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什麼尚「氫」--談燃料電池之放氫探討
氫是一種非常理想的能源。不僅效率極高,且不會造成環境污染。空氣中的含量極少,常用的電解水方式又效果不彰。我們利用Ag、Ru、Cu 、C-CuPu、C 等數種電極,與H2SO4、 H3PO4 、HNO3 電解液,分別在10V 雙電極與-0.8V 三電極下做電解水實驗,研究何種電極與何種電解液能得到最多的氫氣量。在低電壓下找出最好的電極,液與太陽能電池結合,成為電池中的一部份,讓發電效果更好,以利未來燃料電池H is a kind of great power.It is not only effective,but also no environment pollution .Owing to the H in the air is very little,so it is not easy to take .Addition to,we often to take it by electro liquid,but the electrolysis effect is not ideal. Except Ag、Ru、Cu、C-CuPt、C and so on ,in theH2SO4、 H3PO4 、HNO3 electro liquid,we have a experiment in the 10V dual electrode and -0.8V triple electrode to study which electrode and which electro liquid to get the most of H.Under the low voltage,we can fund the best electrode.It is easy to bind with solar energy battery,andit can be a part of battery.Besides, it makes the generator effect better,and it is convenient to make the fuel cell commercialize in the future.
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蟹殼幾丁凝膠應用在金屬氧化物奈米顆粒的製備與燒結
筆者利用自製的幾丁質與不同金屬的混合溶液而燒結出的奈米顆粒成效極佳,不但粒徑大小符合,在燒結的過程中也不需經過物理研磨及介面活性劑的輔助,並且在低溫下即可燒結,可以增加實用性以及商業價值。此外,在分解亞甲藍方面也有不錯的效率,並進一步從金屬氧化物之奈米膠體混合溶液比例的不同,決定其粗糙度(以AFM測定)及能隙改變,在陽光下有更高的應用效率。而在實驗的延伸研究上,希望應用在防菌、除污、甚至光電池。 We make use of self-made chitin with the mixed solutions of different metals to solder nano particles, and the result is excellent. The particle radius not only matches up to the size, but in the process of soldering nano particles, it doesn’t need any physical pulverizing or surfactant assistance. Also, it can solder in low temperature. And we could raise its practicality and the business value. What’s more, there is a good efficiency in decomposing Methylene Blue. We can further decide the roughness (measured with AFM) and the variation of the band gap from nano colloid of different metal oxide mixed ratios.Our experiment in the extending research aims to apply it to the defense of bacteria and pollution, and even photoelectric cell.
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Waits and Measures
Successful calving is measured by the safe delivery of a healthy calf. Any factors that\r cause dystocia (difficult calving) are undesirable; as it will result in weak or dead calves, stress\r dams and a decrease in profit to the rancher. The most often identified reason for dystocia are\r calves that are too large at birth. Ranchers frequently use sires that will result in calves with\r small birth weights that will be born easy. This is especially true when breeding first calving\r heifers. The selection for small calves at birth results not only in less growth in the uterus but\r also less growth after birth, which means less beef to sell. This means ranchers try to balance\r reasonable growth and reasonable calf size when selecting their sires. Much data has been\r published on birth weight and its selection.
