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化學光電池之光敏劑的開發與研究

六種自行合成出來的聯吡啶釕錯合物Ru(bpy)₃、Ru(bpy)₂(phen) 、 Ru(bpy)₂dcbpy、Ru(phen)₃、Ru(phen)₂(bpy)、Ru(phen)₂dcbpy 及商用染料N3-dye,被成功的做成光敏性太陽能電池。光電流的產生率可由IPCE (incident photon-to-current conversion efficiency) 的測量可知。此類釕錯合物可以物理吸附或化學鍵結於TiO₂奈米粒子上。IPCE 的大小可以用來探討不同吸附方式的釕錯合物轉換光電流的效率。在物理吸附上Ru(phen)₂(bpy)的效率最好。化學鍵結的以N3 Dye 最好,我們合成的錯合物以Ru(bpy)₂dcbpy 較佳。此種以TiO₂奈米結構為承載基材的太陽能光電池(Dye-Sensitized Solar Cell),染料仍以商用染料 N3-dye 最佳。本研究發現物理吸附的Ru complexes 也可產生光電流,若能最佳化,將可簡化染料錯合物之合成。 Six ruthenium complexes, Ru(bpy)₃, Ru(bpy)₂(phen), Ru(bpy)₂dcbpy, Ru(phen)₃, Ru(phen)₂(bpy), and Ru(phen)₂dcbpy were synthesized. These Ru complexes and N3 dye have been incorporated into the dye-sensitized solar cell system. The solar energy conversion of the ruthenium complexes were measured and converted to IPCE (incident photon-to-current conversion efficiency). There complexes were either chemically bonded or physically absorbed onto the nano-sized TiO₂ particles. The IPCE were utilized to compare the photon-to-current efficiency of these Ru complexes. Among the physical-absorbed dyes, Ru(phen)₂(bpy) has the highest IPCE. For chemical-absorbed dyes, the commercial N3 dye is still the best. Among the complexes synthesized in this research that are chemical-absorbed, Ru(phen)₂dcbpy has the highest IPCE The commercial N3 dye has the highest IPCE in the dye-sensitized TiO₂nanoparticle solar cell. We found that physically absorbed dye can convert photon to current. With better solar cell assembly, physically absorbed dye can have the same conversion efficiency as N3 dye.

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導電高分子發光二極體製作及性能研究

高分子發光二極體乃是利用電子和電洞在發光工作層結合而形成激子,激子在形成後隨即以光的形式衰退,而發出光來。一般而言,高分子發光二極體是一種三明治的形式,電子注入層/發光工作層(高分子)/電動注入層,而通常我們會選擇加入電子傳遞層和電動傳遞層,來增加其發光效果。本研究係針對聚苯胺做為電洞傳遞層對發光二極體之影響,分別對有電洞傳遞曾和無電洞傳遞層之發光二極體作導電度測量、循環伏安法、電位-電流測量、亮度-電位測量。發光二極體中所須之高分子層,須利用旋轉塗佈機,將其均勻的披覆在載體上,由於本校並無此儀器,所以將離心機改造成簡易旋轉塗佈機,並觀察其披附之效果。另外,在封裝元件時,係因學校缺乏真空蒸鍍的儀器,所以將利用電鍍法把鋅鍍在ITO玻璃上,或將鋁片和ITO玻璃緊靠在一起,針對此二替代方法,本研究將探討其所製出原件成效。Polymer light emitting diode (PLED) utilizes the energy gap between the layer of electron and electric hole that emits the light due to the decay of solitron. PLED is always in the sandwich from, that means the conducting polymer is contained between metal as an cathode and indium tin oxide as an anode. It is used the addition of another electric transfer layer and electric hole transfer layer to improve the lighting efficiency of PLED. The purposes of this study are to discuss the effect of polyaniline as the electric hole transfer layer. The study methods are conductivity measure, the cyclic voltametry, the luminance-voltage curve. The simplified spin coating machine was designed to coat the polymer onto the ITO. The zinc was electroplated onto the graphite as an cathode.

