未得獎作品

本實驗是以實際探勘的地質及泉水資料和文獻為基礎，對於幾個可能造成冷泉降溫的原因(岩石種類、泉水pH值、流通氣體之壓力、流速)進行實驗。我們製作了一個模擬地下泉水流動的實驗管路，此管路並可同時觀察紀錄氣壓、氣體流速，以及實驗前後模擬管路的溫度變化。透過對實驗管路的熱容量校正，我們可以找出各變因對泉水降溫的關係，以建立出一個模型，期望可套用於實際冷泉的狀況，進而推論出更多冷泉的性質。This experiment uses data and bibliography from real exploration as bases to find the possibilities of why the cool spring drops in temperature. (Mineral types, spring water's pH value, air flow pressure, and movement flow.) We created a model of underground spring water for the simulation. From this model, we could observe the air pressure, movement, and the spring's change of temperature before and after the tests. By adjusting the thermal capacity in the model, we could find the direct cause of the spring's temperature drop. And hopefully be able to adopt this model to the realistic problem, increase the effort of analyzing the natural cool spring's properties.

本研究的目的在於探討螺旋狀剝皮對植物生存以及芭樂果實的影響。實驗的設計是將選擇的植株或其枝幹分成四組，分別施予環狀剝皮、螺旋狀剝皮一圈、螺旋狀剝皮三圈及不剝皮等處理。 研究結果顯示，螺旋狀剝皮不會導致植株死亡，且於處理部位下方會長出新的枝葉。芭樂果實經100 天的生長之後，不剝皮處理之枝幹長出的芭樂重量都在 300g 以下，而螺旋狀剝皮一圈之枝幹長出的芭樂有重達300-400g(5%)及 400-500g(5%)，最重的達 490g；螺旋狀剝皮三圈之枝幹長出的芭樂也有重達 300-400g(占 7.7%)。此外，與不剝皮處理者比較之，螺旋狀剝皮也有助於高甜度芭樂比例的提升。 本研究成果若能成功應用在其他果樹上，有助於提高果農產收的經濟價值。 The purpose of our study is to examine spiral bark-stripping’s effects on trees, and observe what will happen with this treatment, especially in the survival of trees and fruit of Guava. The experimental design is as below. First, we divided tree samples or branches into 4 groups randomly, and then treated each group differently with girdling, spiral bark-stripping a circle, spiral bark-stripping 3 circles, or non-stripping on the trunks or branches. As a result, spiral bark-stripping did not cause death of trees. Instead, new green leaves grew below treated area. After 100 days of growth, the fruit of Guava treated with non-stripping weighed below 300 grams, while some fruit weighing above 300-400 grams(5%) and 400-500 grams(5%) grew on those trees treated with spiral bark-stripping a circle, with the heaviest of 490 grams. Besides, there are some fruit weighing 300-400 grams(7.7%) growing on those trees treated with piral bark-stripping 3 circles. The result shows that spiral bark-stripping, compared to non-stripping, promoted the proportion of high-sugar fruit. This study provides a possible way to increase the economic value of fruit harvest if applied to other kinds of fruit trees.

This research analyzes goldfish’ (Carassius auratus) environmental preference behavior by setting up different environmental color-models to spur goldfish’reactions. It is investigated that pre-conditioned preference of goldfish was stressed by electric shock or high osmotic pressure. We’re interested in how stress experience modulate goldfish’ exploring behavior and its environmental preference. Goldfish that prefers brown-colored environment (compared with white) is suitable for being an model animal to investigate fish’s environmental preference. Both electric shocks and high osmotic pressure, two different kinds of stress, can affect goldfish’ behavior. It shows that fish have the ability to learn and memorize the stress experience. Besides, different stress has different effects on fish’ environmental preference behavior. It proves that there are complicated interactions among environmental stimulus, memories of stress and behavior caused by different kinds of stress.本研究利用環境色彩特徵的差異，建立朱文錦(Carassius auratus)環境偏好行為之動物模式，探討不同逆境刺激經驗(施予電擊或高滲透壓環境)，與魚類環境偏好行為的交互作用，以研究魚類的逆境經驗，是否可形成記憶，並影響其行為。我們發現朱文錦偏好土色環境(相對於白色環境)，適合作為探討魚類對環境偏好的實驗動物。電擊與高滲透壓兩種不同性質的逆境經驗，皆可影響朱文錦的環境偏好，顯示魚類具有記憶逆境環境的學習能力。此外，不同性質的逆境經驗，對魚類的環境偏好行為具有不同的影響。證明「環境刺激—經驗(記憶)—行為表現」三者之間具複雜的交互作用。

