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泡泡的特性研究

在參考文獻 Chemistry In The Marketplace 中,讀到若將兩個大小不等的泡泡連通,由於內壓差的關係,小泡泡內的氣體會向大泡泡移動。我們想實際實驗泡泡是否真會如此移動?可不可能發生相反的情形?能不能用泡泡移動的現象來比較液體的界面張力大小?

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評估不同有機酸用於燃料電池之可行性

本研究主要著重在以三極式電化學測試探討不同有機酸燃料甲酸、草酸、檸檬酸與不同觸媒Pt/C、PtRu/C、PtPd/C 在陽極電極的氧化反應之研究。從CV 圖可得知,分子量較低的甲酸有較低的氧化電位。以CV 與LSV 圖可知,以較高的氧化電流區分,是以PtRu/C 為三種觸媒中最適合當陽極電極的;若以穩定度區分,則以PtPd/C 為最佳。我們挑選PtRu/C 此觸媒進行燃料電池放電性能測試,得到的電流不高,原因在於配置的甲酸溶液為1M,甲酸在PtRu/C 電極反應太快,質傳推動力不足,使得燃料供應不足,造成電位迅速下降。This main target of this study is using three-electrode cells to choose which Formic Acid, Oxalic Acid or Citric Acid and Pt/C, PtRu/C or PtPd/C are better for fuel cell. From CV test, Formic acid which structure is simple has the lowest oxidation potential. Combine CV with LSV, if we focus on current, PtRu/C is the best catalyst for fuel cell. But if we focus on Stability, PtPd/C has the best of them. We choose PtRu/C to do the cell performance test. The current density isn’t enough high, this is because the concentration of formic acid is just 1M. Oxidation reaction of formic acid on PtRu/C is very fast. Mass transfer driving isn’t enough for this high reaction rate, so the potential drop is very fast.

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從小玩意探討大問題-磁浮隔空旋轉器的轉動情形與磁場變化之研究

磁浮隔空旋轉器是由一個旋轉軸和底座構成,利用兩者間相互排斥的磁力, 產生隔空漂浮的效果。本研究首先對旋轉軸的結構加以分析,並設計啟動裝置, 探討啟動電壓、旋轉軸重量及底座磁力等因素對漂浮轉動的影響。 我們分析維持旋轉平衡的各種作用力,並探討旋轉軸重心位置與摩擦力的關 係,以驗證我們的分析結果。此外,我們也利用自行設計的啟動裝置,提供穩定 的初始轉速,探討旋轉軸重心位置不同時,持續轉動時間的變化,進一步驗證所 做的分析。 為了瞭解磁場在旋轉軸漂浮過程中發生的變化,我們設計了支架把空間座標 化,再以高斯計測量出各點的磁場,獲得各平面的磁場強度分佈圖。配合磁力線 分佈圖與所測得的磁場強度分佈圖,我們以一個嶄新的分析模式,將抽象的磁場 概念具體化,使我們對旋轉軸放置前後及磁力與重力平衡時的磁場變化,更深入 的了解,同時也發現磁場強度會隨距離的增加而減弱。 最後我們在旋轉器上裝置感應線圈,經由旋轉實驗測得感應電壓的存在,證 明旋轉器轉動時,磁場會產生變化。 經由對磁浮隔空旋轉器的探討,我們得以了解它的漂浮原理、磁力與摩擦力 間的平衡關係,以及旋轉前後磁場變化。The Magnetic Floating Spinner(MFS) is composed of one spinner with a magnetic base. The floating effect of the spinner is caused by the interaction between the two opposite magnetic fields. We first analyzed the detail structure of the MFS, and then designed a starter to rotate it. Later, we studied the effect of starting electric potential, the weight of the spinner and the magnetic force of the base on the floating movement. We presented an explanation for the forces that maintained the floating of the spinner and, to support that, we studied the friction force with the position change of the spinner gravity centre. We also used the starter designed by us to provide a stable initial rotating force and analyzed the relationship between the change of gravity centre position and the duration of rotation. In order to understand the magnetic field change during floating movement, we designed a spatial frame to coordinate the spinner that floated above the base. We measured the surrounding magnetic force with the Goth’s apparatus and conducted a magnetic force distribution diagram. According to this diagram and the line of magnetic force, we therefore provide a brand new analysis model , which bring the abstract concepts of the magnetic field into a concrete theory. This research not only brings us to understand the magnetic field change of the spinner before and after its placement over the base and the balance between the magnetic and the gravity force, but also reveals that the magnetic force will wane with the increase of distance. Finally, we placed an induction coil by the spinner to detect a voltage change during spinner movement. This is an evidence that the magnetic field will change during the spinner movement. Through the study of MFS, we can now understand why it floats, the balance between magnetic and friction force, and the change of the magnetic force before and after the spinner movement. MFS = Magnetic Floating Spinner

