“碘化鋅”產率變變變---溶劑對產率的影響
The research mainly discuss the influence on the rate of zinc iodine with different solution as catalytic agent. We use water, acid water, ethanol methanol acid ethanol, and acid methanol and so on as different solution to participate in the process of an equation: Zn+I2 → ZnI2 to work out the variation of the product's amount. Besides, we also change the proportion of Zinc and Iodine to discuss the difference between the proportion of reactant and the product's amount. The result shows that the product of this equation is ZnI2 not Zn(I3)2. Ethanol and methanol have the same effect as water to accelerate the process of the equation. We find out that this reaction get higher product's amount in acid condition. Also, put the mass Zinc with the mass iodine can get higher product's amount, Furthermore, acid in specific range (0.01M—1.00M), the denser the acid is, the higher product's amount we get. But how the water as catalytic agent work in the reaction is the direction we can research deeply in the days to come.
鋅和碘作用生成碘化鋅的反應,是用水作為催化劑,然而一小滴水卻使這個反應劇烈進 行,我們嘗試了多種和水具有相同作用的催化劑,由於反應時間極短不易測量,我們考慮由 產率部分著手,讓原本只需一小滴的水〈催化劑〉改為此反應的溶劑,計算其產率的變化。
實驗分為三部分,第一部份先是改變不同的溶劑,讓鋅和碘在不同溶劑〈水、酸化水、乙醇、酸化乙醇、甲醇、酸化甲醇〉下反應,計算出產率的變化,我們發現在酸中的產率的確較不加酸者來得高。第二部分我們改變加入鋅和碘的量,改變鋅和碘的比例,讓鋅由過量到成為此反應的限量試劑,觀察其產率的變化,我們發現碘作為限量試劑較鋅作為限量試劑的產率高。由於此反應在酸中產率較高,但酸的濃度高低是否又會影響產率呢?我們繼續第三部分的實驗,改變酸的濃度,讓此反應在不同的酸化水濃度的溶劑下反應,討論產率和酸濃度的關係,我們發現在一定範圍內〈0.01M~0.5M〉,酸的濃度越高,產率亦越高。
實驗方法是將鋅和碘置入同一試管中反應,並使其在不同溶劑中反應,接著離心,將碘化鋅水溶液與未反應完的反應物分離,將所得的碘化鋅水溶液使用結晶法得到碘化鋅晶體,秤重並計算其產率。
國民身分證相片規格驗證暨浮水印防偽系統
政府全面換發國民身分證,並訂定新式身分證之規格,以防範遭不法偽造之情事,確保民眾權益。然而其中的照片規格,有十多條規格的限定,若用傳統的辨別方式,近1876 萬張照片是否合乎規定,那將耗費多少的人力呢?於是本次研究主題「新式國民身分證相片規格驗證暨浮水印防偽系統」即產生,設計一套程式,提高換發國民身分證的工作效率及確保換證使用相片的正確度。並且延伸研究出使用內崁式的數位浮水印〈Digital Watermarks〉,將全國民眾的身分證照片統一建立資料庫,並自動加入個人資料浮水印。日後,照片只需透過本程式分析,即可知道其姓名、身分證字號、有無犯罪前科等個人資料。希望藉此達到降低偽造身分證之犯罪率,以保護民眾之權利。 The government is launching to renew national identification cards with new norms, to avoid fake ones. However, there are more than ten limits on photos, it could be wasting time to discern by people. Thus, I launched a research on "The xamination on new national ID card photos and watermark forgery-proof system". The program will help both to enhance efficient renewal process and to use correct photos. Also we developed the embeded Digital Watermark technology, which would create a database for ID cards of the nation and could add personal infomation automatically. With the help of the program, simply run the photo analysis, we could find out the names, ID number, criminal background, etc.We hope to decrease crimes via fake ID cards, and protect the national right.
