利用奈米色料製作彩色蠶繭之研究
由於奈米科技進步，奈米材料應用在產業上具有多功能的性質。本研究使用不同波美度的色料餵食家蠶，以找出最佳的彩色蠶繭色澤，並研究其如何影響家蠶所結出的蠶繭及色料附著在蠶繭上的絲。同時對色料附著的蠶繭進行水洗、光照、微結構的觀察，以試圖找出色料與波美度之最佳組合參數。由本實驗結果得知，利用奈米色料溶液60 ml，在紅色：1.048、藍：1.058、黃：1.039 的參數下，混合飼料30g，可獲得最佳的彩色蠶繭結繭成功率、均勻度較佳、耐褪色與耐洗滌等優點，並且可獲得表面結構光滑且較細的絲徑，約為19.87μm。相對的，一般色料粒徑為微米級，色彩度優於奈米色料，但表面結構較奈米色料粗糙且線徑較粗，約為21.51μm，易於褪色及不耐洗滌。 Because of the great progress of nano-technology, it has the quality of multi-functions to make use of nano-materials on industrial property. The purpose of this study is to find the best colored silkworm cocoons by mixing different consistency of pigments to feed silkworms. At the same time, this study wished to explore how the different consistency of pigments influenced the silkworm cocoons that the silkworms produced. Besides, in order to find the better association between pigments and Baume degrees, this study exposed the cocoons under different lights, washed with different detergents and take observations of micro-structure of the cocoons. The results of this study are as follows: using the nano-pigments 60 ml in different density, that is, red:1.048, blue:1.058, and yellow:1.039, then mixed them with silkworms’ forage 30g , in this way, best successful ratio to get colored cocoons, desired high visual effects in color, well distribution, long duration and strong resistance to detergents agents are obtained. In addition, we can still get glossy appearance and fine cocoons; the wire diameter is about the size of 19.87μm. On contrast, feeding with the ordinary pigments, the degree of colored silk is better than feeding with the nano-pigments, but the appearance of cocoons are rough and the wire diameter is about the size of 21.51μm.
Automated Traffic Light
This Project is inspired by the situation incurred by pedestrians, which for the most part are students who need a crossway in order to obtain public transportation or to get to the school; the difficulties that are faced by the personnel to exit the parking lot as well as the students who have a vehicle and to help those parents who drop and pick up their children at the school. At the same time, we would like to reduce the amount of contaminated gas emissions that are emanated into our environment. As consequence of the emission of toxic substances, the air contamination can cause side effects such as the burning of eyes or ears, throat irritation and itching and or respiratory problems. Under determined circumstances, some chemical substances that are found in the contaminated air can produce cancer, congenital malformation, brain damage and disorders to the nervous system, as well as, pulmonary damage and harm to the respiratory tract. For the present investigation it has been suggested as a primary goal: The development of a device, in this case a traffic light, which has the objective to reduce the previously mentioned traffic/security problems that arise upon entering and exiting the institution. The secondary goal is to have a friendly ecological impact within our community. This device was built and tested during a month to obtain figures and demonstrate benefits reported. The device should be low maintenance, it should have a long lifetime and, be simple enough to be operated by those who use it. Among the benefits found, the safety of the students, the prevention of accidents such as: car crashes and run overs, etc. Our studies indicate that per week it is consumed an average of 2,020.16 liters of gasoline, in schedules of 13 hours (from 7:00 AM to 8:00 PM) to lessen this figure would have a good ecological impact since all the hydrocarbon emission are harmful to health.
藉由lotus effect 之原理來探討超疏水性表面的製備
超疏水表面(superhydrophobic surface)因其自我清潔效果在近年來引起廣泛的研究及探討，目前世界各大公司皆積極投入自潔性產品(超疏水表面)的研發，但是截至目前為止除了塗料及織物有產品外，其他尚在研發階段。降低表面能及增加表面粗糙度為製作超疏水性表面的兩種方法。本實驗我們針對使用不同方法去仿照自然界植物「蓮花效應」，將二氧化矽粒子適當的分佈在基材表面，以增加粗糙度，製造出超疏水性表面。我們發現鍛燒會使其二氧化矽粒子黏聚在一起，對接觸角的增加無幫助。而在溶膠凝膠的配置過程中直接加入OTS(Octadecyltrichlorosilane)，並利用光散射儀比較二氧化矽奈米顆粒的平均粒徑及粒徑分佈隨時間變化的情形，一段時間後發現會有明顯大顆粒沉澱，塗佈在玻璃基材表面後容易脫落，不適合往後實驗或其他用途。而以氨水催化的溶膠凝膠以不同流速滴入TEOS (Tetraethylorthosilicate，四乙氧基矽)對接觸角的影響也不大。最後我們利用砂紙在基材表面上刷磨，可以使二氧化矽粒子分佈均勻，明顯增加接觸角。塗佈速率的改變搭配疏水性矽烷單分子膜的改質，我們已可以製造出159°的超疏水性表面。Superhydrophobic surfaces are generally made by lowering the surface energy and increasing the surface roughness. In this experiment, we use different methods of spreading silicon dioxide nanoparticles properly on the surface in order to increase the surface roughness and also make superhydrophobic surfaces. In the beginning, we find that the calcinations can cause its silicon dioxide nanoparticles to stick together instead of increasing the contact angles. Then, add OTS (Octadecyltrichlorosilane) directly to manufacture process of sol-gel, and observe the situations of the average length and the spread of silicon dioxide nanoparticles with the time goes by. After a period of time, we will discover that many obvious big particles deposit and spin-coating on the glass surfaces flop easily. Hence, this phenomenon is n’t proper for the following experiments or other uses. However, the contact angles have nothing to do with dropping the sol-gel catalyzed ammonia to TEOS(Tetraethylorthosilicate) by different flowing rates. Finally, it is crucial for us to use the sandpapers to brush on the surfaces because it may cause the silicon dioxide nanoparticles to spread well and obviously increase the contact angles. Combining the silicon dioxide surfaces with the change of spin-coating rate and the cover with hydrophobic SAM, we have made the superhydrophobic surfaces of 159°.