摘要或動機

直接乙醇燃料電池以酒精與氧氣透過氧化還原反應產生電能，但化學反應緩慢，需利用觸媒以增加其速率。本實驗目的在於盡可能找出一個表現最佳的觸媒。本實驗利用活性碳粉作為觸媒（鉑、錫）的載體，以酸性（HNO₃）與鹼性（NaOH）環境分別處理碳粉，再以含浸法與多元醇含浸法將觸媒還原。我們得到以HNO₃ 處理的碳粉無法保有原碳粉的型態，較利用NaOH 處理為差。在觸媒製備方面，多元醇含浸法還原效果比含浸法可得到較小的觸媒尺寸，在本實驗中，溶液中鉑與加入的碳粉重量比為3:7 時，可得到最大的反應面積。此外，當鉑與錫原子數比為4:1 時，可得到最大的乙醇氧化電流。Direct ethanol fuel cell is a kind of power source which generates electrical power by a redox reaction involving ethanol fuel and oxygen. However, this reaction takes place slowly; therefore, catalyst is needed to improve its activity. The goal of this project is to get an optimize catalysts ratio to obtain the best catalyst activity. Activated carbon is used as the support of catalyst (platinum and tin) particles in this project, which is pre-treated in acid (HNO₃) and alkaline (NaOH) solutions respectively. Then, the precursor is reduced by impregnation and EG-impregnation. We learned that activated carbon pre-treated with NaOH activates better than which pre-treated with HNO₃ because the latter bear less resemblance than the former. As for the catalyst, the results of EG-impregnation show smaller size of catalyst particles than those of impregnation. In this project, when the ratio of the weight of platinum and activated carbon added into the solution is 3:7, we can get the largest surface area. In addition, when the ratio of the amount of platinum and tin atoms is 4:1, we can get the largest current of ethanol oxidation.