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近年來重金屬污染問題日益嚴重,因此檢測地下水、工業廢水中的重金屬含量為一重要課題。本實驗即是利用錄音機中的零件-石英振盪器作為電化學分析偵測的工作電極,在0.1 M KNO3(pH = 3)溶液中利用循環伏安法以50 mV/s 的掃描速度從 – 100 到 – 700 mV 持續掃描 10 圈,來穩定電極表面。
以方波陽極剝除伏安法(SWASV)模式設定預濃縮電位– 700 mV、預濃縮時間60 秒偵測重金屬的鉛離子。掃描電位範圍由 – 700 到 – 100 mV vs. Ag/AgCl 往氧化方向掃描。偵測鉛離子濃度範圍為200-600 ppb,之後可針對各種條件作最佳化的條件探討可降低偵測濃度及實際運用於地下水及工業廢水的檢測。
Heavy metal pollution becomes very serious. Lead (Pb) determination is a continuous research interest in clinical, environmental, and industrial application. The main causes for living biological media are mutagenic, carcinogenic, and teratogenic activity. The determination of trace metal in the ground and industrial waste water will be a important project. Here, we report a simple system which using quartz crystal microbalance (QCM) (use in radio machine) for working electrode. The QCM was first equilibrated in 0.1 M KNO3(pH = 3)base electrolyte for about 1 min before electrochemical experiments. It was then pretreated by continuous scans in the window from – 100 to – 700 mV at a scan rate of 50 mV/s until a stable background current obtained.
The amount of Pb2+ was detected quantitatively using square-wave anodic stripping voltammetry(SWASV). The potential range was set from – 100 to – 700 mV in the cathodic direction for most cases. The standard addition method concentration range is from 200 to 600 ppb. Analytical conditions were systematically optimized and extended to practical applications aslo.
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月相變化對極地天氣系統的影響及其引發高緯度天氣變化之探討
本研究比較2003~2005 年,冬季及夏季西經168 度之「海平面溫度異常」對「緯度」的分布圖,結果呈現在赤道附近的變動較小,在高緯度地區的變動較大,為更精確的描述此變動,將每日高緯度地區的變動以「標準差」及「最大振幅」數量化,發現在南、北半球不論2003、2004或2005 年,每7~12 天南、北半球的「冬夏季海平面溫度異常」的變動變大,上述變化在北半球較為明顯,在南半球較不規則。 與2005 年冬季1 月31 日~3月17 日的北半球地面天氣圖進行分析比對發現,溫度的變動和極地天氣系統的形成關係密切,推測原因和冬季時極地為永夜,地面空氣溫度受到兩個跟月球有關的熱源影響較大,其一為海流和極地間每日有接近2 次的潮汐交替運動,其二為月球反射日光後投射到極地時,極地大規模的冰對月光的反照,對極地微弱的加熱作用。 針對2005 年6 月1 日~7月22 日之地面天氣圖作分析,結果發現夏季緯度的溫度變異和高中低緯度天氣系統的改變關係密切,推測此時和月球對海水的吸引使地表(特別在海陸邊界)的溫度,週期性的重新分配,或對大氣應也會造成週期性的質量分配有關。 以農曆為主重製溫度的變動圖並進行比對發現,無論2003、2004或2005 年,在月相為朔及望時常出現低值。此分析結果顯示,接近朔望時,高緯度海平面溫度有較穩定且變動較小的情形。而從天氣圖、農曆標準差綜合,所得結論為地月運動應和地球上高緯度天氣系統存在某種相關性。 ;Our topic is about how the moon phase variation influences the high-latitude weather system. This study analyzes the sea surface temperature anomalies (SSTAs), along 168°W in winters and summers from 2003 to 2005. The results show that the SSTAs varied relatively small around the equator and relatively large in high-latitude regions. So we next analyze the high-latitude SSTAs by the standard deviations, the maximum amplitudes, and the north surface weather graphs. After analyzing, the result shows that the SSTAs rise for every 7 to 12 days. Moreover, they relate to the winter high-latitude weather system very much while relating to the summer medium-and-low latitude weather system a lot. We think it’s because in winter eternal night, the sunlight won’t shine on the arctic zone easily. Other heat sources may become important: (1) the tidal movements between the ocean and the arctic zone. (2) The heat radiation of the moonlight and the moonlight reflection by the polar ice shields. But in summer, the moonlight effect becomes extremely small. The tidal force becomes the bigger influence factor: (1) the tidal attraction may distribute the temperature of the border between seas and land periodically. (2) It may cause the periodic atmosphere mass distribution. Additionally, after repeating the same experiment according to the Chinese lunar calendar, we found near full-moon and new-moon time, the SSTAs are more stable. Probably because of without the moonlight, the movements of rip-tides occur and help stabilize the polar weather conditions. In conclusion, the relative movement of the moon to Earth is likely providing a crucial heat source which will affect the high-latitude climate, and the heat source size probably influences the weather system cycle.
