誰能比我更善變???~ 釩鎵磷酸鹽的合成及其結構鑑定
This research tries to find out how changes of weight or proportion of a reactor would affect the type and structure of a crystal. In the experiment, the Hydrothermal reaction was adopted to conduct the syntheses of Vanadium-substituted Gallium Phosphates and try to pick up the single crystal to collect data with SXRD for further illustrating the crystal structure with diamond software to know well its nature. The research result finds out a new type of crystal unseen in the existing literature produced because of the weight changes of C3H10N2, therefore the weight change of a reactor may affect the structure of crystal significantly. In the future, it is expectation that comparison among structures of other Vanadium-Substituted Gallium Phosphates can be made, and the properties of this compound can be measured, and try to find out a brand new type of structure for new exploration by changing the initial reagent.
本研究係透過改變化合物所添加之反應物的比例，以了解反應物比例的改變對晶體的型態與結構的影響。實驗採用中溫水熱反應來從事金屬釩鎵磷酸鹽的合成。並挑取單晶，以X-ray 繞射儀進行數據收集，再以diamond 軟體繪出晶體的結構圖，且進一步得知其性質。研究結果發現，經改變丙二胺的量後，產生不同於文獻上的新化合物，可知改變所加反應物的比例，對於晶體結構有相當大的影響。未來可朝向與其他的釩鎵磷酸鹽做結構上的比較、對此化合物做更進一步的性質測量、改變起始試劑測試，進而得到更新穎的結構形式等部分進行探究。
吸管笛的諧音之研究與發展
吹長笛時，按同一按鍵，以大小不同的力量去吹，會引發不同頻率的泛音，而通常越用力吹，引發泛音的頻率越高，所以我們想了解為什麼越用力，泛音的頻率會高，其間的關係究竟是什麼？風經過管口會產生各種頻率的噪音，其中某些特定頻率的聲音會因為會在管內形成駐波而放大，所以我們只能聽到某些特定頻率的聲音。當風速增加時，會在管口形成渦漩逸放的紊流現象。其渦漩頻率與流速成正比（註一）。我們以塑膠管實驗。發現以特定的風速引發該基音後，繼續增加風速，當風速達某一定強度時，才會躍遷為下一個泛音的頻率。這個現象告訴我們：在一封閉管下，風速與泛音的關係並非「線性遞增」，而是越「躍遷遞增」的關係。另一個實驗測量不同管長、其諧音之頻率的關係，我們可以得知，越短的管子，因為相鄰兩泛音間頻率差較大，越不易激發更高階泛音。經由這些實驗結果，我們能夠推論：當管子越長、基音頻率越低時，諧音間頻率的差距相對越小，繪出的風速－頻率關係圖應更加顯示了風速與頻率呈正比關係。未來我們可以以閃頻器觀測紊流渦漩的產生，再變化至不同吹入角度，及各式管口造形，這些實驗能協助我們更進一步了解樂器的發聲原理，甚至開發一個以聲音頻率測量風速的儀器。註一：林婉如、張?文2006 國際科工程組佳作作品。When we press the same key and blow a flute using different strengths, we can get different overtones. Usually, the harder we blow the flute, the high the frequency we get. We want to understand why we get a higher frequency when we blow harder into the flute and to understand the relationship between them. When wind passes through the mouthpiece, many kinds of noises will be produced. Some of the frequencies will expand because they will form standing waves in the tube. Therefore, we can only hear certain frequencies. As wind speed increases, a turbulence of the vortex shedding will be formed. The frequency of the vortex shedding and wind speed will be in a direct ratio. We experiment with plastic tubes. When we increase the wind speed and get certain magnitudes, the frequency will jump to the next overtone. The phenomenon shows that the relation, in a closed tube, between wind speed and harmonics is not a linear increase but a transition increase. In another experiment, we measured the relationship between wind speed and different lengths of tubes. We can infer that the shorter the tube, the higher high-frequency harmonics can be produced. Through these experiments, we come to the conclusion that the longer the tube, the lower frequency of the fundamental tone we get and the discrepancy in frequency between harmonics is smaller. Then we make a diagram between wind speed and frequency that indicates that there is a direct ratio between wind speed and frequency. In the future, we can use “” to observe the production of turbulence. Then we can switch to different angles when we blow into flutes. Otherwise, we can experiment with different shapes of mouthpieces. These experiments can assist us to understand more how the instrument sounds. We can develop a device measuring wind speed with frequency.
