高分子複合材料的性質、製作與分解
Synthesis of Polymer Material and its Decomposing Processes Because plastic cannot be decomposed naturally by itself, therefore, additives needed to be added to facile the decomposing process. Let us choose one common material: thermoformed Nylon 66. During the formation process, addition of glucose powder and monosaccharide polymerized will result in yielding the products of methyl cellulose, soluble starch and agar powder. Observe whether adding additives would allow changes to occur structurally, or would the elasticity be improved when exist in a linear state, or even it would form a better pH resistance property. According to the experiments, when Nylon 66 contains methyl cellulose, it can sustain the highest tension. Its coefficient of elasticity is 2 times as large as the original one. In terms of the data, we can also observe that when Nylon66 contains soluble starch, it has the lowest ability to sustain tension. Besides, it has the lowest coefficient of elasticity. And when Nylon 66 contains cellulose, it has the highest rate in the process of decomposing.As we look at the surface of polymers under 400 diameters, we can observe that the Nylon 66 with agar powder has some filiferous substance. But we have not confirmed what the matter is. 由於塑膠不能在自然情況下順利分解,所以我們在塑膠中添加其他成分使塑膠可以較易 分解。我們選定常見的塑膠—熱塑性的耐綸-66。在聚合物的製作過程中添加葡萄糖、澱粉、 洋菜粉末以及甲基纖維素,並觀察加入添加物的塑膠在結構上是否有變化?其塑膠在線型時 之張力是否有增強?耐酸鹼性是否有變化?由實驗結果我們可以得知含有甲基纖維素之耐綸 -66 所能承受之張力強度最高,且其彈性係數也比無添加物之耐綸-66 高出近2 倍;而含可溶 性澱粉之耐綸-66 所能承受之張力最小,且彈性係數也最低。此外,進行生物分解的實驗可發 現,含葡萄糖的耐綸-66 分解的速率最快。使用400 倍的光學顯微鏡可發現含有洋菜粉末的耐 綸-66 表面與其他耐綸-66 複合材料差異較大,值得進一步研究。
奈米使你變美了!-奈米二氧化鈦在化妝品上的應用
奈米的科學與技術將是21 世紀所要探討的方向。在了解奈米粒子的表面效應、小尺寸效應、量子尺寸效應、宏觀量子隧道效應後,發現其應用甚廣,諸如再生物、醫學、環境、國防、工業產品等方面,都將佔有很重要的地位。我們主要是利用溶膠-凝膠法來製造二氧化鈦奈米粒子,並了解二氧化鈦奈米粒子可吸收紫外線及光催化反應,將廣泛應用電子、紡織、塑膠、橡膠,空氣淨化及廢水處理方面。本實驗將利用二氧化鈦的吸收紫外線特性,來研究其應用在化妝品上面。The science and technology of nanomater will be the direction we will explore in the 21st century. After understanding surface area effect of nanometer particle, Small size effect, Quantum effect, and Macroscopic quantum tunnel effect, we can diswver the application is very far-fluing. For example:biochemistry, medical science,eneironment,national defense and industrial products,will devine a very important position.We mainly use sol-gel method to produce U-TiO?,and understand the absorption of UV and photocatalysis,plastics,mbber,purging air,and dealing with effluents.This experiment will use characteristic of absorbing UV of U-TiO? for researching the application of cosmstics.