我們得知從高雄糖廠及堆肥中篩出的嗜高溫好氧菌Geobacillus thermoleovorans T4，是本種細菌首先被報導具有纖維素分解能力的菌株，但目前僅止於學術研究階段，尚未實際應用於廢棄纖維素的分解上。本研究以廢棄農作物纖維素取代學術研究所用的羧甲基纖維素(Carboxymethyl Cellulose，CMC) ，將T4菌株置於稻稈與米糠培養基內，進行分解效能比較，再利用酵母菌的發酵作用進一步將葡萄糖轉化為酒精。本研究發現，在60℃的環境中，活化的T4 菌株可在CMC、稻稈及米糠培養基中生長繁殖且發揮其分解纖維素為葡萄糖的能力，尤其在米糠培養基中的分解效果最快也最好。此外，將生產的葡萄糖加入酵母菌之後，初步發現也能成功地進行發酵作用產生酒精，生質酒精的產出指日可待！;The Research on Using Geobacillus thermoleovorans T4 to Turn the Deserted Cellulose in Agriculture into glucose in Order to Produce Bio-Renewable Energy It has been found that Geobacillus thermoleovorans T4, a thermophilic aerobic bacterial strain isolated from a sugar refinery wastewater （55-60℃）in Kaohsing, Taiwan, can secrete thermostable endocellulase and hydrolyze carboxymethylcellulose （CMC）in some academic research, but it is stillunknown whether T4 hydrolyzes deserted cellulose in Agriculture. The aim of this study is to investigate the best conditions of T4 cellulase activity after mixing with deserted cellulose (such as rice bran and rice straw) by measuring the glucose concentration and bacteria number, and to produce the ethanol by activated yeast. T4 was added rice bran and rice straw medium, and cultured in 60℃ for 10 hours. The number of T4 and the concentration of glucose were measured every two hours. The best conditions were examined by comparing the hydrolyzation efficiency of T4 in different cellulose medium. We observed that T4 grew efficiently in different cellulose medium and hydrolyzed cellulose into glucose, especially in rice bran medium. The yeast also converted glucose into ethanol. Our research may shed light to the development of bio-renewable energy!

本文我們研究下列問題： 1. 何時心律會成穩定的狀態呢？ 2. 是否能建立出心律穩定的數學模型？ 3. 什麼樣的函數會使得心律趨於穩定？我們以xmp+i 表示第p+1 個訊息傳到第i 個細胞之前，第i 個細胞的舒張時間，而且xk 和 xk−m, xk−m+1,..., xk−1的關係為 In this paper we study the problems as follows: When will the rhythm of heart beats approach to a steady state? Can we set up the mathematics model with steady rhythm of heart beats? What kind of function will make the rhythm of the heart beating tend to be stable? The result of our study is as follows:

打開水龍頭，水鉛直落到正下方的水平板時形成圓形水躍。我們實驗研究20＜Nr＜150 的低雷諾數圓形水躍的變因，探討圓形水躍半徑和流量、出水口高度、以及液體黏滯係數間的關係。改用高黏滯係數的液體（4：1 的乙二醇水溶液），鉛直落入板上方深h 的相同液體時，先形成圓形，h 漸大時形成環形圓紋曲面，再加大h，形成多邊形水躍，內外圍同方向旋轉，轉速ω；液中加水，黏滯係數高於及低於某定值，多邊形都消失，側面觀察，外圍液體作鉛直面旋轉。將水平板改置於旋轉盤上方，使高黏滯係數（4：1）的乙二醇水溶液鉛直落入板上方形成多邊水躍，逐漸加快旋轉盤的轉速至 ω 時，多邊形都消失；逐漸減少乙二醇的濃度，至完全用水實驗，亦有多邊形出現，我們認為；平板上方的液體的轉動是非圓形水躍的成因。When a jet of water falls vertically on to a horizontal plate, it spreads out rapidly in a thin layer until it reaches a critical radius at which the layer depth increases abruptly. This phenomenon commonly called the circular hydraulic jump. We study the variations of the circular hydraulic jump radius, as a function of volume flow rate of the jet, the drop height, and the viscosity of the fluid at low Reynold numbers (20＜Nr＜150). When a jet of ethylene-glycol mixed with water (the kinetic viscosity is 10 times of water) falls on to a horizontal plate which is immersed in the same liquid with height h. We find the circular state frequently undergoes spontaneous breaking at its axial symmetry into a stationary polygonal shape. Rather than displaying the weak angular deformation generally seen in fluids, the jump forms clear corners and edges that are often straight. Several of these polygon formations show consistency in height h. And we find the polygon structure rotates in a horizontal motion. When a jet of water falls on to a horizontal plate, and the plate is rotated by a motor ,we find the axial symmetry of the free surface of circular hydraulic jump is spontaneously broken a various number of cornered polygonal shapes. We study the number of corners as a result of the volume flow rate of the jet, the drop height and the viscosity of the fluid in the experiment. And the frequency of rotation of the plate is taking into consideration.