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心手相連的正方形

正方形兩條對角線的交點(即中心點)距四頂點等長,也與四邊等距。如果將正方形的頂點比擬成它的「手」,兩對角線的交點當成它的「心」,則兩個正方形頂點間、中心點間、或頂點與中心點間的線段相連(或重合),就如同「手」或「心」彼此相連。本文即探索當多個正方形間「心手相連」時,衍生圖形間的面積關係。而四個正方形中某幾個頂點相接(邊未重疊),恰圍出兩個三角形的圖形則是本內容討論圖形的主體架構,我們以此架構向外作出「層出不窮」的正方形,再配合中心點連接成四邊形,將推導出這些四邊形與基準正方形(Reference Square)間的面積關係。In a square, the lengths from the intersection point (center point) of two diagonal lines to the four apexes are the same, and so are they from that point to the four sides. If the apexes are “hands” and the intersection point of two diagonal lines is the “heart” of a square, the connection or overlap of two squares’ apexes and apexes, center point and center point, or apexes and center points is just like the connection of hands with hearts. In this article, hence, we are to explore the relation in area of derivative graphs formed by several squares connected “heart in hand.” When some apexes of four squares are overlain without sides overlapped, two triangles are created. And that’s the theme we are going to discuss. Furthermore, we extend the operation to infinitely overlain squares and frame out quadrangles referring to the center points of some squares. Then, the relation in areas of these overlapped squares and the Reference Square would be deduced.

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步步為營

Two soldiers walk on a checkerboard. They can only walk one step once a time and two directions, front and left, are decided randomly. The gunshot is the column and row where a soldier is located, and one will die if he enters the gunshot area of the other. To treat the probability of winning, we first study the cases of 1×n, 2×n, 3×n, and 4×n rectangles iterately. Then we establish a general form of the probability of winning in a general n×k rectangle by using recurrence technique and generating function, respectively. Finally, we extend to the general n×m×k cuboid case to obtain the first soldier’s probability of winning.在一個長方形的棋盤中,兩士兵行走,每一次只走一步,而且上和左兩個方向是隨機的,射程範圍是所在的此行和此列,而進入他人射程範圍則死亡。探討其獲勝機率,從1×n 、2×n、3×n、4×n 矩形的情形逐步研究,並分別運用遞迴式的技巧及生成函數,導出 n×k 矩形中先走士兵獲勝機率的一般式。更進一步地,我們也獲得了n×m×k 立體空間先走士兵的獲勝機率。

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以Geobacillus thermoleovorans T4 菌株轉化農業廢棄纖維素為葡萄糖以發展生質酒精

我們得知從高雄糖廠及堆肥中篩出的嗜高溫好氧菌Geobacillus thermoleovorans T4,是本種細菌首先被報導具有纖維素分解能力的菌株,但目前僅止於學術研究階段,尚未實際應用於廢棄纖維素的分解上。本研究以廢棄農作物纖維素取代學術研究所用的羧甲基纖維素(Carboxymethyl Cellulose,CMC) ,將T4菌株置於稻稈與米糠培養基內,進行分解效能比較,再利用酵母菌的發酵作用進一步將葡萄糖轉化為酒精。本研究發現,在60℃的環境中,活化的T4 菌株可在CMC、稻稈及米糠培養基中生長繁殖且發揮其分解纖維素為葡萄糖的能力,尤其在米糠培養基中的分解效果最快也最好。此外,將生產的葡萄糖加入酵母菌之後,初步發現也能成功地進行發酵作用產生酒精,生質酒精的產出指日可待!;The Research on Using Geobacillus thermoleovorans T4 to Turn the Deserted Cellulose in Agriculture into glucose in Order to Produce Bio-Renewable Energy It has been found that Geobacillus thermoleovorans T4, a thermophilic aerobic bacterial strain isolated from a sugar refinery wastewater (55-60℃)in Kaohsing, Taiwan, can secrete thermostable endocellulase and hydrolyze carboxymethylcellulose (CMC)in some academic research, but it is stillunknown whether T4 hydrolyzes deserted cellulose in Agriculture. The aim of this study is to investigate the best conditions of T4 cellulase activity after mixing with deserted cellulose (such as rice bran and rice straw) by measuring the glucose concentration and bacteria number, and to produce the ethanol by activated yeast. T4 was added rice bran and rice straw medium, and cultured in 60℃ for 10 hours. The number of T4 and the concentration of glucose were measured every two hours. The best conditions were examined by comparing the hydrolyzation efficiency of T4 in different cellulose medium. We observed that T4 grew efficiently in different cellulose medium and hydrolyzed cellulose into glucose, especially in rice bran medium. The yeast also converted glucose into ethanol. Our research may shed light to the development of bio-renewable energy!