臉上真的有蟲嗎?~揭開蠕型?的真面目
I’ve heard a report on the internet that there are mites on the face, even a clean face, and I took an interest in doing a research. First, I found that on the face is Demodex, which lives and depends on human beings; besides, nearly seventy percent of people have these mites on their faces. To know more about the habit of Demodex, I sampled forty people of both sexes and different ages. The analysis, not correlating with sex and times of face washing, showed that more mites are found on the forehead than on other parts of the face, and there is more probability to find Demodex on the face of those who are older, those who have oily skin, and those who suffer from acne. I also observed that these mites are photonegative, often gather together in the hair follicles, and feed on sebum. Moved from the human body, Demodex is livelier in sesame oil than in other kinds of oils, but its life ends in about eight to ten hours and dissolutes at last. In addition, I tried to devitalize Demodex by various kinds of medicine, cleansers and cosmetics, but only those containing sulfer, eau de parfum, and the essence of rosemary or lavender are efficacious. 網路傳聞乾淨的臉上也有蟲,引起我探索的興趣,查探後發現是和人類片利共生的毛囊 蠕形?和皮脂蠕形?,初步調查顯示近70%的人臉上都有蟲。為了更了解蟲的習性,以年齡 與性別區分共在40 人臉上採集樣本,統整結果得知,額頭比其他臉上部位多、年齡越大、膚 質油的發現機率較大,但不受面皰多寡、性別、洗臉次數等影響;觀察後發現蠕形?以人類 的皮脂為食,經常群聚在人體毛囊中,離開人體後在芝麻香油中活動力較佳,但約8~10 小時 後就死亡分解導致無法繼續觀察其生活史,對光有明顯的負趨光性,最後試著用各種藥品減 低蟲的生命力,以薰衣草、迷迭香精油、毒藥香水和蜜花沉澱硫等較有效。
豆類澱粉?抑制劑之研究與應用
豆類澱粉?抑制劑具害蟲防治與血糖調節之功效。本研究從台灣五種豆類中進行澱粉?抑制劑活性初篩,篩選出四季豆對麗蠅的澱粉?有明顯的抑制效果,粗萃後分離純化出單一蛋白質,經胺基酸定序結果得到兩個多?片段-VGLDFVLV 與TETSFNIDG , 與已發表文獻比對推測為腰豆澱粉?抑制劑—αAI-1。經測試發現此抑制劑在85℃時仍具備抑制果蠅澱粉?之活性,為一熱安定性蛋白質,其抑制作用受pH 值影響很大,在偏酸性環境下的效果最好,且其抑制作用具特異性,可明顯抑制果蠅、入侵紅火蟻、白蟻、蟑螂及麵包蟲等昆蟲的澱粉?活性。在調節血糖方面,本研究利用豬胰臟澱粉?進行抑制活性測試,篩選出四季豆、花豆與黑豆對豬胰臟澱粉?有明顯的抑制效果,進一步利用Wistar 品系大鼠,進行豆類澱粉?抑制劑降血糖功效之活體試驗,將四季豆、花豆和黑豆粗萃經濃縮乾燥後餵食大鼠,發現花豆、黑豆在第一小時具有顯著抑制血糖增加效果;四季豆、黑豆在第三小時血糖回升,花豆仍可維持較低血糖濃度。此初步結果顯示,花豆粗萃物可能具備減緩消化吸收作用,具應用潛能,其確切分子作用機制值得深入探究。Amylase inhibitors can be applied in pest control and glucose adjustments. The study screens Phaseolus vulgaris from five Taiwan’s beans that has the most significant inhibition towards Chrysomia megacephala. The protein was isolated and sequenced two fragments, -VGLDFVLV and TETSFNIDG, highly homologous to that of αAI-1 from Phaseolus vulgaris. The pure protein still inhibits the amylase from Drosophila melanogaster at 85℃, suggesting it is thermal-stable. Its activity was specific and was affected by pH, reaching the peak in weak acidic condition. It obviously inhibits amylases from D. melanogaster, Solenopsis invicta, Odontotermes formosanus, Periplaneta Americana Linnaeus, and Alphitobius sp. In addiction, the study points out Phaseolus vulgaris, Phaseolus coccineus L. and Glycine max, which have significant inhibition toward pancreatic amylase. The amylase inhibitors’ functions of decreasing in blood glucose were detected by animal experiments on Wistar rats. The rats fed with the extracts of Phaseolus coccineus L. and Glycine max showed the inhibition of glucose increasing at the first hour, while blood glucose concentration after rats fed with Phaseolus vulgaris and Glycine max increase at the third hour, and blood glucose after rats fed with Phaseolus coccineus L. maintains low. Its premier result indicates that the extract from Phaseolus coccineus L. might postpones digestion and has potential to be applied. According to these results, amylase inhibitors are worthy to further analysis.
