全國中小學科展

2010年

Bio-Conversion of TiO2/UV System Pretreated Rice Straw to Ethanol

1. Purpose of the research :\r One of the greatest challenges for 21st century society is to meet the growing energy demand for transportation, heating and industrial processes. U.S. and Brazil are currently converting corn starch and sugarcane juice into ethanol; however, these are edible products. To stop global warming and poverty, we tried to determine to develop new pretreatment method to produce biofuel using non-edible parts of agricultural products.\r 2. Procedures :\r For our research purpose, we conducted ‘Preparation of Rice straw - Powder’, ‘Pretreatment Method of Rice Straw and Statistical Optimization Using Response Surface Methodology’, ‘Enzymatic Hydrolysis for Saccharification of Pre-treated Rice Straw’, ‘Analyses of Pretreatment Efficiency and Production of Glucose and Xylose Using HPLC & TLC’, ‘Ethanol Fermentation and Recovery’, ‘Strain Improvement for Pichia’.\r 3. Data :\r For the first time, rice straw was pretreated in a novel manner using hypochlorite-hydrogen peroxide (Ox-B) solution. The optimum pretreatment condition was analyzed by response surface methodology and the pretreated rice straw was hydrolyzed using two kinds of enzymes. Following hydrolysis, Saccharomyces cerevisiae and Pichia stipitis were inoculated for ethanol production. The optimum condition was 60 min pretreatment using Ox-B solution containing 0.6% hypochlorite and 25% hydrogen peroxide for 1 g rice straw in 240 ml total reaction volume. The Ox-B solution treatment was an essential step for efficient hemicelluloase hydrolysis. Under these conditions, 406.8 mg glucose and 224.0 mg xylose were obtained from 1 g rice straw. The structural change of rice straw after pretreatment and enzyme hydrolysis was examined by scanning electron microscopy. With the 10% initial sugar concentration, the final ethanol concentration was about 3.46%, which is 90.5 % of stoichiometric and fermentation efficiency yield.\r 4. Conclusions :\r Rice straw was pretreated in a novel mean by using an Ox-B solution broadly used in potable water treatment. Pretreatment modified the structures of lignocelluloses. The Ox-B solution treatment was an essential step for efficient hemicelluloase hydrolysis. Pretreatment modified the structures of cell wall. Further optimization studies of the fermentation process and strain improvement research (for derepressed mutant) are in progress. In the future, I hope to see cultivators to move by the ethanol produced from rice straw and agricultural wastes.

以瑞利準則探討點描畫派最佳觀賞距離

19、20世紀的後期印象派中,點描派為最吸引人的畫派之ㄧ,而喬治‧秀拉(Georges Seurat)即是其畫派之代表人物,因此,設計實驗時以秀拉的畫風為中心。\r 本研究以Photoshop繪圖模仿點描派之作品,?探索物質的本質,選用三原色為混色的原色,來觀察混色後對畫作的效果。研究中,以分析兩亮點之大小、距離與觀測距離的關係來設定點之尺寸,再進一步分析三原色點之觀測距離、比例及三原色點之佈點方式對混色效果之關係做為實驗主軸,並以瑞利準則判斷之。\r 希望藉由本實驗能以物理學的角度瞭解點描畫派之作品,同時,設法將點描畫數位化,並希望找出欣賞點描畫最佳情況,提供賞畫者最好的視覺享受。

結合奈米金粒與DNA適體的金黃色葡萄球菌快速檢測系統

金黃色葡萄球菌是生活中常見的病原菌之一,因其抗藥性日益嚴重,是大家所熟知的超級細菌。 目前醫院對此菌的檢測方式,從培養到獲得結果大約需要兩天,對許多感染此菌的重症患者是無法接受的醫療時間延誤。 有鑑於此,本研究利用創新的適體、光電及奈米技術發展一個可以快速偵檢金黃色葡萄球菌的系統。 適體為具有與抗體同樣分子辨識功能的寡核酸。我們利用DNA適體篩選技術,獲得能夠專一地辨識金黃色葡萄球菌的適體序列,進一步發展高敏感度細菌檢測系統,並測得靈敏度近個位數的金黃色葡萄球菌。本研究亦結合奈米金與共振光散射原理,以簡便的二極體雷射與偵測裝置,可快速判定檢測樣品中是否有金黃色葡萄球菌,大大縮短檢驗所需的時間。