緩步門的木乃伊-會蟄伏的熊蟲
The study is to investigate Taiwanese tardigrades,and the research of that is few. Tardigrades are commonly called water bears and have been identified more than 750 species. Limno-terrestrial tardigrades are small, 0.2-0.5 mm in length, and mostly found in moss cushions growing on rocks, soil, or the wall of houses. When the environment dehydrates in dry weather, Tardigrades desiccate into a reversible state of metabolic suspension called cryptobiosis. We have been finding a number of tardigrades in moss at many places in Taoyuan country. First, we put the moss on the dissected microscope to seek for tardigrades, and then placed it on the microscope for photographing and observing. The study is mainly focus on Taiwanese tardigrades. we have classified 11 Taiwanese species in four families(Echiniscidae,Calohypsibiidae,Milnesiidae and Macrobiotidae), making Chinese keys of classification. From the habitat envoriment, the species, the density and the diversity we survey as well as the most suitable pH envoriment we experiment, we approach the relationship between the distribution of tardigrades and their habitat. Besides, we also research lots of conditions which bring cryptobiosis and make culture medium in order to inspect its living. These results indicate that tardigrades desiccate into cryptobiosis in ten munites in acid rain(pH4.65). From outdoor surveys, we have noticed tardigrades can’t be found in the moss right next to road.The length of each family is: Calohypsibiidae>Milnesiidae Milnesium>Macrobiotidae>Echiniscidae. 此研究是探討台灣熊蟲,而有關台灣熊蟲的文獻資料極少。熊蟲屬於緩步門,體長約 0.2-0.5 mm,熊蟲在不利的環境會蟄伏,環境有利時又會膨脹而復甦,而其構造系統不因此而破壞。 我們在桃園縣多處的苔蘚發現熊蟲,我們先將採集的苔蘚放至解剖顯微鏡下尋找熊蟲,再由複式顯微鏡觀察構造並拍照紀錄。研究主要是探討台灣本地的熊蟲,我們已分類出十一種台灣熊蟲,製作中文檢索表。藉由觀測採集環境和所測的密度、歧異度和種類,及實驗出其最適宜的 pH值,探討環境對其分布的影響。也探討各種因素與蟄伏的關係,製作培養基以觀測其生活史。研究結果顯示:1.已經分類出台灣有緩步門四科(端爪科、Calohypsibiidae科、Milnesiidae科和 Macrobiotidae科)十一種熊蟲。2. 污染嚴重或環境髒亂的地方,不會有熊蟲的存在,且熊蟲有群居性。3. 端爪科(棕色)熊蟲在 pH4.65(台灣都會區雨的酸鹼值)以下的液體環境活動力明顯降低。4.熊蟲多分布在高溼度(87.5~90.4%)的地方,不分布在中低溼度 (76%以下) 的地區。5. 各科的體長為 Calohypsibiidae科>Milnesiidae科 Milnesium屬>Macrobiotidae科>端爪科。
液態導體的磁效應
本文所探討的議題為電解質溶滿通以電流後所產生的效應與機制。本實驗所採用的方法為電解與電鍍,運用這兩種方法,來比較電解液在不同狀況下所產生的結果;經過多次的實驗,累積了許多實驗結果,使我們可以得到更精確的數據 · 在此次實驗中,我們發現電解液在相同的電壓下,通以電流後的穩定性與金屬的活性有關,活性越大越不穩定;反之,活性越小越穩定。另一個發現為,只有單一極性離子移動的情形,可通過的電流,比陰陽離 r 同時移動時為大;但因通過的電流大使電解液反應劇烈,產物時時覆蓋電極使電流下降。所以就穩定性來說,是以陰陽離子同時移動為佳 · 在展望方面,希望可以發展到液態磁屏避的設備,可減少設備過重之問題 ·This is a study of how electric current effects the electrolyte solution. The experiment was conducted through two methods: electrolysis and electroplating, the results of which were compared. The experiment of the same designs hi been conducted repeatedly and, as a result, accurate data were collected and accumulated.One of the two major findings from the experiments was that, when under the same voltage, stability of the electric current varied with the change of activity of the metals; the greater the activity of the metals, the less stability of the current, and vice versa. The other major finding was that, with the movement of dipole-ion, a greater amount of current would go through the solution than that which would go through with the movement of cathode and anode; however, the greater amount of current would cause intense reaction of electrolyte solution, hence merging the electrode and reducing the current. So as long as stability is concerned, the movement of cathode and anode is preferable.It is hoped that more sophisticated experiments designed on the basis of the similar principles will eventually lead to the construction of equipment of liquid-magnetic shielding of smaller weight and size.