台北盆地的熱島效應及其對環境的影響
本研究主要是以台北市中心的氣溫觀測站，以及市區外圍東邊的汐止，南邊的屈尺，以及西邊的山佳等三個氣溫觀測站，從1998 年至2004 年的七年期間的氣溫資料中，來探討台北地區的熱島效應現象。這個研究的結果發現，台北市區與周遭鄰近地區確實會因為熱島效應的影響而產生1~2℃的溫差。這個溫差在白天時不甚明顯，在中午過後，便由台北市中心逐漸向郊區遞減，形成類似同心圓狀的分布。溫差最大值發生在夜晚，使得台北地區晚間宛如一座夜晚增溫的城市，同時夏季的熱島效應又較冬季顯著，氣溫又逐年遞升，造成夏季台北市區的高溫屢創新高，將是未來都市發展的危機。This study is focused on the urban heat island effect of Taipei Basin, northern Taiwan. The hourly temperatures of Taipei meteorological station and three rural sites eastern Hsi-Chih, southern Cyu-Chih and western San-Chia, were compared from 1998 through 2004 to illustrate the temperature differences between city center and surrounding country areas. The results show that a difference of 1~2℃ exists between city center and surrounding country areas, indicating the extent of urban heat island effect in the Taipei Basin. The daily temperature contours show a clear high-temperature bull’s eye at the city center during the midnight, implying the high latent heat trapped by the dense and high rise buildings. This phenomenon is not sharp in the high noon due to the reduction of temperature difference between city center and surrounding country areas. The heat island effect is most prominent in the summer than that of the winter. Along with the increasing temperature-difference trend through years, the summer times often experience record-breaking heat waves and pose great risks for the city development in the future.
「從害羞到大方需要多少時間」(環境因子對含羞草開葉時間的影響)
含羞草會因為受到各種不同外界刺激(光照、外力等等)，而造成膨壓改變。外 觀上表現出葉片閉合或有葉柄下垂的現象。其中含羞草處在黑暗的環境下一段時 間後，會做出睡眠運動。當它重新暴露於光照之中，將會需要一段時間以恢復原 先葉片張開的樣子。這個實驗是研究不同類型的環境因子(主要是光照和溼度)在打 破睡眠運動之後，對其葉片復原時間所造成的影響。我們針對上述環境因子在不 同狀況時，進行我們的實驗上百次，進一步得到了多項的數據。也在實驗中，為 了精確了解整個恢復的程序，而將恢復程序程序做成書面說明。以下是我們所紀 錄與分析完數據後的結果，以及我們在實驗期間，進行一些不同的實驗嘗試，所 發現不同於表面所見的驚人事實。 The mimosa can accept plenty of stimulation (light, force, etc), which results in the change of turgor pressure, and on outward appearance, it shows the phenomenon that the leaves become closed or that the stalks get pendent. Among the stimulation, the mimosa will undergo nyctinasty when it is left in the dark for a period of time, in order to enable it to be exposed to the light once more, which requires certain time. This experiment is based on how different kinds of elements of the environment (primarily light and hydro level) effects the rehabilitation time after the nyctinasty is broken. A large number of data are gained after experimenting on it for hundreds of times. Steps of habilitation are also made into illustration in writing, so as to understand the whole steps accurately in the experiment. Below are our records and analysis based on the data, including a few special experimental tries during our working time, in which some surprising facts that were discovered are different from what are seen on the surface.