平面上三點集中度判別法之探討
關於平面上若干點的集中度之定義,一直很少有人予以仔細的探討,因為判別的方法有很多種。本研究是以平面上三點所構成的三角形之三頂點作討論,分別以三角形的面積、周長,內心、外心和重心至三頂點距離,三點的標準差及平均差的概念,作為不同的判別方式,並以動態幾何化版GSP模擬不同的判斷方法做為研究,在利用統計學上的方法,找出哪一種定義方式最為適合、誤差最少的判斷方法。There are many ways to determine the centralness of three dots on a plane; however, no definition study has been applied. In this study, we focus our interests on the entralness of three vertices of a triangle formed from three dots on a plane. Various methods such as the relationship of area, and the distance of the triangle to the centralness of three dots, the distance from the interior point, exterior point, the barycenter to the vertices of triangle, and the standard error and differences average obtained from three dots were determined with a dynamic geometry software GSP, and a statistic method was used to find a least error way to determine the centralness of three dots on a plane.
敬"屑"不敏 --- 皮屑芽孢菌生長之探討
由於本身有頭皮屑的煩惱,在使用各種洗髮精之後,一方面覺得大部分的洗髮精效果不是很好,另一方面也擔心抗屑洗髮精的成分對人體有害。所以有了研究頭皮屑的念頭,希望能找出減少頭皮屑的方法。\r 在與幾位皮膚科專門醫師討論後,醫師們都不建議在直接人體上進行減少頭皮屑的實驗。於是我們將研究的重點放在〝皮屑芽孢菌生長之探討〞,希望對皮屑芽孢菌有更深入的瞭解。除了洗髮精之外,我們也將研究各種廣為流傳的民間偏方是否能有效抑制皮屑芽孢菌生長。在這些民間偏方的蒐集可兩大類:一類是在日常生活中可以很容易取得的物質,如鹽、醋、大蒜、生薑、洋蔥等;另一類則是台灣特有的物質,如無患子、茶籽粉、竹醋液等。\r 我們希望透過研究方法能瞭解\r (一) 溫度、濕度、酸鹼度、油脂對皮屑芽孢菌生長的影響\r (二) 哪些物質可以抑制皮屑芽孢菌的生長\r (三) 不同稀釋濃度的物質抑制皮屑芽孢菌的生長的效果\r 為了避免繁複的數量計算(如菌數計算),我們採用較多的對照比較(如抑制圈大小)。同時,我們設計了一個簡易的觀察與測量方法(稀釋法與抑菌指數),來比較各種民間偏方\r 的抑菌效果。\r 研究與實驗分為四大項進行:\r (一) 基本生長環境之探討:溫度、濕度、酸鹼度、油脂對皮屑芽孢菌生長的影響\r (二) 民間偏方抑制效果之探討:鹽、醋、大蒜、生薑、洋蔥是否能抑制抑制皮屑芽孢菌的生長\r (三) 民間偏方抑制效果之比較(抑制圈):比較各種物質的抑制圈大小\r (四) 民間偏方抑制效果之比較(稀釋法):利用抑菌指數來比較各種物質的抑菌能力\r 經過研究,我們所蒐集到的民間偏方都有某種程度的抑菌效果,大致可以分為強效(蒜液、竹醋液、茶樹精油)、有效(食鹽水、食用醋、洋蔥液、檜木芬多精、茶籽粉)及普通(薑汁、無患子)三種效果。\r \r Since I have the serious dandruff problem, I try to seek, except the shampoo, the natural materials to decrease the dandruff. After consulting with some dermatologists, they suggest I can focus my research on the “Malassezia Furfur”, which is the major bacteria causing the dandruff.\r This project is designed for finding the materials which have the most powerful inhibition capability for the “Malassezia Furfur”. I collect some folk prescriptions from the internet that salt, vinegar, garlic and onion can decrease the dandruff. The problem is “Do they have good inhibition capability for the Malassezia Furfur too?”\r The goals of the research are as followed.\r (1) The exploration of the basic environmental factors for the growth of Malassezia Furfur, such as temperature, humidity, acidity & alkalinity.\r (2) What kinds of material have the good inhibition capability?\r (3) The comparison of inhibition capability of the different material with different consistency.\r We especially design a method called “Dilution metering and index” to compare the inhibition capability of the different material. By using very simple observation, this method will transfer the simple “Qualitative Analysis” to the result of complicated “Quantitative Analysis”. The “Dilution metering and index” is the major achievement of this project, and it is also the good way for the projects which are not equipped with the precision instrument for bacteria inhibition capability measurement.