分散質的結構與張力
洗滌用的界面活性劑分散系,沾在吸管可吹成泡,沾在框上則生成特定形體的薄膜;兩種不同現象,依據各自的性質原理,分別設計為可測量的裝置,研討表面張力與濃度間的關係,發現『兩泡連通法』,測量的靈敏度較佳,並且;薄膜總面積法則會因為框的形不同,測得薄膜總面積與表面張力大小的變化趨勢不一樣,而且數據誤差都比『兩泡連通法』大。市售的洗劑有肥皂與合成清潔劑兩類,它們溶於水的分散系,表面張力與濃度大小的變化趨勢正好相反;肥皂的濃度愈大表面張力愈大,合成清潔劑的濃度愈小表面張力愈大。這種現象發生的原因,和分散質是否含苯環結構無關。用數位照相輔助毛細管上升法,觀測『兩泡連通法』標準液的張力與濃度關係,數據顯示兩泡連通法與毛細管上升法,兩者比較各種分散系張力與濃度大小的結果相同。因此,用『兩泡連通法』比較不同分散系張力大小是簡便生動的可行方法。The dispersion of surfactant used for the purpose of cleasing,if dipped on a blowpipe,can be blown into bubbles and,if dipped on a frame,will form a certain shape of membrane.For these two different situations,according to the principle of their quality,measuringdevices can be respectively designed to explore the relation of surfact tension to its concentrate.It is discovered that,with the measuring device of the Two Bubble Connection Method,the sensitivity measured is better;and that,because of the difference of the structures of the frames,the total area of the membrane and the change trend of the degree of the surface tension will also be different and the probable error of the measured digits is always larger and it is not easy to find regularity. For the two categories of dispersion,soaps on the market and synthesis detergent,when they are measured with the Two Bubble Connection Method about the relationship of their surface tension to the degree of their concentrate,the trend of change is exactly opposite.The surface tension and concentrate of the category of soap are in right proportion whereas,for synthesis detergent used for cleaning bowls and plater and washing clothes,when its concentrate is less,its surface tension is more intense.Based on the findings of this study,the concentrate and the change trend of the degree of tension have no connection with whether there is benzene structure in the solvent. With the Capillary Rise Method assisted by digital photography to observe the relation of the tension of standard solution to the concentrate,we have found that they totally correspond to the result measured with the Two Bubble Connection Method designed in this study.
讓瓶塞隨心所欲
這是一種可在膨脹狀態及未膨脹狀態間轉換的膨脹收縮瓶塞。本設計之瓶塞包含一彈性橡膠之塞座及一剛性塑膠之旋轉控座。該瓶塞在未膨脹狀態,可將瓶塞置於平口內將瓶塞順時針方向旋轉90度使瓶塞由未膨脹狀態轉換至膨脹狀態將瓶子密封;欲開瓶時將瓶塞逆時針方向旋轉約90度使瓶塞由膨脹狀態轉換至未膨脹狀態,可輕易將瓶塞從瓶子內拉出。根據顧客之需求設計瓶塞並選定適當之塑膠材料以製作旋轉控座及適當之衛生橡膠以製作塞座,依廠商提供塑膠及衛生橡膠之特性資料做有限元素分析預測橡膠元件受撐大之變形量,進行加工與製造印證分析之結果,與預期目標有相當的差異,故製作簡易之試件進行探求塞座內縮量與瓶塞膨脹量之關係, 探求瓶塞膨脹量與瓶子所能承受的壓力之關係,進而逆向設計瓶塞之塞座內縮量。 This is a kind of bottle plug that can change at the situation of swell or unswell.The design of this bottle plug includes a rubber plug and a rigid plastic controller that can revolve around. We can put the bottle plug at the top of the bottle and rotate it 90° c.w., the bottle pug will be at the situation of swell and then seal up the bottle. If we want to open the bottle, we just rotate 90° c.c.w., and the bottle plug will be at the situation of unswell and then we can pull the bottle plug out easily. I design this bottle plug according to the need of the customers; choose the certain plastic material to make the rigid plastic controller, and the properly rubber to make the plug; analyze and predict the amount of deformation by Finite Element Method in accordance with the characteristics of rubber and plastic supplied by the factories. However, the result and the expected result are quite different. In order to solve the problem, I make an easy sample to search for the relationship between the contraction of the rubber plug and the swells of the plastic controller and also the relationship between the swells of the plastic controller and the pressure that the bottle can endures. Then I design the contraction of the rubber plug on the base of the result of the experiment I made above.