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蟹殼幾丁凝膠應用在金屬氧化物奈米顆粒的製備與燒結

筆者利用自製的幾丁質與不同金屬的混合溶液而燒結出的奈米顆粒成效極佳,不但粒徑大小符合,在燒結的過程中也不需經過物理研磨及介面活性劑的輔助,並且在低溫下即可燒結,可以增加實用性以及商業價值。此外,在分解亞甲藍方面也有不錯的效率,並進一步從金屬氧化物之奈米膠體混合溶液比例的不同,決定其粗糙度(以AFM測定)及能隙改變,在陽光下有更高的應用效率。而在實驗的延伸研究上,希望應用在防菌、除污、甚至光電池。 We make use of self-made chitin with the mixed solutions of different metals to solder nano particles, and the result is excellent. The particle radius not only matches up to the size, but in the process of soldering nano particles, it doesn’t need any physical pulverizing or surfactant assistance. Also, it can solder in low temperature. And we could raise its practicality and the business value. What’s more, there is a good efficiency in decomposing Methylene Blue. We can further decide the roughness (measured with AFM) and the variation of the band gap from nano colloid of different metal oxide mixed ratios.Our experiment in the extending research aims to apply it to the defense of bacteria and pollution, and even photoelectric cell.

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在浪碎之前

本研究以模擬實驗探討波浪在斜坡海灘上的行為。實驗在長1.8公尺、寬0.75公尺的透明水波槽中進行,以長0.90公尺、寬0.60公尺的木板在深水區產生單峰波向淺水區前進,同時以數位錄影機錄影後進行分析。結果發現單峰波由深水進入淺水,波速會變慢,但當波高對水深的比值增加到一定值時,波速隨水深變淺而變快,波高也變高。當比值繼續增加,波前方的水面形成垂直的水牆,接著波就碎了。如果坡度較緩,碎波點會離水岸線較遠,水牆維持的時間也較長。有趣的是,水波槽中的單峰波移動時,有蠕動現象,波寬會伸縮,波高會起伏,波速也會些微地忽快忽慢。 ;This study simulates the behavior of the wave on a sloping beach. Experiments are performed in a sloping wave tank. A paddle wave maker at the deeper end generates single crest waves. To analyze the wave height, speed and breaking point, a digital camera is used. The results show that when the wave moves toward the coast, the shallower the water is, the slower the wave moves. But when the ratio (wave-height/water-depth) exceeds a critical value, it turns out that when the water is shallower, the wave speed becomes faster and the wave height, higher. As the ratio keeps on increasing, the front part of wave becomes a vertical water-wall, and then breaks. If the slope is gentler, the breaking point will be farther from the coast and the water-wall will keep for a longer time. An interesting phenomenon is also found that a single crest wave squirms with slightly undulated changing of width, height, and speed while it propagates in the sloping wave tank.