六種自行合成出來的聯吡啶釕錯合物Ru(bpy)₃、Ru(bpy)₂(phen) 、 Ru(bpy)₂dcbpy、Ru(phen)₃、Ru(phen)₂(bpy)、Ru(phen)₂dcbpy 及商用染料N3-dye，被成功的做成光敏性太陽能電池。光電流的產生率可由IPCE (incident photon-to-current conversion efficiency) 的測量可知。此類釕錯合物可以物理吸附或化學鍵結於TiO₂奈米粒子上。IPCE 的大小可以用來探討不同吸附方式的釕錯合物轉換光電流的效率。在物理吸附上Ru(phen)₂(bpy)的效率最好。化學鍵結的以N3 Dye 最好，我們合成的錯合物以Ru(bpy)₂dcbpy 較佳。此種以TiO₂奈米結構為承載基材的太陽能光電池(Dye-Sensitized Solar Cell)，染料仍以商用染料 N3-dye 最佳。本研究發現物理吸附的Ru complexes 也可產生光電流，若能最佳化，將可簡化染料錯合物之合成。 Six ruthenium complexes, Ru(bpy)₃, Ru(bpy)₂(phen), Ru(bpy)₂dcbpy, Ru(phen)₃, Ru(phen)₂(bpy), and Ru(phen)₂dcbpy were synthesized. These Ru complexes and N3 dye have been incorporated into the dye-sensitized solar cell system. The solar energy conversion of the ruthenium complexes were measured and converted to IPCE (incident photon-to-current conversion efficiency). There complexes were either chemically bonded or physically absorbed onto the nano-sized TiO₂ particles. The IPCE were utilized to compare the photon-to-current efficiency of these Ru complexes. Among the physical-absorbed dyes, Ru(phen)₂(bpy) has the highest IPCE. For chemical-absorbed dyes, the commercial N3 dye is still the best. Among the complexes synthesized in this research that are chemical-absorbed, Ru(phen)₂dcbpy has the highest IPCE The commercial N3 dye has the highest IPCE in the dye-sensitized TiO₂nanoparticle solar cell. We found that physically absorbed dye can convert photon to current. With better solar cell assembly, physically absorbed dye can have the same conversion efficiency as N3 dye.

資訊時代的來臨，促使我們的社會型態大幅改變，無一不朝數位化的方向邁進。網際網路與資訊科技的快速發展，近年來影像資料庫和數位圖書館大量的成立，關於影像資料檢索的研究已漸漸成為一門極為重要的研究議題。在本研究報告中，我們提出一種植基於向量量化編碼法的灰階影像檢索技術。向量量化編碼法是一種極為簡單的影像壓縮技術。我們應用這個編碼法，來萃取出灰階影像內容的特徵值。同時我們也計算出整張影像與影像中間位置的像素平均值，作為日後檢索影像時過濾掉影像資料庫中不需要比對特徵值的依據。\r 我們所提出的方法能有效地萃取影像內容的特徵值並且讓使用者可以快速且正確地查詢到所需要的影像。當影像資料庫中存在與查詢影像完全相同的影像時，我們的檢索技術都能在第一時間第一順位檢索出這張影像。即便影像資料庫中不存在與查詢影像完全相同的影像時，我們的檢索技術平均74.3%也能在第一時間前五個順位檢索出最相似的影像。\r \r With the coming of the information age, our sociological system change extensively, and everything has moves toward digitization. Due to the rapid development of Internet, information technology, the rapid growth of image databases and digital libraries recently, the related researches of image retrieval have become a very important issue. In this memoir, we propose an image retrieval scheme based on the vector quantization to retrieve similar images from the image database according to the pre-collected image features. Vector quantization is a very simple image compression scheme. We have applied vector quantization to extract features from grayscale image. In order to speed up the retrieval process, we also calculated the mean pixel values of whole images and the central part of the image to filter the images, which are significantly dissimilar to the query image.\r The experimental results show that our proposed approaches can effectively extract features from the image and enable users to retrieve images from image database quickly and accurately. When images stored in image database match query image, the proposed scheme can instantly retrieve the stored image at the first rank. Even though images stored in image database query image exactly, the proposed scheme can instantly retrieve the stored image over 74.3% at the first five ranks.

