2006年

由於想了解化學反應的微觀形態，我們設計微型化學反應裝置來比較巨觀(傳統型)與微觀(創新型)化學反應間的差異，並探討其實用及環保方面的問題。在顯微鏡底下，我們觀察化學反應的沉澱結晶及電解反應，嘗試以各項變因(溫度、濃度、聲波…等)來觀察其結晶的型態。我們已成功地將實驗藥品用量減少到一滴(約0.04ml)，並以微觀的角度觀察化學反應的過程。在實驗中，發現反應進行時，粒子會不斷流動，經查證後為愛因斯坦所提出的布朗運動，並且測得硫顆粒的直徑大小約4.2 ~ 6.7 微米。不同聲波所造成硫粒子的移動速率不同，而不同溫度的部份，我們發現→每增加十度硫粒子移動速率增加約兩倍。在面積4.392×10-4cm2 範圍內大約有250~300 顆硫沉澱的粒子。本實驗成功地將顯微鏡應用在化學領域上，若將此實驗推廣，可達到污染少、觀察實驗的時間短、用量少的目標。此實驗是邁向化學微觀世界，一種值得嘗試且創新的方法。In order to compare the differences between the chemical reactions of macroscopic reactor and microscopic reactor, we have designed a device of chemical reaction and researched into the problems of their environmental protections and practical aspects. Under the microscope, we observed not only their precipitating crystal compound from the chemical reaction and electrolytic reation but their types of crystal. We have successfully reduced the dose to one drop ( about 0.04ml) and observed the process of their chemical reaction from the angle of microscopic reactor. During performing the experiment, we found the particles would keep flowing while the reaction was working. It was proved as "Brown motion" introduced by Einstein. The diameter of these particles were around 4.2~6.7μm. We find that different sound waves and temperatures,the motion speeds are quite different. And the movement rate increases about two times as the sulfer particles increase 10℃ each time .Within the measure of area of 4.392×10-4cm2,there are 250~300 sulfer particles.The experiment has successfully used a microscope in the field of chemistry. If we popularize the experiment, we can reach the goal of less pollution, fewer the dose and time-saving observation. It’s an innovation to step to the world of chemical microscope world.

茶品的發酵程度對其香氣與口感有決定性的影響，然而業界卻缺乏相關的客觀指標與其有效的量測方法。茶品發酵的主要化學過程是其兒茶素的氧化與聚合，這些茶單寧將隨著發酵過程逐漸由還原態轉變成氧化態。所以，不同發酵程度的茶，其氧化態單寧與還原態單寧的比將有所不同。這個比值預料可由氧化還原電位間接地量測得知。本研究使用白金絲與銀/氯化銀參考電極為電極對來量測此氧化還原電位。量具則使用具高輸入阻抗(大於十億歐姆)的pH 電極用電位計以取得茶汁中微弱的氧化還原電位訊號，可於十秒內取得高再現性(相對標準差小於3%)的電位訊號所得到的電位訊號與發酵程度呈高度的線性相關(相關係數大於0.9)。Degree of fermentation is pivotal for the aroma and the aftertaste of tea, but an objective scale and efficient evaluating methods are demanded for the important quality factor. Oxidation along with the polymerization of catechins is known to be the major chemical process during tea fermentation; the tea tannins will gradually change from their reduced forms to their oxidized formats. As the consequence, the ratio of oxidized tannins to reduced tannins will differ with the extent of fermentation. The ratio can be measured simply by the redox potential. In the present study, we used a platinum wire and an Ag/AgCl reference electrode as the electrode pair to measure the redox potential. A pH meter with high input impedance (over Giga ohm) served as our voltmeter for the weak voltage signals retrieved from tea infusions. The measurement was quick (less than 10 second) and with good reproducibility (CV0.9).

A study was conducted to improve the thermal stability, fire retardant (FR)\r properties and rheological properties of ethy-lene vinyl acetate because of\r its growing use in commercial applications. The approach employed\r was to modify an organo-clay, Closite 20A (C20A), with transition metal\r ions (TMI). In this study eight transition metal salts were acquired for\r modification. It was observed that all TMI modified organoclay\r nanocomposites improved thermal stability through thermo-gravimetric\r analysis (TGA). Rheological testing was done using a parallel plate\r measuring system (PP MS) to determine the dependence of storage\r modulus and loss modulus of copper and iron modified organoclay\r nanocomposites relative to pure EVA 350. The process of gelation was\r also tested for by calculating the ratio between the loss modulus and the\r storage modulus. It was found that copper modified organoclay\r nanocomposites promoted gelation and thus decreased the fluidity of\r EVA 350. The intercalation of the TMI modified organoclays with the\r polymer matrix was determined by the use of small angle X-ray\r scattering (SAXS). Testing revealed that the intercalation was\r successful, further proving that the TMIs had improved thermal stability,\r FR properties and rheological properties,