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所有的物質都跟人們一樣喜歡最安穩舒適的休息,表面張力正是水溶液中扮演使水安穩的角色,它的存在能使水面平靜盡可能不被影響。影響表面張力的因素很多,包含溫度、溶液酸鹼性、瓶子的口徑大小、添加不同物質的水溶液都是影響表面張力的原因,意味著會間接影響到整杯水溶液的平靜,故到底各個情況對表面張力的影響為何,將是我們致力想了解的目標。
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Development of an ECG-System using AndroidTM and Modified Bluebeatc Hardware
Electrocardiograms are important medical devices used to monitor the cardiac activity of patients over a period of time. Designed to provide convenient monitoring of patients, although most useful, ECG’s however are expensive and usually not portable, limiting its availability and therefore usefulness. Taking advantage of current technological developments, the researchers developed an ECG System with Androidâ„¢ smartphone based monitor, and Bluebeat© ECG Front circuit based electrodes. The system is divided into two, software and hardware interface. The developed software interface code used an Android based Java language which displays the converted ADC values in the LCD. Saving and user friendly features were also included in the smartphone. The hardware interface is composed of the ECG front and the Data Acquisition Module. The ECG front contains the filters and amplifiers that will receive the human cardiac signal. The DAT Module will then receive it with its Gizduino (Arduinoâ„¢ clone) microcontroller which converts the analog signals into ADC values, and finally sends it to the smartphone using Bluetooth© wireless communication. The first phase of data gathering used signal generator and indicates the system’s accuracy and speed. The second phase testing of the study meanwhile utilizes the ECG front to get actual cardiac signals from human. This phase has already been done, though it still needs more polishing and further trials. For the final testing, nine patients of varying ages and cardiac health status will be taken with ECG readings, three replicates from the developed ECG system, and one from an actual ECG device. Using cardiologists’ and patients’ feedback, the user friendliness and accuracy of the ECG-system will be confirmed, and further modifications shall be made. Lastly, the overall cost of producing the ECG system shall be compared to the price of an ECG device, to see if the developed system is indeed cheaper. However, it is ensured that the system is far more portable than its bulkier ancestors. Once the project is fully finished, the accuracy, replicability and usefulness of the system shall be confirmed using F-test.
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光由植物體下方向上照射對植物生長影響的探討
今日老師講國中生物(上冊)第六章“植物的感應”時擧向光性為例。老師說:一般的光源都是高於地平線,因此植物的莖,對射來的光源是取平行位置生長的,所以稱為「向光性」同時又具「背地性」。而根則與莖相反,與光源成相反方向生長,所以稱為「背光性」,同時又具「向地性」時,我就站起來請教老師,如果光源是從植物體下方向上照射的話,對植物的生長有影響嗎?又各種光質對植物生長的影響怎樣?於是老師很高興奮地說:這是很好的題材。接看又說:大多數高等植物都遵循趨性的原理而生長,是毫無逾越的。如果我們把光源移到植物體下方向上照射的話,本來植物的莖是屬於向光性的,應該往下生長;但是莖的背地性又會使莖向上生長,到底令其向下生長?還是向上生長?同樣的理由,根因有向地性而須向下生長,但又具有背光性,又令其向上生長,向上向下無所適從,實際上到底應如何生長呢?確實值得我們來做實驗加以探討,那麼寒假是最好的機會了。
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黑擬蛺蝶(Junonia iphita iphita)的幼蟲生存策略
黑擬蛺蝶(Junonia iphita iphita)為台灣地區常見的蛺蝶,其幼蟲具有築巢行為,但文獻中對其幼蟲行為的描述極少,因此本實驗探討黑擬蛺蝶幼蟲在野外的族群變化與環境之關係,並研究幼蟲築巢行為,以探討其適應環境的生存策略。首先於室內及恆溫生長箱中飼養幼蟲,以建立其生活史基本資料,並於野外統計各齡期幼蟲在不同植物上的數量變化及築巢行為的差異,以探討不同環境因素對幼蟲築巢之影響。由實驗結果得知,黑擬蛺蝶生活史短,可取食多種爵床科(Acanthaceae)之植物,其寄主植物除文獻所紀錄之台灣馬藍(Strobilanthes formosanus)及賽山藍(Blechum pyramudatum)等外,也取食大安水蓑衣(Hydrophila pogonocalyx)、無花水蓑衣(Hygrophila violacea)、易生木(Hemigraphis repanda)及翠蘆利(Ruellia brittoniana)等。黑擬蛺蝶幼蟲野外族群波動與溫溼度及雨量等環境因子並無直接關係。黑擬蛺蝶一年發生多世代且有世代重疊情形,世代波動與四季律動關係不明顯,顯示黑擬蛺蝶對環境的適應力大。黑擬蛺蝶幼蟲利用築巢以適應環境變化,應是其幼蟲良好的生存策略。且幼蟲在強風及光線強的環境下築巢率增加,降雨時則減少。