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無紫外光下的抑菌-可見光奈米光觸媒研發
In this experiment, we hope to produce appropriate-sized nano particles of by using the chitin. By mixing the particles with the metal of Ti, Fe and Zn of proper proportions and therefore narrow their band gaps. Thus, the Bacteriostasis of LightPhotocatalysts could appear under the environment where the energy is lower than ultraviolet ray. We use de-acetylated chitin in three ways -- chelating agent, surfactant and protecter. Then we put a thin layer of the mixture of chitin and metal nano particles on a piece of glass, and afterwards, sintering the mixture on the glass. Next, we scan the surface of the glass with AFM(Atomic Force Microscopy) to measure its particle size. The result we got showed that the surface-roughness of the Ti-Fe nano particles was 30.642nm, the best solution of all the samples. Yet, in this experiment, Fe was not suitable. Therefore we should choose the sample of Ti-Zn mixture, which is slightly smaller in roughness. According to the result we got from the experiment, we found that, under the yellow light, the survivable strain-number ratio of the sintered Ti-Fe-Zn mixture on the glass and empty glass was 0.09±0.06. This was much better than the survivable strain-number ratio of 0.17±0.06, the result we got out from the glass of pure Ti and empty glass. From the measurement, we found that the proportion of mixture could lower the excitation energy Ti needs. Through this experiment, we hope to create a layer of film containing nano particles, and by applying it to daily-use products, we could prevent harmful bacteria. 本實驗的目的,就是希望可以利用幾丁質製作出適當粒徑大小的金屬奈米顆粒,混合適當比例的鈦、鐵、鋅金屬,使其能隙變窄,讓我們能在低於紫外光能量的光譜下,產生奈米光觸媒的抑菌效果。筆者在實驗中利用去乙醯化之幾丁質在本實驗中扮演三種角色:螯合劑、介面活性劑及保護劑,以將幾丁質與金屬奈米顆粒均勻塗抹於玻璃上,並以燒結玻璃的方式進行實驗。並且利用AFM掃描玻璃表面,確認其表面尺度,驗證的結果Ti-Fe混合比例的奈米顆粒之表面粗糙度為30.642nm,為最佳狀態,但在本實驗中Fe並不適用,故應以粗糙度僅次於Ti-Fe的Ti-Zn混合比例為主。根據實驗的結果,在綠光下,混合比例的Ti-Fe-Zn玻璃與空白玻璃的菌落數比,菌落存活率為0.09±0.06,相較於純Ti的0.17±0.06來的低,代表混合比例可降低Ti所需之激發能量。經過此實驗未來筆者希望可以以幾丁質製作出一層含奈米顆粒的薄膜,應用到各種生活用品防止細菌的危害。
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The discovery of America
1.- Purpose of the research This Game is a new education system, where we take as reference a historical event called "The Discovery of America." The objective is to implement a new way of teaching materials using the technology developed in recent decades, where the teacher uses a modern and educational support to keep the mind of the student in ongoing activity; this will allow greater retention which gives result better understanding and more knowledge. The system is designed to model how to teach with the versatility of being a teacher to provide knowledge through a book because it contains the text outlined and summarized the history and examination by the implementation of questions that offer 4 possible answers and answering incorrectly restart the game, it forces the player to pay attention and remember information. 2. Procedures It divided the two-step strategy: 1. Define the game. The player is asked to bring the features of the game. It must recognize three: a) The technical aspects, allowing the appropriation of technological language and sometimes the understanding of the technology used to play is essential for future acquisitions; b) the commercial tab: identify which company developed the game, age or classification suggested, price, where purchased, country of origin, etc.., a review of the business tab allows to point out habits, and c) a description of the game, review of the plot, characters, history, objectives, modality, gender (role, simulation, strategy, battle, etc..) duration, etc.. This category allows the recognition of recreational preferences of the subject. 2. Thinking the game. Before, during or after the game the subject must think what you do to win or how the game unfolds. Contrary to what seems, while playing one thinks and sometimes thinks that performing other tasks and this time it is the player or the viewer understand the way it works and identify the physical or mental is used to play, trying to understand what I do but most of all how I do it, it is metacognition. 3. Data This prototype is structured in RSS: stands for Ruby Scripting System: System with Ruby Scripting for games. Object-Oriented programming "OOP" is a model used by the most programming languages, that lets you use objects and their relationships to program what will be the final application. In order to expand its use were included languages spoken in America and expanded platform for different operating systems. 4. Conclusions With this fun game is a simple way to learn the story in time, the environment and the circumstances where the player is the student of our system that shapes the teacher, book review, making it a modern and practical way to teach with the advantage of keeping the mind active during the use of our game, this allows the continued interest in the student normally lost in conventional classes.