碳黑受閃光產生爆鳴聲之研究

紙杯底部用蠟燭燻出碳黑,經數位相機閃光拍攝後會聽到爆鳴聲。探討的結果為爆鳴聲是由相機的閃光與碳黑之間的互動所引起,甚且到冒煙程度。\r 探討結果得到爆鳴聲大小會受電場、溼度的影響而且碳黑量愈多,電子傳遞路徑會縮短、導電性則增高,且與產生的電量接近線性關係。\r 發現波長較短的可見光可形成較多的電荷;若照度大、受照射面積大或碳黑的粒徑小,這些會產生較多的電量。\r 經由電顯及AFM圖可知去漬油、蠟燭、瓦斯、95汽油、酒精燃燒後產生的碳黑,大小範圍都是在30nm~100nm範圍內。將蠟燭碳黑接受不同次數的閃光後,看出表面碳粒會變成灰燼。

架構「類球狀多面體」的理論與實務

本報告的目的在:電腦Cabri 3D 軟體上模擬出「類球狀多面體」(圖1-8),\r 並實作其模型(圖9)與它們的星體(圖10)。「類球狀多面體」的定義如下:\r 可由「正多面體」切出之多面體,且需滿足以下性質:(1) 除「正多邊形」外,\r 其餘皆是「六邊形」。(2)鳥瞰每個「正多邊形」時,形狀皆保持不變。(3)\r 等長的稜數最多。\r 以「正十二面體」切出之「類球狀多面體」為例,(圖1)中兩個「正五邊形」\r 相距一個「六邊形」簡稱A1。(圖2-4)依序為A2、A3 與A5。正二十面體可切\r 得(圖5-6),正六面體可切得(圖7-8),......等。(圖9)為A2 的實體模型,\r (圖10)為A2 的星體模型。

Nonlinear Time Series Analysis of Electroencephalogram Tracings of Children with Autism

Methods of nonlinear time series analysis were compiled for use in the analysis of Electroencephalogram (EEG) tracings of children aged three to seven with varying degrees of autism in order to provide a quantitative means of diagnosing autism and determining its severity in a child. After determining the EEG leads to be used for analysis, the identified methods were coded and saved as functions on Scilab. To test the compiled program, a minimum of five EEG readings per cluster of children diagnosed with mild, moderate, severe and no autism will be obtained. The project was able to identify the mean, standard deviation, skewness, kurtosis and other higher order moments, the autocorrelation function, and the Fourier Series as the time-resolved statistical methods to be used for time series analysis. The nonlinear analysis methods identified include the use of the correlation integral, time-delay embedding and the Lorenz equations. One-way ANOVA testing will then be used on the numerical data obtained from the analysis to determine if a significant numerical differentiation has been obtained between the different clusters of EEG. This will provide a definitive way to medically diagnose autism, pinpointing children afflicted with the disorder and giving them proper treatment.\r Two copies of the "Abstract of Exhibit" (in English) should be sent to the National Taiwan Science Education Center or email to fung@mail.ntsec.gov.tw or yuonne@mail.ntsec.gov.tw before December 31, 2009.

光觸媒結合分子篩-去團聚及光催化效果探討

二氧化鈦是光觸媒中最常被使用的,雖然合成方法很多,但如何提升其產量及分解效果,一直是學界及業界的熱門議題。\r 在此篇報告中,我們發展出一種新的方法來製造二氧化鈦,利用控制合成時溶液的pH值、使用幾丁質當作新的保護劑,並且改變加熱的溫度和時間來得到二氧化鈦奈米顆粒。在降解實驗中亞甲藍光的分解反應速率級數為一級,降解亞甲藍液的半生期在2.9~7.0分鐘,比一般文獻的數十分至數小時以上的速度高出許多。\r 另外,在幾丁質未燒去的實驗中,我們發現亞甲籃分子會被吸附在幾丁質的表面上但不被分解,燒去幾丁質時奈米粒子又無法完全分散,為解決這一個問題,我們使用了分子篩,分子篩可以吸附許多有機物質,再加上其為具有許多中/微孔構造的鋁矽酸鹽礦物,奈米粒子可以分散在其表面而不生團聚;在光降解的實驗中發現光觸媒結合分子篩後可大幅提高染料的分解效果,在短短一分鐘之內便將亞甲藍分解掉一半以上!\r 這個實驗提供了很好的方法,可以快速有效的合成二氧化鈦奈米顆粒,作為光觸媒使用。我們相信這個方法可以推廣到其他有機汙染物質,以降低工業進步後對地球環境所造成之污染危害。