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Hourglass 2011

Over the past year Conor has been developing an electronic time keeping device named Hourglass. Hourglass has a three-fold focus on functionality, intuitive design and simplicity. To simplify the device he has limited the hardware to a bare minimum. Just three buttons and an LCD screen comprise the user-interface. Although this interface is simple, the user can access many features. These include intuitive scrolling menus, countdown, lap and alarm functions, accessed through button combinations as well as multiple ways to use single buttons, such as holding or short pressing. Many functions have been integrated into the device, such as a stopwatch with lap times, a countdown, up to 99 Custom Alarms with an individual active/inactive state and a lock/unlock feature. The stopwatch is accurate to 1 second and can be started, stopped, reset and used to record lap times. When laps have been recorded, the user can then take the time value of a lap and turn it into a countdown. A countdown of up to 99 hours can be set, and will run until deactivated or until it reaches zero. Upon reaching zero the alarm is activated. The home screen displays the time, any active countdown and notifies the user if an alarm is active. It can be locked or unlocked by holding the blue button a set period of time, helping to reduce any inadvertent change in setting. All of the functions available can be operated easily with the intuitive 3 button interface method. The menu system is simple, but has been set up through clever coding. An arrow indicated which option is selected, by pressing the top button on the clock the option above the current selection is selected/the menu scrolls up. Pressing the bottom button selects the next option in the downward direction/scrolls down. The button in the centre positioned off to the left is used to activate an option. When a Yes or No prompt appears on the screen, the action corresponds with the button position. Therefore the triangle layout of the buttons is simple and intuitive. Thus Conor’s device relies on complicated, yet elegantly formulated and annotated code and simple hardware interfaces to interact with the user in a way which is intuitive and provides great functionality. It does this while being simple and easy to understand. Here these principles are applied to a clock project, but there are implications for good design that go way beyond this context.

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Johnny the Random Walker-振動平面上的顆粒運動

顆粒在受垂直振動時有擴散、對流的現象,其中對流的情況較難觀察,但表面的擴散可用影像擷取分析系統來測量。本實驗利用喇叭作為顆粒振動的能量來源,將顆粒放入扁平的壓克力圓盒,再用攝影機、ImageJ作為影像分析系統。同時透過顆粒數目與Γ值(振動台最大加速度與重力加速度的比值)兩種變因,分析兩變因對於擴散係數、平均自由徑及平均自由時間、速率分布的影響,探討顆粒在近似於平面上的運動行為。

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積木與級數

我們發現 l+ 2+…+n=n(n+l)/2這個公式可用下列這種積木堆積方式證明:我們先將其式子看成如下的積木排列數:如〔 圖(一)〕 這時,我們將另一塊形狀大小完全相同的積木組合,與圖(一)疊合如圖(二)。 ∴很明頭地,疊合成的積木組合為一矩形,積木數 2S=n(n+l) ∴S=n(n+1)/2 即 l+2+…+n=n(n+l)/2

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Giving Bugs the Chop !