液滴在我眼前蒸發
本研究的目的在觀察液滴的蒸發過程，探討影響一滴蒸發方式改變的變因。我們利用數位攝影機外加近攝鏡頭，由側面逆光拍攝液滴蒸發過程，並轉錄成電子檔利用電腦協助分析。液滴影像分隔放大投影在方格紙上，以便測量接觸角及高度的變化。結果發現蒸發情形可分為三種：Ⅰ.當接觸角大於九十度時，液滴和界面的接觸線迅速外擴，直到接觸角遞減至90度後定住不動，蒸發終了時，接觸線迅速內縮，留下縮小的實心殘跡。Ⅱ. 當接觸角小於九十度時，接觸線先些微外擴迅速外擴，之後定住不動，直到蒸發終點，液體內縮，留下環狀殘跡。Ⅲ.當接觸角小等於九十度時，接觸線始終定住不變，液滴蒸發後留下原大小的實心班跡。液滴蒸發時接觸角和高度並不是連續變化，而是交互階梯式遞減。本研究的結果可應用在探討噴漆及噴墨印表機的噴墨印刷上。The objective of this investigation is to observe the evaporation of liquid drop and find out the factors that could affect it. A digital camera with micro lens is used to film the process of the evaporation. And a close-up of the sample drop is taken with backlight. The results are analyzed with a personal computer. The magnified images of the drops are projected on grid papers for measuring the changes on contact angles, and heights of drops. We classify the evaporation of a drop into three types: Ⅰ. The contact angle is greater than 90 degrees. At first, the contact line will spread outwardly till the contact angle decrease to the 90 degrees and then be pinned until the evaporation reach its terminal. At last the contact line quickly contract inwardly, and a solid stain remain. Ⅱ. The contact angle is less than 90 degrees. The contact line will spread slightly and then be pinned. At the terminal the liquid contract inward, and a ring-like stain is formed. Ⅲ. The contact angle is equal to 90 degrees. The contact line will always be pinned, and no ring, but spot stain is left. During the evaporation, we discover that the contact angle and the height of the drop do not change continuously but alternatively decrease by steps. The results of our investigation can be applied to the aspects of paint-spraying and jet printers.
平面上三點集中度判別法之探討
關於平面上若干點的集中度之定義，一直很少有人予以仔細的探討，因為判別的方法有很多種。本研究是以平面上三點所構成的三角形之三頂點作討論，分別以三角形的面積、周長，內心、外心和重心至三頂點距離，三點的標準差及平均差的概念，作為不同的判別方式，並以動態幾何化版ＧＳＰ模擬不同的判斷方法做為研究，在利用統計學上的方法，找出哪一種定義方式最為適合、誤差最少的判斷方法。There are many ways to determine the centralness of three dots on a plane; however, no definition study has been applied. In this study, we focus our interests on the entralness of three vertices of a triangle formed from three dots on a plane. Various methods such as the relationship of area, and the distance of the triangle to the centralness of three dots, the distance from the interior point, exterior point, the barycenter to the vertices of triangle, and the standard error and differences average obtained from three dots were determined with a dynamic geometry software GSP, and a statistic method was used to find a least error way to determine the centralness of three dots on a plane.
聚苯胺導電高分子在鐵系金屬防蝕上的應用與研究
聚苯胺導電高分子的發展蓬勃迅速，其應用也愈趨廣泛，金屬防蝕為其可能應用之一。台灣四面環海，工業發達，造成金屬腐蝕損害嚴重。本文為探討聚苯胺導電高分子在鐵系金屬防蝕上之應用，針對以下各點進行研究： ( 1）探討導電高分子聚苯胺性質與合成方法（2）探討聚苯胺導電原理（3）測試不同腐蝕條件下聚苯胺的防蝕效果（4）探討聚苯胺防蝕原理（5）各種氧化還原態聚苯胺防蝕效果之比較。實驗結果顯示塗布聚苯胺與未塗布聚苯胺之鐵系金屬（生鐵、不鏽鋼、鍍鋅鐵）在 3 ％氯化鈉、 0 . 5M 鹽酸、1M 鹽酸溶液中之腐蝕狀況，以鹼式中問氧化態聚苯胺（ Emeraldine base 。）最具防蝕效果。聚苯胺防蝕機構包含阻隔防護、腐蝕抑制劑、陽極保護、惰性化、形成保護性氧化物薄膜、阻礙離子擴散速率、電化學介面遷移等機構 ·The development and application of the conducting polymer polyaniline is getting prosperous and popular. One of the applications is corrosion protection. Because Taiwan is surrounded by sea and the pollution of industry is more and more serious than before the damage of corrosion is greater and should be properly controlled. In this paper, the authors attempted to study the effect of the corrosion protection of polyaniline in ferrous metal. This study could be divided into four parts: (1) the study of the property and synthesis methods for the conducting polymer polyaniline, (2) the conduction theory of the polymer polyaniline, (3) The corrosion protection effects of the polymer polyaniline under different corrosion situations, (4) the corrosion protection theory of the polymer polyaniline, and (5) the comparison of the corrosion protection effects of various polymer polyanilines. According to the experimental results the Erneraldine-based polyaniline gets the best corrosion protection effect. The mechanism of corrosion protection may be the result of the following ones: barrier protection, corrosion inhibitor, anode protection, innobeling, chemical active layer. inhibition of diffusion rate, and the shift of electrochemical interface.