空心球的奧秘
上體育課的時候看到同學投空心球(籃球在沒有碰著籃框的情況下進入籃中),覺得好厲害。因此,我們利用相關的數學知識與運動原理來討論籃球投出後的運行軌跡,以及影響其命中率的相關因素。我們得知籃球的運行軌跡是一條拋物線,並求出其二次方程式;並利用標準籃球直徑與籃框直徑找出籃球進入籃框的最小入射角。若要提高命中率,必須考慮籃球投出時的投射角、初速度、籃球投出時的高度以及籃球與籃框水平距離之間的相關影響。此外,我們藉由電腦軟體列出相關數據提供作為實際投籃時的參考,並藉此進一步分析上述因素如何影響籃球運行軌跡以及如何提高投籃的命中率。Those who always shoot nothing but the net in basketball games were always heroes to me. I have being thinking for a long time how to become a person of that kind. For this, we investigated the trajectory of shooting a basketball and the factors to increasing the field goal percentages through our knowledge on mathematics and physics. We have obtained that the trajectory is in fact a parabola and, we further, found its quadratic equation. We also derived the minimal incident angle from the diameters of the standard basketball and hoop as well as the quadratic equation we have found. To raise the field goal percentages, some important factors must be taken into consideration, such as the vertical and horizontal distance between the basketball and the hoop, the incident angle and the initial velocity of shooting. Finally, we provide some concerning data for reference, and analyzed how the important factors we have mentioned above have affected our basketball trajectory and how, of the most importance, to increase the field goal percentages
聚苯胺導電高分子在鐵系金屬防蝕上的應用與研究
聚苯胺導電高分子的發展蓬勃迅速,其應用也愈趨廣泛,金屬防蝕為其可能應用之一。台灣四面環海,工業發達,造成金屬腐蝕損害嚴重。本文為探討聚苯胺導電高分子在鐵系金屬防蝕上之應用,針對以下各點進行研究: ( 1)探討導電高分子聚苯胺性質與合成方法(2)探討聚苯胺導電原理(3)測試不同腐蝕條件下聚苯胺的防蝕效果(4)探討聚苯胺防蝕原理(5)各種氧化還原態聚苯胺防蝕效果之比較。實驗結果顯示塗布聚苯胺與未塗布聚苯胺之鐵系金屬(生鐵、不鏽鋼、鍍鋅鐵)在 3 %氯化鈉、 0 . 5M 鹽酸、1M 鹽酸溶液中之腐蝕狀況,以鹼式中問氧化態聚苯胺( Emeraldine base 。)最具防蝕效果。聚苯胺防蝕機構包含阻隔防護、腐蝕抑制劑、陽極保護、惰性化、形成保護性氧化物薄膜、阻礙離子擴散速率、電化學介面遷移等機構 ·The development and application of the conducting polymer polyaniline is getting prosperous and popular. One of the applications is corrosion protection. Because Taiwan is surrounded by sea and the pollution of industry is more and more serious than before the damage of corrosion is greater and should be properly controlled. In this paper, the authors attempted to study the effect of the corrosion protection of polyaniline in ferrous metal. This study could be divided into four parts: (1) the study of the property and synthesis methods for the conducting polymer polyaniline, (2) the conduction theory of the polymer polyaniline, (3) The corrosion protection effects of the polymer polyaniline under different corrosion situations, (4) the corrosion protection theory of the polymer polyaniline, and (5) the comparison of the corrosion protection effects of various polymer polyanilines. According to the experimental results the Erneraldine-based polyaniline gets the best corrosion protection effect. The mechanism of corrosion protection may be the result of the following ones: barrier protection, corrosion inhibitor, anode protection, innobeling, chemical active layer. inhibition of diffusion rate, and the shift of electrochemical interface.