自組薄膜(SAMs, self-assembled monolayers)乃是具有特定官能基的化合物在不需外力作用 下自動吸附到基質表面上而自行排列成有自序規則之結構。SAMs技術因製備容易且穩定，在 應用上深具潛力。目前此方法中，以硫醇接在Au上的研究最為廣泛。本作品希望藉著SAMs 方法將硫醇分子吸附於鐵片或其他金屬表面上，以達成防鏽與抗酸目的。我們分別透過接觸 角量測研究正十二硫醇在鐵片上形成分子薄膜的可能性；利用酸與金屬產生氣體的速率研究 分子薄膜抗酸蝕的情況；測試分子薄膜的耐熱性；根據鐵片生銹時pH值變化、重量變化與[Fe2+] 含量差異來探究分子薄膜能否防鏽；最後找出適合形成分子薄膜的濃度與溫度效應。由實驗 結果我們發現SAMs薄膜確實能吸附於鐵(及鎳、銅、鋅等金屬)的表面上並增加抗酸與防鏽蝕 能力，薄膜對熱的穩定性極佳，35℃時結合效果較佳，而濃度的提高有助於SAMs的效用。 Self-assembled monolayers(SAMs) are elements which have specific functions.SAMs,ordered molecular aggregates can automatically adhere to the surface of substrate without any force.The applcation of SAMs’technique has high potential not only because ther are easy to make but also because they are stable.Exposing molecules such as alkyl thiols to an Au(0) surface is now in widespread use. In this work,we apply the thiols chemisorb onto the Fe or other metal surface to make it rust-resistant and acid-resistant.We study the following issues to find the appropriate conditions of forming monolayers in varying concentration and temperture: I. The possibility of forming n-dodecanthiol molecular monolayers on Fe surface by measuring the contact angles. II. The ability of antiacid corrodibility by comparing the rates of producing gas from acid and metal. III. The heat-resistant of molecular monolayers. IV. Whether it’s antirust by detecting the changes of pH,weight,and the concentrations of Fe2+ during the iron rust. According to the results,we conclude SAMs do adhere to the surface of Fe(and other matal like Ni,Cu,Zn), which increases the ability of antiacid and antirust.Besides they are stable to heat, have good combining effect at 35℃, and it is beneficial to the effect of SAMs through raising their concentration.

The natural fruits of soap berry are worth-while detergent in the aspect of environmental conservation. It has been shown that the soap berry fruits can reduce the itching of head and inhibit the growth of fungi. Here we would like to test the inhibitory activity of soap berry fruits on the bacteria. This might benefit to the further application of the soap berry fruits. First,the soap berry extract was prepared and mixed with E.coli or S. aureaus. The number of bacteria was counted to realize the inhibitory activity of the soap berries. We found that the soap berry extract can inhibit the growth of E.coli and S. aureaus. Higher concentration of the soap berry extract and longer duration for the mixture make better inhibitory activities. 天然的無患子果實是一種極具環保價值的清潔劑，已知它有抑制黴菌生長的能力，可以 去頭皮屑、止頭皮癢。因此，我們想進一步探討無患子果實對於細菌生長的抑制能力，以期 了解無患子清潔劑在廣泛推廣上的應用價值。 在實驗設計上，我們自製無患子萃取液，並選擇日常生活中常見的大腸桿菌及金黃色葡 萄球菌，並然後使菌液與適量的無患子萃取液混合，計算菌液在加入無患子之前、後的細菌 個數，藉以了解無患子的殺菌力。我們發現無患子萃取液對大腸桿菌及金黃色葡萄菌有明顯 的殺菌力，且無患子濃度愈高、作用時間愈長，殺菌力愈好。