling of the point spread function (PSF) in Python. The PSF code was based on the method of getting wave vectors by Richards and Wolf. The optimal PSF was established to be the PSF of a large monolithic mirror. The PSF of a single optical lens was compared to its counterpart segmented lenses. Through the comparison of maximum intensity, the normalized mean square error (NMSE) and the Linfoot’s criteria of correlation quality, fidelity, and relative structural content, the study has produced results which proved that highly segmented optical components produce results with less quality compared to less-segmented optical components. It was found that as the segmentation increases, the maximum intensity decreases. Higher values of maximum intensity denote higher light gathering power. The normalized mean square error of the set-ups having one to seven layers had values greater than zero but less than one. This denotes that the PSF of those set-ups are near the PSF of the optimal set-up. Higher values of correlation quality, fidelity, and relative structural content denote higher correlation, higher signal to noise ratio, higher closeness of correspondence between the optimal set-up and the segmented set-up. The number and the size of the optical components of the segmented mirror were manipulated in order to achieve a negligible difference between that of the optimal PSF and the PSF of a segmented mirror. The equivalent single lens radius in terms of maximum intensity of the current set-up of the telescope was determined to be 234.25 mm. If the optimal PSF is achieved, the physical parameters of the optical components generated may be applied to the optical components of the 64-cm telescope. The design that resulted from the study could be used in the future construction of a wide-aperture telescope, which could aid in the acquisition of knowledge about heavenly bodies.

密碼鎖

一個有3 個旋鈕,每個位置的號碼數分別是a、b、c 的密碼鎖,如果有兩個位置的數字正確就能打開,最少需要猜多少次才能保證打開這個鎖。在本論文中,我們將密碼鎖三個位置的號碼數分成:a=b=c=n、a=b<c,a=b>c 和a>b>c 四個部份來討論。前兩部份的研究已經找到最少次數開鎖的方法 ,後兩部份則是給了一個演算法可求出開鎖次數的上界。If a combination lock with three rotate wheels can be opened when two wheels are adjusted to the correct numbers, then how many guesses does one need to make before he or she can actually open this lock? Let us say a , b and c respectively represents the numbers that should show on each wheel. In this paper, we divide the numbers into shown on the three wheels, and they are a = b = c = n , a = b c and a = b < c . The research on the first two combinations has already given us the method we can use to open he lock with the least number of trials. On the other hand, the latter two offer us an algorithm that can be uses to obtain the upper bound of tries needed to open the lock.

鋪蓋之研究與探討

本文是利用整數分拆及排容原理研究以1x2 矩形鋪mxn 矩形的排法邏輯及總排法數,並進一步探討下列兩種情況:雙邊不含缺陷線及至少有一缺陷線的排法數。\r Based on the Apart of Number and the Inclusion- Exclution principle, this research intends to analyze the logic and final result of permutation by laying an 1x2 rectangle over an mxn rectangle. From the analysis, this study will go further to explore the possible permutation in the following two situations : when there is no fault line on both sides and when at least one fault line exists.\r

Reuse Waste and Save the World by Production Fiber Reinforced 'CB' made from Empty Fruit Bunch (EFB)

At present Malaysia is the largest exporter of palm oil in the international market. In the process of extraction of palm oil from oil palm fruit, biomass materials such as palm empty fruit bunch (EFB) and palm pressed fibre (PPF) are generated as waste products. Natural fibres reinforced cement-based materials have gain increasing application in residential housing components. One of the natural fibres considered is oil palm empty fruit bunches (EFB) fibres which offer advantages such as availability, renewability, low cost and the established technology to extract the fibres. This study investigates the properties of cement board incorporated with large amount of oil palm EFB fibres Among the tests conducted was compressive strength, density, water absorption and thickness swelling tests. It was found that high EFB fibres content lead to lower strength and higher absorption . The results also indicate that high EFB fibres contents reduced the self-weight of the blocks and the resulting blocks can be classified as lightweight cement blocks suitable to be used as lightweight walling materials. Our research is to study the production of cement board using Empty fruit bunch(EFB)These board were made from empty fruit bunch, cement and water. Two chemical are added is aluminium sulphate and sodium silicate. Cement : EFB mixture by weight was 2.5:1, 2.75:1 and 3.0:1 used to produces a cement board.