The heavy rain fall brought by Typhoon Mindulle in 2004 caused debris flows in the mountains of Taiwan. The most serious debris flows took place in the areas along the East-West Expressway. The area from Mt. Li to Tien Leng, namely, from the upper course to the middle course of River Da Chia. There was plenty of debris flowing to the courses of the rivers from the hot spring area in Ku Kuan to the starting place of East-West Expressway, Tien Leng. This situation caused the sedimentation of the river courses. According to the data issued by The Soil and Water Conservation Bureau of the R.O.C, on July 2nd debris flows erupted in the First and the Second branches of the river in Sung Ho Village and caused 1 death and 2 injuries, besides, the disaster destroyed 8 major roads causing transportation breakdown. On August 24th, the Typhoon Aere caused the heavy flow of the river which destroyed Po I Elementary School and Chun Chin Bridge. The researchers employed research reviews and field investigations as the research methodology with the research scope of Sung HoVillage in middle Taiwan and disaster of debris flow. The First and the Second branches of Sung Ho River belong to the category of high potentiality of danger of debris flows. The Chichi Earthquake had accumulated sufficient sedimentation of soil and stone. 2004 年敏督利颱風豐沛的雨量，引起台灣山區發生土石流，中橫公路沿線尤其嚴重。從 大甲溪上游的梨山到中游的天冷都有災情；谷關溫泉區至新中橫起點的天冷，大量土石，流 入溪中，造成河道淤積。據水土保持局的資料顯示，7 月2 日松鶴一、二溪爆發土石流，傷 亡各1 人，2 人失蹤，對外聯絡道路台8 省道崩塌中斷。8 月24 日艾莉颱風來襲，溪水暴漲， 沖毀博愛國小、長青橋及民房7 戶【1】。 本文以松鶴為試區，土石流災害為對象，使用文獻探討及現場調查的方法，進行研究。 結果顯示，松鶴一、二溪，均屬於土石流高危險潛勢溪流；肇因於九二一地震的崩塌地，提 供充足的土石堆積物。

單淘汰賽是一種失敗一次即遭淘汰的賽制；在此假定每位選手都有一相對應的能力數值，本文主要探討在均高的單淘汰賽程表之下，若賽程安排完全依照種子安排原則(亦即最強的選手對最弱的選手、次強隊次弱….)，則對於能力越強的選手越有保障，直觀上而言能力最強的選手應有最大的奪冠機率，探討此種賽程安排是否滿足能力較強的選手有較大的勝率？因發現在某些特殊的選手能力數值分佈之下會發生次強選手勝率大於最強選手的情況，令A、B代表最強與次強選手，P(A)、P(B)代表A、B奪冠的機率，故擬定P(B)/ P(A)為參考依據，尋求P(B)/ P(A)的最大值發生處作為最極端的狀況。發現四位選手的情況下，P(B) / P(A)最大值 = 1；八位選手的情況下，P(B) / P(A)最大值=(196+98) / 343=1.0938，當選手數為2n時，P(B)/ P(A)最大值隨n的增加而遞增。 Knockout Tournament is a highly competitive system in which any player losing a game can no longer play in the tournament. Here we suppose that every player has a numerical value that corresponds to his ability. We consider a totally-seeded knockout tournament with 2n players where in the first round, the strongest player matches the weakest player, the second strongest player matches the second weakest player, and so on. We examine whether a stronger player always has a greater probability of winning the tournament. The answer is in the affirmative for n = 2. For a tournament with eight players(n = 3), the situation is much more complicated. In certain cases, the second strongest player has the greatest probability of winning the tournament. Specifically, let A and B denote the strongest and second strongest players, P(A) and P(B) their respective probability of winning the tournament. We find that the maximum value of P(B)/P(A)equals (196+98) / 343 = 1.0938. For n > 3, we have not obtained the maximum value of P(B) / P(A) . However, it can be readily seen that the maximum value of P(B) / P(A) is non-decreasing as n increases.