The purpose of the research was to find out if Manuka oil (an oil with natural healing properties which is extracted from the NZ Manuka plant, Leptospermum scoparium) could be used to reduce the populations of bacteria and fungi that build up on chopping boards used in the kitchen for food preparation. If it were effective, then it would reduce the risks of microbial contamination of foods prepared using the boards.

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還我無水污染的顯微電解世界

Chemistry experiments in school produce an abundance of waste in both materials and equipment. Since hands-on experimentation is a critical pedagogical tool the trend in classroom experimentation is clearly towards environmentally friendly experiments that scale, but was also able to measure reaction rate in blue cupric sulfate solution using the color dissipation as a rate gauge. There was an evolution of apparatus and experiment design beginning with simple magnifying glass optics and advancing to a custom made, light-gathering microscope video apparatus that allows the experiment to be monitored and files recorded for later viewing. I was inspired by the Yin Yang Sea phenomenon in Taipei County. The Yin Yang Sea is a coastal area in Chinkuashih, Taipei County where coastal currents in the area lack the strength to disperse the heavy metal pollutants that empty into the Lientung Bay. The result is a contrast between the blue sea water and the turgid yellow ground water. This contrast led me to add an all-purpose indicator to the reactant solution. This deepens the visual effect of the electrolysis experiment. 我們從環境保護的角度去思考學校的化學實驗時,減量減廢的微型化學實驗已是未來實驗的趨勢。經過多年的努力,我除了成功的做到電解最微量的一滴溶液外,對於從藍色硫酸銅溶液顏色消失的電解時間裡,還可做定量的檢定感到不可思議!為了更清楚看到液滴溶液的電解反應,儀器的設計由放大鏡到自組顯微投影機,最後進階到顯微視訊的畫面,它不但可記錄下來,而且可在電腦中播放。為了更清楚看到液滴溶液的氧化還原反應和酸鹼變化,我想到了在北台灣的金瓜石海域一處特別的景觀,那就是離岸近海處有黃藍兩個不同顏色的陰陽海!於是我加了廣用指示劑到液滴中,由電解後出現的的陰陽海畫面,更可加深實驗的效果。 最重要的是:最環保也最接近零污染的顯微化學實驗,已然是未來可發展下去的目標。

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以簡易方法探討奈米銀的化學活性優於非奈米級銀粒子

A novel and simple method was developed to determine the activity of silver in nanometer particles more than in non-nanometer particles. The conductivity of conducting polymer, polyaniline (PANI) doped with different amount of nanometer silver particles was used to evaluated the activity of nanometer silver. In polymerization of polyaniline, hydrogen chloride solution usually used to increase the conductivity of polyaniline. When 1%(w/w) nanometer silver particles doped during the polymerization, the conductivity of polyaniline was down from 2.28 s/cm to 0.65 s/cm, then increased with increasing the amount of nanometer silver doped. The conductivity of polyaniline was changed from 2.28 s/cm to 0.47 s/cm when 3%(w/w) nanometer silver particles doped, but it is increased from 2.28 s/cm to 2.44 s/cm when was doped with 3%(w/w) micrometer silver particles. The conductivity of polyaniline changed due to the formation of silver chloride (AgCl) in doping nanometer silver. Some of the nanometer silver particles were formed to silver ion in hydrogen chloride solution for the high activity property of nanometer silver. This also can be proved from the spectra of XRD and FE-SEM. Therefore; determination the conductivity of conducting polymer by doping nanometer metal particles can be used to determine the activity of the nanometer particles. 本研究為開發一個新穎的檢測奈米金屬粒子化學活性大於非奈米金屬粒子的簡易方法。方法為利用導電高分子聚苯胺,於合成過程中添加不同濃度的奈米銀粒 子,並分別偵測其成品的導電度,藉以評估奈米銀粒子的化學活性。由於聚苯胺在合成過程中通常加入鹽酸以提高其導電度,致活性較大的奈米銀粒子於氧化後,隨即與氯離子形成氯化銀的沉澱,而降低聚苯胺的導電度,如添加1﹪(w/w)奈米銀粒子的,其導電度由2.28 s/cm 降至0.65 s/cm,隨後隨著添加量的增加導電度先降後再稍回升。一般非奈米級銀粒子因氧化電位為負值,即化學活性小,而不易被氧化。由實驗結果,我們發現同樣添加3%(w/w)的奈米級銀粒子或微米級銀粒子,添加奈米級銀粒子的導電度由2.28 下降為0.47,添加微米級銀粒子的導電度卻由2.28 上升為2.44,此乃說明本方法確實足以證明奈米級金屬的化學活性的確遠大於微米級金屬,因相同條件下,微米級銀粒子未如同奈米級銀粒子一樣被氧化成銀離子。即奈米級銀粒子可以輕易的被氧化,而非奈米級銀粒子則不易被氧化。尤其也可由X 光繞射儀分析光譜圖和場發射式掃描電子顯微鏡拍攝圖證明。因此,我們可以採用添加3 %(w/w)奈米級金屬銀粒子及微米級金屬銀粒子於導電高分子的方法,並藉導電度的變化,證明奈米金屬粒子的高活潑性。

