A Novel Spectroscopic-Chemical Sensor Using Photonic Crystals
Detection of harmful chemicals used in industrial complexes is crucial in order to create a safer environment for the workers. Presently, most chemical detectors used in workplaces are expensive, inefficient, and cumbersome. In order to address these deficiencies, a novel sensor was fabricated to produce a unique spectroscopic fingerprint for various toxic chemicals. The sensor was fabricated by depositing several layers of silica spheres (diameter ~250 nm) on a glass substrate using evaporation-based self assembly. As the spheres assemble to form a photonic crystal, they also create void (i.e., air) spaces in between them. Once the spheres assemble as a photonic crystal, a spectrometer was used to monitor the reflectivity. The spectrum had a high reflectivity at a specific wavelength, which is governed by the average index of refraction between the spheres and the void spaces. As a foreign chemical infiltrates into the photonic crystal, it occupies the void space, which results in an increase of the average index of refraction of the structure. Consequently, the peak wavelength of the reflectivity spectrum red-shifts, which then confirms the presence of a foreign substance. While the as-grown photonic crystal is able to detect chemicals, it is unable to differentiate between chemicals that have similar indices of refraction, such as ethanol and methanol. In order to detect chemicals with similar indices of refraction, five pieces of a single photonic crystal (i.e. five pixel device) were exposed to different silanes, which changed the surface chemistry of the silica spheres in the photonic crystal. In turn, the five pixel device was able to produce a unique chemical fingerprint for several chemicals, which can be calibrated to detect toxins in the workplace.
Studies of Hydrogen Evolution Reactions from Aluminum Foil using Waste Materials and Their Reaction Mechanism
Nowadays, the most of waste materials are incinerated and generated the toxic gases in 日本. On the other hand, the Hydrogen gas (H2) has attracted attention as clean energy due to no emissions of toxic gases. In this work, we investigated that the new hydrogen evolution system using waste materials, such as aluminum (Al) foil and lime desiccant, and also investigated their reaction mechanism. The grinded desiccant was added to Erlenmeyer flask containing 300 mL of water. After dissolution the desiccant, the Al foil was added to the solution to begin the reaction. Generated gas was determined by water displacement method. The gas components are identified by gas chromatography. We found that the waste material reaction combined with waste lime desiccant and Al foil could be used for one of the hydrogen evolution system. This reaction is depended on solubility of lime desiccant, thus mean solubility of CaO in water. The Al foil is reacted with the desiccant more than 20 times of reaction stoichiometry. The calcium ion or calcium complex ions are involved with the excess reaction of Al foil.
Random number generators and their applications in Computer Science with the Monte Carlo Method
Monte Carlo methods are non-parametric algorithms that use random numbers and theorems of probability theory to approximate values that are not random. The purpose of my research was to approximate the surface of different geographical areas that can be easily approximated to polygons (e.g. lakes, glaciers, deserts) with Monte Carlo simulations starting from either Cartesian coordinates or pictures. Computer science would not exist without math, and this research project showed me the importance of a deep understanding of probability theory in the world of simulations and, more generally, the importance of developing new theorems and algorithms. The results of my research could be developed in different ways: it would be interesting to produce software that allows one to approximate areas from pictures taken from a smartphone; as well, the theorem I found has to be proven, and also Monte Carlo methods as a means of random number generation can always be improved. There are still many possibilities.
永恆的旋轉木馬
本研究作品主要在探討「平面上各種曲線內關於相鄰等角割線段的新的不變量」與「空間中特殊圓錐曲面的特殊等角割線段的新的不變量」。 若圓錐曲線、蚶線等曲線中有相鄰等角的 條割線段,則這n條割線段之m次方和為定值。在圓錐曲線中這些割線段的交點可以是焦點、曲線內任意點,在蚶線中則為基點。甚至經由反演,還能將此性質推廣至直線上。 研究最後擴及至空間,先考慮特殊橢圓、拋物、雙曲球面,其一焦點為F,將正N面體VN之重心G與F重合,使得VN以F為旋轉中心任意旋轉,此時由F對VN之各頂點做射線交圓錐曲面於 PN,則FPN之倒數m次方和為定值,其中u=1,...,n,N=4, 6, 8, 12, 20 。
The Polar Equation from Butterfly Sprinkler Heads
This project aims to create the polar equations from the relation of the points on the centre line of the water twisted from Butterfly sprinkler heads. The water path includes inner rim, outer rim and centre line laying in the middle of the water path is used Rhombus’s property. The diagonals are perpendicular bisectors of each other to create the centre line. Then we create the polar equation of the centre line of water that twists from 4 types of the Butterfly sprinkler heads: edge frame, curve frame, STL and STL rotary. The polar equation of outer rim and inner rim is created by adding and removing the “ f ” value ( ; is the distance between the outer rim and the centre line, and is the geometric sequence that is ) of the coefficient (a) of the polar equation respectively. The results show that the formal equation of the centre line is which can explain the different properties of Butterfly sprinkler heads. If “ f ” value is increasing the water path and the blade will be wider that affects droplets distributing thoroughtly. Furthermore the relationship between the volume of water and the radius of water distribution can be processed to find the least time that can increase the appropriate moisture level of soil.