Beings inherit various morphs and natural ability properties from their genetic parents to adapt to the environment and survive; Precis iphita iphita , for instance, is a best example of it. Although few literatures on Precis iphita iphita is found, through long-term field observation on the food intake, nest building, avoiding predator of immature stage, and living domain, the oviposition, plant preference of the adult, different stages of morphs and changes of behavior can be classified obviously when there are environmental or weather changes. The above can help investigate how they interact and influence with plants. This study aims to record and describe various behaviors and surrounding changes for Precis iphita iphita. 生物為適應環境求取生存，從親代遺傳許多形態、本能；黑擬蛺蝶（Precis iphita iphita） 的生活史就是個很好的例子。雖然文獻報告對黑擬蛺蝶的形態與行為描述不多，但藉由野外 長期實地觀察幼蟲的攝食、築巢、躲避天敵，以及成蝶的領域、產卵、食草選擇，可明顯區 分當環境、氣候產生變化時，黑擬蛺蝶不同蟲期的蟲體都有許多外在行為的改變，可作為探 討其與植物間的交互作用和影響。本研究旨在描述黑擬蛺蝶各種不同的行為與當時環境的狀 態，並將實際觀察所得詳實記載，以供他人比較參考。

To compare the habitat and physical\r differences of two burrowing scorpions, Opistophthalmus pugnax and\r the Opistophthalmus glabrifrons to be found in the Gauteng area\r (South Africa). Although these scorpions’ habitat overlaps, they don’t\r co-occur at the same site.

近年來，由於科技的進步，導致合成性高分子材料大量開發利用，雖然便利 了人們的生活，卻造成許多環保問題，例如：資源的消耗，以及對環境的污染。 然而「生物可降解人工合成的聚乳酸高分子」和「天然的幾丁聚醣高分子」均具 有優良的生物可相容性及生物可分解性，添加無機層狀蒙脫土可補強其機械性質 之不足。本實驗之目的是以生物可分解之合成性高分子聚乳酸作為主體，再和經 有機化改質後的蒙脫土摻混而製備出聚乳酸/蒙脫土之奈米複合材料。 本實驗主要分為三大部分： (一)以界面活性劑對蒙脫土進行改質 (二)製備聚乳酸/蒙脫土奈米複合材料試片 (三)對試片進行生物降解性測試 此外，本實驗以X-ray 繞射儀（XRD）檢測改質後蒙脫土層間距離的變化； 場發射電子顯微鏡（FE-SEM）觀察生物降解後複材之表面型態；膠體色層分析 儀（GPC）檢測生物分解前後複合材料之分子量的變化；DMA 檢測複合材料之 機械性質；TGA 檢測複合材料之熱穩定性Thanks to the development and advance of modern technology, the synthetic polymers have been put in wide use. Though the synthetic polymers provide convenience for our lives, they also bring about many environmental problems, such as consumption of natural resources and environmental pollution. Nevertheless, both biodegradable man-made PLA（Poly Lactic Acid）and natural chitosan contain good biocompatibility and biodegradability. Else, adding MMT（Montmorillonite）into PLA can modify the mechanical properties. Our experiment aimed to prepare the PLA （Poly Lactic Acid）/ Montmorillonite Nanocomposites by adding organo-modified MMT into the biodegradable PLA. The experiment underwent three phases：（1） modifying MMT by means of CTAB(n-Hexadecyl Trimethyl-ammonium Bromide, CTAB ) and chitosan （2）preparing PLA（Poly Lactic Acid）/ Montmorillonite Nanocomposites （3）testing the biodegradability of the Nanocomposites we prepared. While conducting the experiments, we made use of the XRD（X-ray Diffraction）to examine the change in MMT’s layer thickness. The SEM（Scanning Electron Microscope）was also employed to observe the surface pattern of the Nanocomposites, and used Gel Permeation Chromatography （GPC）to examine the decrease of the Nanocomposites’ molecular weight. Moreover, we also used Dynamic Mechanical Analysis （DMA）to test the mechanical properties of the Nanocomposites（Tensile testing）. Last, we test the thermal stability of the Nanocomposites by using Thermogravimetric Analysis (TGA).