奈米粒子對細胞與生物之毒性及其分佈

人類目前廣泛的應用奈米鑽石,奈米鑽石粒子極為微小因此很容易進入生物體內,對於生物體所產生的影響為本次的研究對象:奈米鑽石、奈米磁性粒子之生物毒性與其在生物體的分布。\r 加入奈米鑽石、奈米磁性粒子之後綠豆發芽數減少。發芽的綠豆中加入不同量的奈米鑽石、奈米磁性粒子,發現濃度越高生長速度越慢。在綠豆吸收奈米鑽石、奈米磁性粒子後,在根、莖、葉細胞內都有發現奈米鑽石、奈米磁性粒子。在麵包蟲的研究中發現,在0.25克濃度下,有些微的影響,而在0.75克和1克之影響甚大。在人類胎盤滋養層細胞中,發現加入奈米鑽石800微克以上對其有毒性。在細胞的分布,可發現細胞質及細胞核中都有奈米鑽石,當細胞內太多或作用太久時,會出現細胞凋亡的現象,此時奈米鑽石會大量聚集在細胞核,這可能是造成細胞死亡的原因之一。本研究意外發現在細胞分裂時,奈米鑽石只分布在細胞核周圍的細胞質,但是在赤道板及染色體上並沒有。

The Use of Simulated Annealing in Predicting Solar Flare Activity

A program based on the simulated annealing (SA) algorithm was developed to allow for a longer-term prediction of the occurrence of solar flares, thus reducing the risks they may pose to astronauts, satellites, and ultimately the planet Earth. Sunspot data such as the solar cycle, the appearance of sunspots, the sun's magnetic field, the occurrence of solar flares and other factors that concern the sun were considered in the development of the algorithm. The program, coded in C++, included providing for an initial random state that pertained to the sun's state at a specified time. A neighborhood function was designed based on how sunspots are formed and how they disappear, and the probability function was designed using previous solar cycles to show relationships between the number of sunspots and the time it takes for the sun to reach solar maxima. Finally, the cooling function was designed as a representation of the time. Recorded sunspot counts obtained from the US National Geophysical Data Center (NGDC) during the solar cycle 22 from 1986 to 1996 was used as test data. The output was compared to the actual recorded solar events or the period. The program was found to be 66.7% accurate in predicting solar flares when compared on a smoothed trendline, while it exhibited a 50.5% accuracy when comparing day-to-day data. Since solar flare acitivty is predicted in terms of the trend of activity and intensity, improving daily data accuracy is superfluous. Smoothed trendline prediction accuracy may however be improved by altering the importance of each factor in predicting solar flare activity and by devising a different sunspot classification scheme for intensity and activity.

The Titanium Dioxide Toilet Disinfectant

This project aims to improve the quality of toilet hygiene. The product designed should fulfill the requirements of being an environmentally friendly, user friendly and economical toilet seat system which guarantees the safety and hygiene of the toilet. This project also aims to discover the efficiency of the toilet seat system in eliminating pathogens through conducting various experiments.\r In this project, the photocatalytic property of titanium dioxide is applied. When titanium dioxide is under exposure to ultraviolet radiation, they generate free radicals, which are efficient oxidizers of organic substances. Also, research has shown that the safest ultraviolet light used will be UVA. Thus, by using titanium dioxide paint under exposure to ultraviolet light to oxidize pathogens and toxins, the aims will be achieved. Other than that, experiments will be conducted to explore the efficiency of titanium dioxide under exposure to UV radiation in eliminating pathogens by counting the number of bacteria on the toilet seat system after different time intervals the seat system has been turned on.\r The procedure of constructing the product includes drafting the product, purchasing the appropriate apparatus and materials, constructing the prototype, and checking if the product fits the goals set. Lastly, improving the design based on the flaws found during the checking procedure, as well as checking the product to see if it fits the original goals set.\r The procedure of the experiments aimed to explore the efficiency of titanium dioxide under exposure to UV radiation in eliminating pathogens conducted includes\r counting the number of bacteria on the toilet seat system after different time intervals by inoculation of bacteria on the agar plates.\r Test results showed that the number of bacteria had a steady and notable decline after different time intervals. Results also showed that bacteria would be thoroughly terminated after the system had been turned on for at most one hour. The information was then used to set the delay timer to restrict the amount of time the ultraviolet lamp was turned on to save energy.\r Moreover, the toilet seat system has also been improved so that it will complete the automatic cleaning procedure even without the user lowering the toilet seat. This improvement was made so that the product could be more convenient to toilet users.\r The system also deodorizes the toilet as the oxidization of bacteria and organic substances reduces the putrid odor released by them when they carry out chemical reactions.\r In conclusion, the project succeeds in accomplishing the goals set and is capable of improving the quality of toilet hygiene, especially in common households. The project is also successful in finding out that the toilet seat system is efficient in eliminating pathogens.