帶電的離子受到垂直的磁場與電場作用,會因為受到洛倫茲力而產生有趣的轉動現象。我們利用上述原理設計簡易的裝置設備,探討電解質溶液不同濃度、不同離子電荷數,受到不同離子間靜電力,產生不同的離子移動速度。經由所測量的時間與圓周運動的距離,可計算電解質的絕對遷移速度。由實驗結果推論在固定電場下,當電解質濃度降低,正、負離子間的相互作用力降低,離子遷移速度(migration velocity)加快,莫耳電導率 Λ(mole conductance)也隨之增加。同濃度時,電解質2-1 價型硝酸銅與2-2 型硫酸銅離子強度(ionic strength)不同,2-2型硫酸銅離子強度較大,遷移速度較小,莫耳電導率Λ 也較小。Because of the effect of Lorentz force, charged ion will have interesting rotation under the vertical magnetic and electric field. We use the above principle to design a simple instrument or tool, in order to evaluate and study the formation of different ionic mirgration velocities. The velocity of the charged ion in the instrument is affected by differences in the electrolyte, the charge differences of the ion tested and the differences in electrostatic forces between ions. From the experiment we can deduct that at a fixed constant electric field, when the concentration of the electrolyte is reduced, the interaction of forces between positive and negative ions will be reduced. When the migration velocity of ions increase, the mole conductivity Λ (mole conductance ) will also increase. At the same concentration, the ionic strength between copper nitrate ( 2-1valency type ) and copper sulfate ( 2-2 valency type ) are not identical. Copper sulfate, a 2-2 valency type has higher ionic strength, the velocity is slower and the mole conductivity Λ is also smaller.
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