摘要或動機

This research tries to find out how changes of weight or proportion of a reactor
would affect the type and structure of a crystal. In the experiment, the Hydrothermal
reaction was adopted to conduct the syntheses of Vanadium-substituted Gallium Phosphates
and try to pick up the single crystal to collect data with SXRD for further illustrating
the crystal structure with diamond software to know well its nature. The research
result finds out a new type of crystal unseen in the existing literature produced
because of the weight changes of C₃H₁₀N₂, therefore the weight change of a reactor
may affect the structure of crystal significantly. In the future, it is expectation
that comparison among structures of other Vanadium-Substituted Gallium Phosphates
can be made, and the properties of this compound can be measured, and try to find
out a brand new type of structure for new exploration by changing the initial reagent.

本研究係透過改變化合物所添加之反應物的比例，以了解反應物比例的改變對晶體的型態與結構的影響。實驗採用中溫水熱反應來從事金屬釩鎵磷酸鹽的合成。並挑取單晶，以X-ray
繞射儀進行數據收集，再以diamond 軟體繪出晶體的結構圖，且進一步得知其性質。研究結果發現，經改變丙二胺的量後，產生不同於文獻上的新化合物，可知改變所加反應物的比例，對於晶體結構有相當大的影響。未來可朝向與其他的釩鎵磷酸鹽做結構上的比較、對此化合物做更進一步的性質測量、改變起始試劑測試，進而得到更新穎的結構形式等部分進行探究。