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了解抗氧化的「旋」機-利用自製的旋光儀來探討旋光性與抗氧化成分之間的

In this research we derived heating effects on anti-oxidation by optical rotation analyses. A simple and accurate Polarimeter was devised with polar screens, laser, and photo resistor; the laser was used for light source, and the photo resistor for detection. Four kind of fruits, Hyloceeus polyrhizus, California plum, kiwi and tomato were experimented by heating them in boiling water and microwave oven. Their optical rotations versus time duration were calculated. Then we used ABTS/ the H2O2/HRP analysis system from Arnao's research to obtain the heating effects on anti-oxidation by calculating the vitamin C densities versus lag time. We found that there was a tendency of increased anti-oxidation at the beginning by heating, but decreased afterwards. Better oxidation was achieved by using microwave for Hyloceeus polyrhizus, by using boiling water for kiwi and tomato, and by using both methods for California plum. The same tendency was also found in the optical rotation analyses. Therefore we successfully developed a new method to measure the antioxidant activities by the optical rotation. We can also apply this method to simulate the fruit digestion process in the stomach, which let us understand further about anti-oxidation ( or optical rotation ) versus time. 本研究利用偏振片、雷射光為光源、光敏電阻為偵測器,組裝成一個簡易且精確的旋光度計。 我們利用此旋光度計對奇異果、火龍果、聖女蕃茄、加州李子四種水果以微波、水煮及油浴三種方式來處理,求出水果的旋光度與熱處理時間的關係。再藉由Arnao 研究的ABTS/ H2O2/HRP 分析系統,以不同濃度的維生素C與延遲時間畫圖作為標準曲線來測量總抗氧化活性,並比較熱處理後抗氧化活性的變化趨勢。 透過本研究可以了解不同熱處理方式對四種水果之抗氧化活性初期皆有增加的趨勢,但隨著時間增長則抗氧化活性降低。其中奇異果與聖女蕃茄用油浴,火龍果用微波處理,加州李子則是用任何熱處理方式均可得較佳的抗氧化活性,而熱處理後在旋光度測量上也有相同的趨勢。因為此兩種方法有一致的反應趨勢,所以證明我們成功地開發出一種可以利用旋光度來測定抗氧化的新方法。 最後,應用本方法進一步模擬水果在胃部裡的消化,讓我們更可以了解在整個消化的過程中抗氧化活性(旋光度)隨時間變化的情形。

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A load-balancing strategy for coarse-grained tree searches as applied to fractal image compression

An exact solution to many current computational problems, such as the famous Travelling Salesman Problem (TSP), require a complete tree traversal in order to determine. This is often unfeasible, as the time complexity of the tree traversal grows exponentially with the size of the input, thus leading to an essentially computationally intractable problem. The branch and bound technique is an approach commonly used to speed this process. It entails dynamically pruning off branches of the tree in which the answer is probably not found in, hence reducing the amount of data that is needed to be traversed and the total time and resources required to perform the computation. In this paper, we introduce a new load-balancing strategy for the execution of such a branch and bound algorithm in parallel, using a three-tiered hierarchical approach, to perform fractal image compression, which is essentially a complete tree traversal problem. This novel heuristic is aimed at achieving optimal load-balancing and minimising unnecessary network traffic and bottlenecking, which functions by predicting the optimum search depth and hence controlling the coarseness of the input that is assigned to each worker node. Our scheme additionally enables us to tailor to the specifications of different clusters, as the heuristic is adjusted based on network speed and processor speed, which vary appreciably from cluster to cluster. We further discuss how to apply our method to other large tree search problems, such as the TSP and other NP-complete problems. We have also enhanced an existing load-balancing strategy outlined in Crivelli et. al. (2004, IBM Journal of Research and Development), by prioritising the reallocation of idle worker nodes such that supervisors who are in need of more help receive a larger share of the free workers.