Finding a Better Brain Booster

The purpose of my project was to determine which activity improved academic performance the most: 10 minutes of exercise, 10 minutes of Brain Gym (cross-lateral movements), or a combination of 5 minutes exercise and 5 minutes Brain Gym. This project was conducted to find which activity would be a better learning aid in grade 4 students. There were many steps to conducting this study. First, I located teachers and classes, willing to allow the testing and determined days and times to test. Next, I created consent forms to explain the project and had permission forms from the students and their parents signed. Then I prepared 15 math and reading tests at students’ grade level. There were two tests for 15 days- labeled Before Test and After Test. When I administered the tests for the classes doing the activities, I made sure the tests were given by the classroom teacher, which kept the students motivated. Tests were given every day for 5 days. The Before Test was given at 1:00 pm. Then at 1:30 pm students did 10 minutes of the planned activity for that week. Immediately after the activity, students were given the After Test. This was done every day and was repeated for Exercise, Brain Gym, and Combination week. The control class was designed to determine if doing the test for a second time in a day improved the student’s performance. The Before Test was given at 1:00 pm and then at 1:30 pm. When the Before Tests were completed, the students continued with their daily work for 10 minutes. Then at 1:40 pm students were given the After Test. This was repeated for Exercise, Brain Gym, and Combination week. Students were given 10 minutes to complete the scheduled activity that week; either Exercises, Brain Gym or a combination of the two. During the week of Exercise, Jumping jacks, Skipping, Stride jumps, Burpies, Twisties and Jogging on the spot were completed in the 10 minutes provided. During the Brain Gym week, there were 26 Brain Gym movements. The lists of movements were rotated each day; so all movements were performed. The test results of this study were intriguing. (Bar=Standard Deviation) I concluded that 10 minutes of exercise was the better brain booster. Exercise improved academic performance by 9.8%. Brain Gym improved academic performance by 0.2% and the combination activities increased test scores by an average of 3.2%. The control class test scores decreased on average by 1.0% indicating that writing the tests twice in a day, did not improve students’ test scores. Exercising for 10 minutes improved student’s math scores by 11.0% and reading scores by 6.9%. Brain Gym math test scores decreased by 1.4%, and increased in reading by 1.8%. In the combination of the two, the math test scores decreased by 1.0%, reading test scores increased by 7.4%. Overall, the most effective and reliable brain booster was 10 minutes of mild aerobic exercise alone.

Self driving car

Autonomous car is a very new concept, being a car without any driver. Several concurrent software process data using Artificial Intelligence to recognize and propose a path which the car should follow. The goal of the project is that a driverless car can reduce the distance between the cars, lowering the degree of road loadings, reducing the number of traffic jams, avoid human errors, and allowing people with disabilities(even blind people) to travel using an autonomous car. Theoretically a car without driver in the future should be much safer, because human reaction speed is higher than 200 ms, and the computing power of the newest computers allows traffic calculations even to 10 ms. The necessary power is provided by three multi-core laptops that process with Artificial Intelligence in order to recognize traffic signs, traffic lanes , traffic car fingerprints, processing the data from a 3D radar, using particle filters to localize car in a GPS map, the management of database with traffic signs, magnetic sensors, acceleration sensors, a distributed software, a supervisory system and the software which drives the stepper motor to turn the steering wheel (acceleration and braking). Currently the software is able to recognize the traffic signs, register them in a database using Google Maps. The fields record the sign and direction of travel from that area. Each car participating in the traffic and using this software will register new signs detected and the will modify the degree of confidence of recognition for other users. Another software component is able to recognize the demarcation lines between lanes, with three cameras to calculate exactly or using probabilities where it is on the road, where the roadsides are and to propose a new direction even in the absence of traffic signs for the next seconds. Another part of the software is trying to use Artificial Intelligence to detect other car fingerprints from webcam images. The calculation was performed on 3 computers, requiring distributed processing. I developed a management information system based on semaphores that allows data processing and supervision from 3 different computers. This project presents a hardware version of a LIDAR – a 3D radar and a software for creating a 3D environment in which the car navigates and using it the car will take decision to avoid obstacles. The LIRDAR contains a total of 16 avalanche photo-detector mounted on a stepper motor that spins at a frequency of 10 Hz. The information provided by my radar is about 576.000 pixels at resolution of 10 bits. The 3D radar helps the entire software system to increase the confidence of decision.