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大自然的飛行家--蝴蝶飛行之初部探討
本研究主要針對蝴蝶之飛行進行探討,研究中主要探討蝴蝶翅膀形狀、身體重量、翅膀面積、展弦比、拍翅頻率及環境溫度對飛行速率之影響,並利用自製之風洞裝置,觀察蝴蝶之翼翅運動,分析通過蝴蝶模型之氣流方向及相關氣動力。研究結果顯示:紋白蝶展翅約4.5~5 cm,平均展弦比(AR)為1.71 ± 0.12,身體重量約為0.06± 0.02 g,翅膀面積約0.0012 ± 0.0003 m2,當紋白蝶身體重量愈重,則翅膀面積愈大(R2=0.9586)。另外,紋白蝶身體重量愈重、展弦比愈小,則飛行速率亦愈快(R2=0.5559、R2=0.4726)。23℃時,紋白蝶飛行速率為1.01±0.24 m/s,當環境溫度愈高(5、16、23℃),則飛行速率亦愈快(y=0.07x+0.7733,R2=0.6967)。風洞實驗發現:蝴蝶會逆風而飛,當風洞的風愈強,蝴蝶翅膀拍動角度愈大,且快而持久,仰角也變大(45 度);蝴蝶翼尖軌跡呈八字形,翼翅運動包含線性平移及旋轉;蝴蝶拍翅時,可在翅上方及前方產生低壓帶,在後方產生高壓帶,以利蝴蝶向前方飛行。另外,翅緣彎曲角度(上反角)愈大,蝴蝶模型之上升高度亦愈高,當上反角60°時,蝴蝶模型之上升高度最高(2.2±0.1cm)。This research approaches the flying ability of butterflies. Our research mainly discusses the weight, aspect –ratio of butterflies, frequency of flapping, and the shape, surface area of butterflies’ wings, and the connection between temperature and flying velocity. More over, we use the wind tunnel which was made by us to observe the movement of butterflies’ wings and analyzed the direction of airflow and aero-elastic which pass through the wind tunnel. Our research shows that Pieris canidia’s length of wings is about 4.5 to 5 cm. The average of aspect –ratio (AR) is 1.71±0.12 . Its weight is about 0.06±0.02 . And its surface area is about 0.0012±0.0003 m 2 . The heavier Pieris canidia is, the bigger its surface area will be (R2 =0.9586). In addition, the heavier it is, the smaller its aspect –ratio will be (R2 =0.5559, R2 =0.4726), and the swifter its flying velocity will be. When it is 23°C, the flying velocity of Pieris canidia is 1.01±0.24m/s. The hotter temperature is (5,16,23°C), the swifter it flies (y=0.07x+0.7733,R=0.6967). Accroding to the detect of the wind tunnel’s experiment , the butterflies will fly on luff. When the stronger the wind of the wind tunnel is, the larger the angles of wing’s flap are. And they are fast and lasting, the elevation also becomes larger (45°). The butterflies’ trochoids of wings mimic the word “eight”, and the movement of wingspan includes parallel movement of linearity and wheel. When butterflies flap, it will amount depression upon and in front of the wings, amounting the high pressure on the back so that butterflies can fly antrorsely. Furthermore, the larger the curvy angle of marginal wings (Dihedral) is, the higher the ascending height of model butterfly will be. When dihedral is 60°, the ascending height of model butterfly is the highest(2.2±0.1 ㎝).
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Lose Trail Pheromone? Application of adult transport to optimal feeding strategy of the Asian needle ant, Pachycondyla chinensis.
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斑馬魚 SULT2 ST2在早期胚胎發育的 RNA 表現
在哺乳動物裡,硫酸化是一種參與外來物解毒作用、內生組織的荷爾蒙調節、藥物代謝及膽汁解毒之重要路徑。其中, SULTZ ( hydroxysteroid sulfotransferase )是能進行上述反應的酵素之一,為了對 SULTZ 的功能與早期發育所扮演的角色作進一步的研究,在本實驗中,我們以班馬魚為模式動物,希望藉由原位雜交法( in situ hybridization )找到 SULTZ 在班馬魚早期胚胎發育的 RNA 表現位置。由目前的實驗結果,發現從卵巢到1-cell、 dome 、 50 %一 epiboly 、 12 小時,都可在胚胎細胞看到訊號表現 · 在 24 小時、 36 小時、 48 小時、 72 小時則可在脊椎兩側體節的肌肉、內胚層、嗅窩、頭部看到訊號表現,此外,在成腦的原位雜交染色結果中亦看到了訊號表現。由此可推論 SULTZ 在斑馬魚早期發育確實扮演了重要的角色。Sulphonation is an important pathway for detoxification of xenobioties, bile acids, drug metabolism, and the regulation of endogenous hormones. SULT2 (hydroxysteroid sulfotransferase) is one of the enzymes which catalyse sulphonation. Zebrafish has emerged as a popular animal model in recent years. Compared with other vertebrates, it provides advantages including ease to get embryos, rapid external development, virtually transparent embryos and ease of genetic manipulation. The above-mentioned strong points made zebrafish a good model animal for us to understand the function of SULT2 during early embryonic development. We performed in situ hybridization to find out the RNA expression of SULT2 during zerbrafish early development. According to our present results, we can detect expression signal on the edge of telencephalon and tectum opticum. the edge on the dorsal zone of corpus cerebelli and ventral zone of periventircular hypothalamus of the adult brain. Besides, we can observe signal evenly distributed in blastocytes of the embryo at 1-cell, dome. 50%-epiboly and 12 hours after fertilization. We also find signal on the muscle next to the spinal cord during the stages of 24, 36, 48 and 72hrs. There are also expressions on hypoblast of embryos at 24, 36 and 72hrs, the olfactory pit at 36 and 4hrs, and strong expression in head region at 48 and 72hrs. These results suggest that SULT2 may have some function at the early development of zebrafish.