Junonia iphita iphita belongs to Nymphalidae(Lepidoptera). They can be found easily in the wilderness of Taiwan. Its larva shows nest-making behavior. However, there is little literature documenting the behaviors of its larva. Therefore, the purpose of this research is to investigate the relationship between the quantities of Junonia iphita iphita’s larvae and its natural habitat, to research its nesting behaviors, and to investigate its survival strategies to adapt to the environment. I started by raising larvae in a growth chamber under a controlled temperature in order to obtain its initial information regarding its life history. In the field, I documented the numbers and the changes of larvae at each stage on different host plants and recorded the differences in its nest-making behavior in order to find out which environment factors influence the nest-making of Junonia iphita iphita’s larvae. These experiments concluded that the life history of larvae is short. The immature intaking habit showed that the larva takes various plants of the Acanthaceae. In addition to the host plants mentioned in the literature, such as Strobilanthes formosanus, and Blechum pyramidatum, Junonia iphita iphita’s larvae also live by Hydrophila pogonocalyx, Hygrophila violacea, Hemigraphis repanda, and Ruelba brittoniana, which were not listed in the literature. Through experiments, I discovered that there is no direct correlation between the population fluctuations of larvae and it’s enviroment including factors such as temperature, humidity or rainfall. Junonia iphita iphita can produce multi-generations in a year accompanying generation overlapping. There is also no obvious correlation between the generation fluctuations and changing seasons, showing that larvae can easily adapt to the environment. Junonia iphita iphita’s larvae adapt themselves to the different environments by nest-making which should be a good survival strategy. Besides, the rate of nest-making increases when larvae are under strong winds and strong lights and decreases when the rain falls.
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本篇報告主要以尿液為電解質,並搭配金屬片為電極,嘗試組合出可使LED 燈泡發亮的尿液電池,由此證實尿液能發電。再藉由各種金屬片的組合及鹽橋的使用,找出電力超強的最佳條件。經測得銅片與鎂片為最好的電極配對,創造出「尿液手電筒」。
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由截痕及不變量來探討二元二次函數之極值
我們知一元二次函數f(x)=ax 2+bx+c,一定有極值,當a>0時, f(x)有極小值為-b 2-4ac / 4a,a
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本次的研究主題是由井字棋延伸而成的桌遊3×3奇雞連連及4×4「棋」蹟連連。我們想要在不同格數棋盤以及不同類型棋子種類的情況下,分析其遊戲邏輯。我們的研究方式是將棋子依照規律,先手放在棋盤上的各種位置,再接著依照當下最好的選擇出棋,我們分析了井字棋、3×3奇「雞」連連及4×4「棋」蹟連連的各種遊戲局面,以及三種遊戲中不同種棋型的比較,並且找出格數與和局關聯的公式。
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最近報上一大新聞「濫用肥料農藥,土地污染受酸」這是台灣地區土壤調查人員調查的報告,為什麼土壤會變酸呢?覺得很奇怪,於是請教老師,老師說:「我們可以研究土壤的真面目呀!」於是我邀了三位好同學赴(新莊、林口、土城、光復橋下)……不同地點採集土壤標本,進行觀賞與研究。
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從有限三角和公式研究偶次調和級數之遞迴公式及其相關等式之推廣與應用
本研究中,我們將提出一些新穎結果,著重討論其在三角中的應用;同時,找出其遞迴關係式,得出三角展開式與其所對應之多項式分解式,進而討論出多種的規律性及所涵蓋的內容及推廣性質,我得到很多高中數學公式無法推導出在【4】和【8】中的漂亮公式及創新的結果,且這些等式都是由我們不太瞭解的無理數所構成的。
主要是討論我們在【7】中所得到的收穫與經驗;複數是三角、幾何、代數互動的橋樑,我是以不同的角度及嶄新的方法來綜合探討在【6】中相關的應用。提出關於正整數平方的倒數和公式更為精簡且基本的證明,將 sin−2 x 表示成級數形式的部分分式,進而應用在(a,b) = 1的機率問題上;並研究相關的等式,直接透過三角與代數來研究關於 2p 次方的倒數之求和問題,得出級數 之和的有用遞迴公式,並與最重要的常數扯上關係。
For one thing, we present diverse methods to evaluate finite trigonometric summation and related sums. Trigonometric summations over the angles equally divided on the upper half plane are investigated systematically. Several related trigonometric identities are also exhibited.
What is more, we use methods of calculus, and make several surprising and unexpected transformations. A useful recursive formula for obtaining the infinite sums of even order harmonic series, infinite sums of a few even order harmonic series, which are calculated using the recursive formulas, are tabulated for easy references. Furthermore, is there any interesting results and applications?
Finally, the purpose of this paper is to develop a new proof of and related identities, but their derivations are more complicated. The following studies are completed under the instruction of the professor.
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