聚苯胺導電高分子二次電池之研製及性能研究
塑膠一向被認為絕緣體。但Heeger,MacDiarmid,以及Shirakawa證實,塑膠可以被改製成電的良導體。這須在高分子合成的過程中,使碳鏈呈現單、雙鍵交錯排列情形。此外,高分子也須加以摻雜(doped),換言之,電子必須在氧化過程中被移除或在還原過程中被加進聚合物。電子移除所留下的電洞,或新加進的電子則可自由在分子鏈上移動,形成導電性。我們所要製備的導電高分子二次電池就是由這個原理完成的。所謂的二次電池(Secondary Cell)簡單的定義就是「可反覆充電、放電,循環使用的電池」,我們將會將其與市售電池比較,並改良出合適商品化的高分子二次電池。我們將以聚苯胺做為我們電池的正極,並用鋅片(原本我們要用鋰金屬的,但其再空氣中即易氧化,因此改採鋅)做為負極,製成一聚苯胺二次電池。The plastics is thought to be a insulator, but Heeger, MacDiarmid, and Shirakawa had proved that conductivity of plastics can be improved by doping other media. The conjugated polymers such as polyacetylene、polyaniline have the interlaced single-double bonds that electrons can move from one side to another side caused the production of electric currents. The purpose of this study is try to study the application of the conjugated polymer polyaniline to make a secondary battery. First, we use the chemical and electrochemical method to compose the polyaniline. Then we test the conductivity of the produced polyaniline and test the current and electrical potential of the polymer battery. The battery that we made from our laboratory has the electric potential about 0.5 volts and the electric current is greater than 50 microamperes. Finally, we also try to use the lithium as cathode to improve the performance of the polyaniline battery.
研究傳統降火氣食品是否具有抗發炎效果
在炎炎夏日總希望來點可以「降火氣」的食品,依據古籍記載某些中藥材具有降火氣的效應,而中醫所謂的降火氣與西醫的抗發炎反應密切相關。本實驗利用巨噬細胞株受到LPS (Lipopolysaccharide,革蘭氏陰性菌細胞壁表面所含有的脂多醣體)刺激後,會分泌發炎介質的現象,再分別加入各項傳統認為可降火氣(以菊花、薏仁、仙草作為樣品)或上火氣(選用龍眼作為樣品)的中藥食材,來評估中藥材對巨噬細胞分泌發炎介質能力的影響。經由實驗,我們發現市售的『降火氣』中藥食材,在適當的濃度下,確實具有降低IL-6、TNF-α 分泌量的能力,但濃度過高時卻會造成細胞凋亡。另外,傳統以水熬煮的方式比冷凍乾燥取得的樣品有更好的降低IL-6、TNF-α 分泌量的能力。 我們期望以此一系列的實驗,來建立篩選『降火氣』食材的抗發炎效用的研究模式,並在後續實驗中可用以篩選出更多具抗發炎效應的中藥材。In summer, people always consider eating some special things to refresh themselves. According to ancient books, there are some Chinese herbal medicines that were recorded to have the function of cooling us down, which is related to anti-inflammation in the Western. Macrophage cell lines can be stimulated by LPS (Lipopolysaccharide) and secrete proinflammatory mediators. Thus, it is often used to evaluate the anti-inflammatory effects of different herbs. In our experiment, we also use macrophage cell lines to test different anti-inflammatory effects between chrysanthemum, Job’s tears and grass jelly. In addition, some Chinese herbs such as longan that can parch us are also tested in our experiment. In our results, we found these herbs that are available indeed have ability to anti-inflame in appropriate consistency; however, high dose does harm to cells. In addition, the samples that are poached in ancient ways have better ability to show the low dose of IL-6 and TNF-α. Finally, we would set up a model to test the anti-inflammatory ability of different herbs that were said to be able to cool us down, and then we could test more herbs in the future.