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魔術猜牌-由再生訊息延伸推展猜中比值之研究
本研究是藉由數學手法探討;如何由一疊 36 張四種花色的撲克牌中,尋找出保證可猜中最多張花色的方法。研究過程是以在適當的猜牌時機,以邏輯推理、二進位、分析與歸納 … … 等數學原理與方法,搭配巧妙的策略運用而達到目的。 猜牌方法:先約定好猜牌規則,助手將 36 張牌背圖樣相同但非對稱的撲克牌,以旋轉牌背的方向傳達訊息。在本研究中得出「經由巧妙的猜牌方法保證可以猜中不少於 26 張花色」,並得出「當總張數趨近於無窮大時,保證可以猜中不少於 81 . 07 %的牌,並且證出若僅使用獨立的訊息猜牌,無論任何猜牌方法皆無法猜中多於 87 . 37 %的牌」 · 其中一個猜中多於 80 %的例子是‘「當總張數等於 23006 張時,保證可以猜中不少於 1 8405 張牌(18405/23006 > 4/5)」 ·The study is mathematically based with reasonable explanations behind it. We are to correctly guess as many cards as possible from a deck of 36 cards, with random numbers and four different suits. We will apply mathematical methods, such as logic inference, binary system, and analytical reduction, upon right timing. Using careful arrangement of the principles and reasoning, we can reach our ultimate goal. To state guessing: Conference between the guesser and the assistant about the guessing rules, the assistant will have 36 cards with the same exact pattern on the back but not symmetrical. The pattern of the cards will be different when rotated 180o. The only communication between the two is by rotating cards. In this study, we can prove that through mathematical method, we can assure 26 or more cards can be correctly guessed. Furthermore, when the total amount of cards is close to infinity, we can assure 81.07% or more of the cards can be correctly guessed, and prove that if the cards are guessed from independent information, no more than 87.37% of the cards will be correctly guessed by any guessing methods. One of the examples, which 80% of the cards are correctly guessed, is that when the amount of the cards is 23006, 18405 or more of the cards can be correctly guessed. (18405/23006 > 4/5)
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目前市面上缺乏簡單而精準的過氧化氫檢測法,我們參考Fenton Reaction 中,鐵離子對過氧化氫分解的催化模式,利用鐵、鈷、鎳、錳、鋅分子篩,測試他們催化過氧化氫分解反應的效率,從成本、毒性、活化能的多方考量下,選擇以分子篩來固定金屬催化離子,作為我們後續實驗的研究主軸。實驗的初步,我們選擇過氧化氫作為自由基,並著重於過氧化氫的分解反應。利用濃差電池的原理,設計出一套濃度檢測系統,由分子篩作為電極。鑒於粉末狀的分子篩容易流失,我們製備出陶土鐵分子篩,以陶土固定分子篩,並以此作為電極,搭配白金絲,透過能士特方程式,測出過氧化氫的濃度,且藉由電路調控放大倍率,可以直接控制檢測範圍。從實驗結果得知,鐵分子篩在處理過氧化氫的時候,不會有鐵離子溶出的現象,且其催化性在酸性液中可以維持,能不斷的使用,長時間來看,分子篩相當有經濟與環境保護上的價值。We attempted to provide a system for quickly determining the concentration of free radicals. The existing methods or techniques are inefficient or need expensive equipment, therefore, an inexpensive system is being sought for. As a preliminary study, we focused on the decomposition of hydrogen peroxide. Taking the Fenton reaction as reference, we designed a measuring system. This system includes a catalyst containing Fe or Pt ions for catalyzing hydrogen peroxide decomposition reaction. The Fe- and Pt-zeolite were prepared to hold Fe and Pt ions to avoid losing. Because the electrically induced potential would decrease with the decrease in the concentration of hydrogen peroxide, we could measure the concentration of hydrogen peroxide by monitoring the electrical potential. We determined the initial concentration of hydrogen peroxide in water from the initial electrical potential measured through the equation obtained from the calibration line. The practicability of this system has been assured after a series of experiments. We will further develop the technique for measuring other free radicals. We anticipate that this technique will be further developed for measuring other free radicals. Although there are several problems and limitations to be solved and conquered, one thing is for sure: this system is an environment-friendly and cost-effective facility for determining the concentration of free radicals in an aqueous solution.