氧化壓力影響基因轉換表現對脂肪分化之作用
細胞脂肪分化是造成肥胖、骨質疏鬆、和糖尿病的重要前置因素。我們若要維持良好身材又想省去減肥藥的問題，那麼我們必須了解造成脂肪化的原因，才可能擁有好的預防之道。利用人類骨髓間質細胞可以分化成骨質與脂肪等細胞的特性，我們研究氧化壓力對間質細胞\r Ras基因轉換表現後骨質與脂肪分化的影響。結果發現以添加超氧根 (O2-，l5nM)形成氧化壓力，可促進正常Ras基因表現的間質細胞朝骨質分化;相反地，超氧根會促進\r Ras基因突變而不表現的細胞，朝向脂肪分化的現象。進一步研究其作可原理，發現氧化壓力可促進 RaS蛋白質啟動細胞外訊息活化酵素(ERK)，接著驅動骨質轉錄因子(CBFA1)表現，再到骨鈣蛋白質與骨結節形成。而抗氧化酵素(超氧根轉化酵素;SOD,5OOU/ml)的作用，可以抑制正常Ras基因細胞氧化壓力下骨質分化的進行;但不能防止氧化壓力促進Ras基因突變細胞，朝向脂肪分化的作用。總結而言:Ras基因的表現與否，是決定脂肪分化的關鍵切換點;也是影響氧化壓力對間質細胞朝骨質分化的樞紐。這種基因與氧化壓力互動影響骨質與脂肪分化的剖析，將有助於提醒人們:使用抗氧化劑來調節抗衰老、肥胖、和美容時，必須是在不同情況和不同基因體質的人，有所不同。
\r Human\r mesenchymal stem cells are able to differentiate into bone, muscle, cartilage or\r fat tissues. Our preliminary study with human mesenchymal cell line (HS-5) showed\r that HS-5 cells could differentiate to bone, cartilage and muscle but not fat cells\r as determined by histochemical staining of phenotypes. We have further studied the\r influence of oxidative stress on the switch between bone and fat cell differentiation.\r Results showed that oxidative stress started with exogenous superoxide, produced\r by the interaction of xanthine oxidase and hypoxanthine, promoted the differentiation\r of osteogenic lineage showing expression of osteocalcin and bone nodule formations.\r The mechanism was investigated and superoxide was found to induce ERK (extracellular\r regulated signal kinase) activation; and then the expression of osteogenic specific\r transcriptional factor (CBFA1). A plasmid containing ras-mutant (Ser 17 Asn) which\r can inactivate the expression of ERK was transfected into the HS-5 cells for studying\r the influence of oxidative stress on ras-mutated mesenchymal cells. Surprisingly,\r it was found that oxidative stress did not promote osteogenesis but it enhanced\r adipogenesis from the ras-mutated HS-5 cells. Further studies indicated that superoxide\r neither induced ERK activation nor CBFA1 expression, but it did enhance expression\r of adipogenic specific transcriptional factor (C/EBPα) and lipoprotein lipase in\r the ras-mutated mesenchvmal cells. Taken together, the study model to induce the\r bone cell differentiation from human mesenchymal stem cells may be employed to make\r bone cells for tissue engineering.