以有機溶劑摻雜改善高分子分散型液晶性質之探討Resistin透過活化WHSC1/Twist途徑促進肺癌惡化

高分子分散型液晶(Polymer Dispersed Liquid Crystal,簡稱PDLC)是由高分子聚合物包覆的液晶微滴所組成,透過電場量值的改變能有不透光與透光的變化。然而目前PDLC的閾值電壓相對於傳統液晶而言較高,成為發展的阻礙之一,因此我們希望透過摻雜有機溶劑的方式來降低PDLC的閾值電壓。 我們先探討不同製程變因對PDLC的影響,以建立影響PDLC光電性質的理論模型,接下來我們嘗試摻雜不同的有機溶劑,並發現以乙醇的效果最佳,於是我們便進行不同重量百分率的摻雜實驗以及調整摻雜方式。我們發現酒精的摻雜可以大幅降低PDLC的閾值電壓,摻入25%的酒精約可使閾值電壓降低50%,除此之外,酒精的摻雜似乎可以降低PDLC的遲滯效應,而PDLC的初始光穿透率與摻入酒精的重量百分率約成正相關。這樣的結果相信對於PDLC在節能省電的應用方面將有很大的幫助。

瓶蓋呀瓶蓋─飲料兌換問題的推廣研究

本文主要在討論一個益智遊戲─瓶蓋問題,我們延伸本問題,觀察多個正交互影響的變數的變化規律,並了解在兌換中的特性,進而找出計算法則來求取可兌換到的瓶子總數。 我們的研究過程如下: 1. 對原始問題進行定義化並求出增減初始瓶數所得之飲料通解。 2. 改變瓶蓋、瓶身兌換所需數量並觀察總共可喝飲料與殘餘瓶蓋、瓶身數量的變化。 3. 以含有高斯符號的等式描述總體變化關係。 4. 求得上述的第2點,並求出演算法則。 5. 增減可用於兌換的事物數量(瓶蓋、瓶身),並觀察總共可喝飲料與殘餘瓶蓋、瓶身、‧‧‧(其他可用於兌換的事物)數量的變化。 6. 以含有高斯符號的等式描述總體變化關係。 7. 求得上述的第5點,並求出演算法則。 8. 擴張規則,引入m級的概念。 9. 以數團概念描述兌換過程。 10. 求得上述的第8點,並求出演算法則。 11. 調整研究的角度,納入銷售者與經濟學者觀點進行討論。

察魚觀色-自製電化學儀器偵測魚肉中的CO含量

商家或是店家常常為了保持魚肉的鮮紅色澤使其看似新鮮可口,往往會利用CO氣體進行處理。CO對於魚肉中的肌紅蛋白有很強的結合力,可保持鮮紅色澤不易腿去。為了簡易、快速又有效的偵測魚肉中CO氣體之有無及含量,我們自製電化學CO偵測器,並以不同種類的溶劑以及不同濃度之酸,探討肌紅蛋白中CO氣體逸出的機制。此外,我們也討論如何有效增進CO氣體的偵測。我們由一氧化碳感測器(SnO2)、花茶罐、鑽洞的器材、三通閥、電池及電路板,完成自製偵測CO氣體電化學儀器,不僅方便攜帶,更能取代市售昂貴CO氣體偵測器及改善偵測器體積太大的問題。實驗中我們加上pasco電壓偵測及電腦裝置,利於我們進行實驗觀察。而且本儀器也利於在硫酸、醇類及高溫的環境下進行實驗,且高溫的環境下有利於促進CO從魚肉中逸出並偵測。