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由嘉義地區的氣象資料來探討二十四節氣與聖嬰現象
二十四節氣是中國古代對氣象觀測的智慧結晶,由於近幾年來聖\r 嬰與反聖嬰現象的影響,在透過嘉義氣象觀測站的協助之下,利用\r Excel 進行簡易的雨量和氣溫統計,並配合中央氣象局發布的環流型\r 態和農業災害,來探討二十四節氣在嘉義地區的適用性。\r 以陽曆來區分節氣,每年會誤差6 小時,加上四年一閏,剛好彌\r 補差距,農曆則需19 年。至於聖嬰現象對嘉義地區則呈現涼夏和暖\r 冬,但在反聖嬰現象中則變為加強四季之特性,即是熱夏與寒冬。兩\r 者都造成雨量集中夏秋兩季,形成冬春乾旱。至於二十四節氣則是以\r 夏、秋的氣溫和雨量相關的諺語較適合嘉義地區。\r Abstract\r The 24 Solar Terms, is the achievement of weather observation from\r ancient China. Because of the effects from El Nina and La Nina these\r years, we proceed simple statistics of rainfall and temperature by using\r Excel and the assistance from Chia-yi Weather Station. We adopt the\r Circulation Type and the damage of agriculture from Central Weather\r Bureau, to discuss if the 24 Solar Terms for in Chia-yi area.\r To divide the 24 Solar Terms according to the solar calendar, there’ll\r be a six –hour gap every year. The gap could be made up every four years.\r But with the lunar calendar, it takes nineteen years to offset. The El Nina\r shows cool summer and warm winter in Chia-yi area, but the La Nina\r emphasizes the characteristics of the four seasons. It shows hot summer\r and cold winter. Both of them rain mostly in summer and fall, and cause\r the drought in winter and spring. The saying of the 24 Solar Terms is\r suitable for the temperature and the rainfall during summer and fall in\r Chia-yi area.
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自組薄膜(SAMs, self-assembled monolayers)乃是具有特定官能基的化合物在不需外力作用 下自動吸附到基質表面上而自行排列成有自序規則之結構。SAMs技術因製備容易且穩定,在 應用上深具潛力。目前此方法中,以硫醇接在Au上的研究最為廣泛。本作品希望藉著SAMs 方法將硫醇分子吸附於鐵片或其他金屬表面上,以達成防鏽與抗酸目的。我們分別透過接觸 角量測研究正十二硫醇在鐵片上形成分子薄膜的可能性;利用酸與金屬產生氣體的速率研究 分子薄膜抗酸蝕的情況;測試分子薄膜的耐熱性;根據鐵片生銹時pH值變化、重量變化與[Fe2+] 含量差異來探究分子薄膜能否防鏽;最後找出適合形成分子薄膜的濃度與溫度效應。由實驗 結果我們發現SAMs薄膜確實能吸附於鐵(及鎳、銅、鋅等金屬)的表面上並增加抗酸與防鏽蝕 能力,薄膜對熱的穩定性極佳,35℃時結合效果較佳,而濃度的提高有助於SAMs的效用。 Self-assembled monolayers(SAMs) are elements which have specific functions.SAMs,ordered molecular aggregates can automatically adhere to the surface of substrate without any force.The applcation of SAMs’technique has high potential not only because ther are easy to make but also because they are stable.Exposing molecules such as alkyl thiols to an Au(0) surface is now in widespread use. In this work,we apply the thiols chemisorb onto the Fe or other metal surface to make it rust-resistant and acid-resistant.We study the following issues to find the appropriate conditions of forming monolayers in varying concentration and temperture: I. The possibility of forming n-dodecanthiol molecular monolayers on Fe surface by measuring the contact angles. II. The ability of antiacid corrodibility by comparing the rates of producing gas from acid and metal. III. The heat-resistant of molecular monolayers. IV. Whether it’s antirust by detecting the changes of pH,weight,and the concentrations of Fe2+ during the iron rust. According to the results,we conclude SAMs do adhere to the surface of Fe(and other matal like Ni,Cu,Zn), which increases the ability of antiacid and antirust.Besides they are stable to heat, have good combining effect at 35℃, and it is beneficial to the effect of SAMs through raising their concentration.
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