在實驗用共振法測量聲音在固體、液體、氣體中的駐波聲場，測量各介質中的聲速。研究超聲波在液體中的空腔效應，鋁箔在不同液體受空腔效應所破損面積與時間略成正比，並發現在水與各濃度的洗潔精水溶液中以水的破損效果最明顯。另外利用1.65MHz 高頻超聲波打入水中，因駐波使水有疏密不同產生狹縫，以雷射通過狹縫有光的繞射花紋產生，由干涉條紋可推估駐波波長。利用閃頻共振法研究光彈材料超聲波場，且發展出以肉眼觀測的裝置，由光彈材料的花紋級數與應力研究中，發現花紋級數與應力成正相關，由聲場中的花紋顏色判斷所受應力大小，並發現超聲波不僅有聲場產生並伴隨熱效應，會影響觀測花紋級數。This project began by studying the fundamental properties of acoustic waves, the relationship between its velocity, frequency and wavelength. Experiments regarding the distribution of sound waves in different mediums, and the induction of resonance in solid, liquid and gaseous materials were conducted. Results from utilizing suspending method to confirm theoretical prediction of sound velocity was accurate, and the sound wave patterns in photo-elastic materials were observed. It was also observed that an aluminum foil would be cut in an ultrasonic cleaning device. The effects of different liquids such as water and detergents on cleaning effectiveness were then experimentally determined, taking into account factors such as viscosity. From reference materials, we learned that ultrasonic waves would create Caritation in liquids. Traditionally, sound waves are expected to exhibit only longitudinal waves, yet in this study it was discovered that the residual\r stresses from resonance in photo-elastic materials also indicate the existence of transverse waves.

原題目是環球城市盃中，一個圖論的問題。而題目提供了一個證明，是證 明此種連線都是偶數的圖形，一定會在三的倍數邊形成立。在經過一番思考過 後，我們希望能將原本的偶數連線性質加以驗證，並確定奇存在性。此時，我們 也不禁聯想到：奇數是否也有所特別的性質。因此，我們也向奇數連線做研究。 就在平面得到了部分結論的同時，我們想到這個問題是否可以推廣至三維 空間。然而在推至三維空間的過程中，我們又聯想到，另一種平面：球面。在球 面上放點，能否也找到一些不同的性質。因此，我們分別從平面、球面、立體圖 下手。 基本上，探討平面和立體問題的方法，是以土法煉鋼的方式來求出結果。 然而這種圖論的問題，不可能嘗試到無限多點的情形。因此，我們是著找出一個 關鍵的key，那就是結合性質和外接合性質。以這兩種方法，我們可以將一個簡 單的基本圖形，推向無限多點和無限多邊的情況。 接下來，還有討論一些特殊狀況，例如： deg v＝3n+1，探討其結果。 最後得到的結論是： 1、平面偶圖成立的條件為：此多邊形為三倍數邊形， 而且除了內 部一、二、四點以外， 其他點數都可以成為偶圖。 2、平面奇圖成立的條件為：奇數邊形的情形下，除了三點以外，其 他的內部奇數點的都可以成為奇圖。偶數情形下， 除了四 點以外， 其他的內部奇數點的都可以成為偶圖。 3、三角形平面圖，d eg n 皆為m 成立的條件：2＜ m＜ 6( m? N ) 4、三角形內外任意點d eg 皆為3n ( n ? N )的成立條件： 三角形內部4 x+1 個點( x ? N )。 5、三角形內外任意點d eg 皆為3n+1 ( n ? N )的成立條件： 三角形內部3 x 個點( x ? N )。 6、立體偶圖n 頂點(n＞4)面體的成立條件為： 內部點數為5m+ n- 3、5m+ n- 1、5m+ n、5m+ n +1、5m+ n +3。(m 為大於或等於零的整數) 7、立體奇圖四面體的成立條件為： 內部點數為偶數皆存在。 The original problem is a question of Graph Theory in IMTOT ,which provides\r a proof that proving the figure which its linking-line number is even ,should also be\r contented in the triple-sides figure. After profound consideration ,we try to make sure\r the existence of the properties the we mentioned above. Meanwhile ,it also occurs to\r us that whether the properties would be contented ,in the figure which its linking-line\r number is odd. So we make our way to it. Additionally ,three-dimensional and\r spherical figures are part of our research as well.\r Basically ,we discuss the problem in two-dimensional and three-dimensional\r aspects with the simplest method .However ,it is impossible to discuss the problem in\r unlimited dots .Hence , we are going to find a “key” to solve this problem .As a\r result ,we can find a simple basic-picture , and expand to infinite-multiple lateral\r pictures.\r Next step ,we also discussed some special situations , for example: for each\r point v , deg v=3n+1.\r At last the conclusion is following:\r 1、The conditions of linking-line number is even: triple-sides. And the amount of\r points inside the figure is without 1,2,and 3.\r 2、The conditions of linking-line number is odd: In the odd-sides figure , all number\r of the points inside the figure can be content without 3 point. In the even-sides\r figure , all number of the points inside the figure can be content without 4 point.\r 3、In a triangle , each point’s deg is the same number m: 2