摘要或動機

塑膠一向被認為絕緣體。但Heeger，MacDiarmid，以及Shirakawa證實，塑膠可以被改製成電的良導體。這須在高分子合成的過程中，使碳鏈呈現單、雙鍵交錯排列情形。此外，高分子也須加以摻雜(doped)，換言之，電子必須在氧化過程中被移除或在還原過程中被加進聚合物。電子移除所留下的電洞，或新加進的電子則可自由在分子鏈上移動，形成導電性。我們所要製備的導電高分子二次電池就是由這個原理完成的。所謂的二次電池(Secondary Cell)簡單的定義就是「可反覆充電、放電，循環使用的電池」，我們將會將其與市售電池比較，並改良出合適商品化的高分子二次電池。我們將以聚苯胺做為我們電池的正極，並用鋅片(原本我們要用鋰金屬的，但其再空氣中即易氧化，因此改採鋅)做為負極，製成一聚苯胺二次電池。The plastics is thought to be a insulator, but Heeger, MacDiarmid, and Shirakawa had proved that conductivity of plastics can be improved by doping other media. The conjugated polymers such as polyacetylene、polyaniline have the interlaced single-double bonds that electrons can move from one side to another side caused the production of electric currents. The purpose of this study is try to study the application of the conjugated polymer polyaniline to make a secondary battery. First, we use the chemical and electrochemical method to compose the polyaniline. Then we test the conductivity of the produced polyaniline and test the current and electrical potential of the polymer battery. The battery that we made from our laboratory has the electric potential about 0.5 volts and the electric current is greater than 50 microamperes. Finally, we also try to use the lithium as cathode to improve the performance of the polyaniline battery.