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天然A 尚好-探討天然果實無患子的殺菌力與時效性

The natural fruits of soap berry are worth-while detergent in the aspect of environmental conservation. It has been shown that the soap berry fruits can reduce the itching of head and inhibit the growth of fungi. Here we would like to test the inhibitory activity of soap berry fruits on the bacteria. This might benefit to the further application of the soap berry fruits. First,the soap berry extract was prepared and mixed with E.coli or S. aureaus. The number of bacteria was counted to realize the inhibitory activity of the soap berries. We found that the soap berry extract can inhibit the growth of E.coli and S. aureaus. Higher concentration of the soap berry extract and longer duration for the mixture make better inhibitory activities. 天然的無患子果實是一種極具環保價值的清潔劑,已知它有抑制黴菌生長的能力,可以 去頭皮屑、止頭皮癢。因此,我們想進一步探討無患子果實對於細菌生長的抑制能力,以期 了解無患子清潔劑在廣泛推廣上的應用價值。 在實驗設計上,我們自製無患子萃取液,並選擇日常生活中常見的大腸桿菌及金黃色葡 萄球菌,並然後使菌液與適量的無患子萃取液混合,計算菌液在加入無患子之前、後的細菌 個數,藉以了解無患子的殺菌力。我們發現無患子萃取液對大腸桿菌及金黃色葡萄菌有明顯 的殺菌力,且無患子濃度愈高、作用時間愈長,殺菌力愈好。

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利用Google Maps 建立高中地理資訊系統

台灣通史「婆娑之洋,美麗之島」,身為台灣人,應知台灣事,本研究本維 基百科(Wikipedia)所揭示的「海納百川,有容乃大」精神,以Apache 網頁伺 服器為平台,MySQL 為資料庫,利用AJAX、PHP 網頁技術,並使用Google Maps 提供之服務,建立符合Web 2.0 精神的的b04地理資訊共享系統。在此系統下, 我們允許教師(編輯者)以合作方式上網提供與課程相關的地理資訊,並可進行資 訊修改或刪除,希望集合所有教師之力,提供給學生最豐富、最正確的b04地理 資訊系統。 In this paper, we propose a new map-based collaboration environment “MyGIS” for geographical information distribution. In MyGIS, the publishers/teachers can easily collaborate to annotate a spot with contents such as messages and links. The annotations of a spot are updated on the map in real-time which enables the receivers/students to correctly study at anywhere and anytime. To ensure the trustfulness of the content, the publishers are authenticated using login mechanism. In this study, several technologies inc lu ding Apache, PHP, MySQL, Ajax are involved. Finally, We implemented MyGIS on Google Maps and evaluated its feasibility and usefulness.

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探討第三號誘餌受體對NOD小鼠糖尿病預防與T細胞分化影響之研究

DcR3是腫瘤壞死因子6B的成員(Tumor necrosis factor receptor superfamily),又稱為TR6或M68。DcR3會藉由與Fas Ligand, LIGHT或TL1A等細胞表面配位結合,阻擋T細胞的死亡訊息傳輸,保護該細胞免於細胞凋亡;另外,DcR3也會與抗原呈現細胞的硫化肝素糖蛋白結合,誘導未分化之T細胞發育成能減少自體免疫疾病發生的Th2細胞,顯示DcR3有充分作為自體免疫疾病預防之藥物的可能性。因此我藉本實驗探討DcR3對T細胞分化與發育造成的影響與造成此一現象的原因。 根據實驗結果,我們發現DcR3不僅有上述之功能,更能增加調節型T細胞(Treg)這種抑制免疫反應的特殊T細胞表現量,若能藉由Treg調控免疫系統活力,將可改善易般免疫抑制劑治療造成病人免疫力下降之缺點。因此我藉由NOD小鼠,實際檢測DcR3在活體中對抗自體免疫疾病發生的能力,並以DcR3與T 細胞之交互作用實驗,探討現象的成因。根據實驗結果,在Somatic gene therapy和Protein therapy的實驗中,皆可看出疾病延遲發生的現象。而在DcR3對T細胞存活率的影響方面,可看出DcR3並不會造成T細胞之異常死亡。故我們推測DcR3可藉由增加Treg表現量減緩或降低NOD小鼠糖尿病的發病。 因此我們認為DcR3非常有潛力作為未來自體免疫疾病預防或移植手術後用以抗排斥之藥物。

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