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Moire'圖形在數學上的應用

物理課做水波槽實驗時,重疊的波紋引起我們極大的興趣。於是老師介紹我們看一篇( The Physics Teacher)雜誌中有關Moire' Pattern 的文章。Moire' Pattern 的特徵是當有寬度的條紋彼此重疊時,會出現一些新的圓形,我們對於這些富於變化,又具有規則性的圖形,感到興奮不已,就開始研究了。

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Transiency

Transiency… something which only stays for a short time, and changes\r frequently. You’re probably wondering now what this has to do with our sports and\r we must admit that at first sight it really doesn’t seem to, but think of the world an\r how many changes sports have experienced. Is it not time we thought of how sports\r facilities could be improved? And what if you were told that there would be an\r “ever-changing” sports centre which you could use?\r You really might get the chance to use such a sports centre one day, and that’s\r what our idea is all about. A multipurpose sports center is what you could call it, but\r it’s not in the least like any one you’ve seen before. In places like Hong Kong, where\r space is everything, multipurpose sports centers are common, but they always have\r so many colored clines that tend to confuse both players on the court and spectators\r off the court. Just how often have you seen referees and players arguing about\r whether the ball is out or not? And how often have you found that you are not\r enjoying the game as much as you should? Yup, we’re sure it happens all the time,\r but you don’t have to worry anymore, as our innovative design will solve all your\r problems. Yes, its time for us to change…\r In our dream sports mat, we’ll have lines which can change and also detectors to\r tell you where the balls land. You’re probably thinking, “Lines which change?”, and\r yes that’s it! The perfect solution to all those confusing lines would be lines which\r could change their positions. And to do this, we’ve made use of some new technology\r called ‘E-INK’ which would make this possible. Of course it sounds like something\r which is really costly but in fact, this technology doesn’t cost that much and its really\r durable, so it’s really worth the money to start changing. Moreover, these mats can\r also be rolled up and stored somewhere else, so when you don’t need to use the sports\r ground you can just pack it up and the venue can be used for other purposes.

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Mathematical Analysis of Root Growth in Gamma-irradiated

Root growth is related to the acquisition, distribution, and consumption of water and nutrients of plants. As a vital organ, roots directly take the effect of environmental change and its behavior is closely related to the growth of the whole plant. With such, the importance of root systems has motivated botanists to seek a better understanding of root branching complexity. This complexity, which has been difficult to comprehend using simple Euclidean methods (i.e. lines and circles), is important to the survival of plants, especially when the distribution of resources in the environment is scarce. Mathematical models using fractals and computers can be applied to accurately understand the growth and form complexity of plant root systems. This study was conducted to analyze the root growth of gamma-irradiated cashew and mangosteen using fractals.

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